Simultaneous use of geochemical and geophysical methods to characterise abandoned landfills

. Groundwater sampling and geophysical methods determined a serious contamination problem associated with refilled exploitation sites at the Cal Dimoni area, Llobregat delta, Barcelona, Spain. To characterise this process, hydrogeochemical analyses were performed and showed the following modifications to groundwater chemical composition: increasing pH values, changing redox conditions, significant increases in total organic carbon (TOC) and certain trace elements, and high groundwater conductivity values. Major ion content accumulations were found under the refilled area. In contrast, elements involved in the oxidation–reduction processes, such as iron, manganese and nitrates, clearly diminished. Electromagnetic prospecting methods were also performed and delineated the contamination plume extent. These methods also showed separate sources of contamination, one clearly related to the groundwater–refilled zone leachate interaction, another as a consequence of the manure–accumulation surface site. Geochemical and geophysical methods have shown similar results for locating groundwater contamination sources, and for determining leachate generation mechanisms and flow paths.     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Thermal and rheological structures of the Xisha Trough, South China Sea

The Xisha Trough, located in the northwest of the South China Sea (SCS) mainly rifted 30 Ma ago, has been a failed rift since the cessation of the seafloor spreading of the NW subbasin. Based on the velocity–depth model along Profile OBH-4 across the Xisha Trough, a seven-layer density–depth model is used to estimate density structure for the profile. The relationship between seismic velocity and radiogenic heat production is used to estimate the vertical distribution of heat sources in the lower crust. The 2-D temperature field is calculated by applying a 2-D numerical solution of the heat conduction equation and the thermal lithosphere thickness is obtained from the basalt dry solidus (BDS). The rheology of the profile is estimated on the basis of frictional failure in the brittle regime and power-law steady-state creep in the ductile regime. Rheological model is constructed for a three-layer model involving a granitic upper crust, a quartz diorite lower crust and an olivine upper mantle. Gravity modeling supports basically the velocity–depth model. The Moho along Profile OBH-4 is of relatively high heat flow ranging from 46 to 60 mW/m² and the Moho heat flow is higher in the trough than on the flanks. The depth of the “thermal” lithospheric lower boundary is about 54 km in the center, deepens toward two sides, and is about 75 km at the northern slope area and about 70 km at the southern Xisha–Zhongsha Block. Rheological calculation indicates that the two thinnest ductile layers in the crust and the thickest brittle layer in the uppermost mantle lie in the central region, showing that the Xisha Trough has been rheologically strengthened, which are mainly due to later thermal relaxation. In addition, the strengthening in rheology during rifting was not the main factor in hampering the breakup of the Xisha Trough.     

基于GIS的区域地质调查数字制图--以1∶5万<里庄幅>为例

本文以 1∶5万里庄幅为例 ,阐述了运用GIS系统对区调过程中各种资料的处理与编辑方法 ,并介绍了数字制图方法及工艺流程 ,提出了GIS系统在 1∶5万区调工作中的应用前景     

Spatial and temporal variation of the nekton and hyperbenthos from a temperate European estuary with regulated freshwater inflow

The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary.     

Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

WEB站点安全性研究

从单密钥加密、公用密钥加密、安全散列、数字签名等网络安全技术出发，讨论了网络通讯中的信息加密、信息完整性以及客户机服务器认证等技术知识。并详细分析了SSL协议工作原理，讨论了如何利用CA数字证书签发机构和SSL协议原理在Internet/Intranet中建立Web安全站点，本文将以Windows NT和UNIX环境为例，详细介绍安全Web站点的配置步骤，充分利用SSL的强大功能，以确保通信双方的信息安全性。     

On the Acoustic-Electromagnetic Analogy for the Reflection-Refraction Problem

The same mathematical theory can be used to describe physical phenomena of different nature. For instance, the wave equation and the related mathematical developments can be used to describe elastic and electromagnetic wave propagation, and it is also extensively used in quantum mechanics. Fresnel's equations are a classical example of the analogy between shear waves and light waves. George Green in the nineteenth century, used analogies to obtain the reflection coefficients for sound waves and light waves, before the advent of the electromagnetic theory of light.In this work, we investigate the mathematical analogy between elastic waves and electromagentic waves. We obtain a complete parallelism for the reflection and refraction problem, considering the most general situation, that is, the presence of anisotropy and attenuation—viscosity in the elastic case and conductivity in the electromagnetic case. The analogy is illustrated with Fresnel's equations, the Brewster and critical angles, the concept of reflectivity and transmissivity, and the corresponding duals fields. The analysis of the elastic-solid theory of reflection applied by Green to light waves, and a brief historical review of wave propagation through the ether, further illustrate the analogy.     

黄海及其沿岸历史地震初步研究

黄海及其边缘，经历史地震资料整理，地震参数估定与编目，截至1949年8月，共有M≥3级地震2187次，其中M≥43/4级地震259次，资料显示大致有三个相对集中活跃区，16世纪曾有过历史地震活动高潮。