Effects of Volcanic Ash on Computers and Electronic Equipment

Computers and electronic equipment are an important component of the infrastructure of our modern environment. It is therefore essential that we know the effects of volcanic ash on such equipment. This paper presents the results of a pilot study to test computers and cooling fans in an ash-charged environment to assess their vulnerability. In the experiment, ash was poured on to computers and cooling fans in a sealed 0.216 m³ perspex box, with the effects on both the ash and the equipment monitored. Three different types of ash (1996 Ruapehu andesitic ash, Sakurajima andesitic ash and Kaharoa rhyolitic ash) were used in the experiments.In the first experiment each type of ash was photographed by Scanning Electron Microscope (SEM), then passed through the bearing unit of a cooling fan and photographed again afterwards. The bearings within the cooling fan continued to work even after 720 h of testing and there was no significant abrasion of the fan-shaft bearing. The ash was however fragmented, suggesting that the brittle ash shattered to fine dust, which caused significantly less abrasion to the bearings or shaft than expected. Three computers were then tested in the sealed box. Ash was introduced at increasing rates to simulate catastrophic entry of ash into a work environment, and computers were tested throughout using the BURNIN^® testing programme. Failure times ranged from 100 to 150 h; most failures occurring when humidity was increased by spraying water mist into the airflow. If dried out the computers continued to operate again if failure was not catastrophic. Card slot edge connectors proved to be one of the weakest links, as a bridge of ash formed across the gap. They were also subject to abrasion with some of the gold plating being removed. This did not however cause operating difficulties.The conclusions are that computers are more resilient than originally thought, unless the ash is moist. Simple low-tech procedures should be adequate to protect computers from small amounts of dry and moist ash contamination.     

Resolving mechanisms of toxicity while pursuing ecotoxicological relevance?

In this age of modern biology, aquatic toxicological research has pursued mechanisms of action of toxicants. This has provided potential tools for ecotoxicologic investigations. However, problems of biocomplexity and issues at higher levels of biological organization remain a challenge. In the 1980s and 1990s and continuing to a lesser extent today, organisms residing in highly contaminated field sites or exposed in the laboratory to calibrated concentrations of individual compounds were carefully analyzed for their responses to priority pollutants. Correlation of biochemical and structural analyses in cultured cells and tissues, as well as the in vivo exposures led to the production and application of biomarkers of exposure and effect and to our awareness of genotoxicity and its chronic manifestations, such as neoplasms, in wild fishes. To gain acceptance of these findings in the greater environmental toxicology community, “validation of the model” versus other, better-established often rodent models, was necessary and became a major focus. Resultant biomarkers were applied to heavily contaminated and reference field sites as part of effects assessment and with investigations following large-scale disasters such as oil spills or industrial accidents.

Over the past 15 years, in the laboratory, small aquarium fish models such as medaka (Oryzias latipes), zebrafish (Danio rerio), platyfish (Xiphophorus species), fathead minnow (Pimephales promelas), and sheepshead minnow (Cyprinodon variegatus) were increasingly used establishing mechanisms of toxicants. Today, the same organisms provide reliable information at higher levels of biological organization relevant to ecotoxicology. We review studies resolving mechanisms of toxicity and discuss ways to address biocomplexity, mixtures of contaminants, and the need to relate individual level responses to populations and communities.     

Observations of minor planets with the very large array

The weak thermal emission from the largest minor planets can be detected and measured at all points around their orbits at microwave frequencies using the Very Large Array (VLA). Position determinations of astrometric quality have been obtained, and flux measurements have provided size estimates. When enough precise positional observations have been accumulated, the orbits of the minor planets and the Earth can be determined. This will allow the equinox to be located within the radio reference frame, providing a truly fundamental coordinate system for radio source positions. It will also provide a means of relating the optical and radio (quasar) coordinate systems.The National Radio Astronomy Observatory is operated by Associated Universities, Incorporated, under contract with the National Science Foundation.     

Community preparedness for lava flows from Mauna Loa and Hualālai volcanoes,Kona, Hawai‘i

Lava flows from Mauna Loa and Huallai volcanoes are a major volcanic hazard that could impact the western portion of the island of Hawaii (e.g., Kona). The most recent eruptions of these two volcanoes to affect Kona occurred in a.d. 1950 and ca. 1800, respectively. In contrast, in eastern Hawaii, eruptions of neighboring Klauea volcano have occurred frequently since 1955, and therefore have been the focus for hazard mitigation. Official preparedness and response measures are therefore modeled on typical eruptions of Klauea.The combinations of short-lived precursory activity (e.g., volcanic tremor) at Mauna Loa, the potential for fast-moving lava flows, and the proximity of Kona communities to potential vents represent significant emergency management concerns in Kona. Less is known about past eruptions of Huallai, but similar concerns exist. Future lava flows present an increased threat to personal safety because of the short times that may be available for responding.Mitigation must address not only the specific characteristics of volcanic hazards in Kona, but also the manner in which the hazards relate to the communities likely to be affected. This paper describes the first steps in developing effective mitigation plans: measuring the current state of peoples knowledge of eruption parameters and the implications for their safety. We present results of a questionnaire survey administered to 462 high school students and adults in Kona. The rationale for this study was the long lapsed time since the last Kona eruption, and the high population growth and expansion of infrastructure over this time interval. Anticipated future growth in social and economic infrastructure in this area provides additional justification for this work.The residents of Kona have received little or no specific information about how to react to future volcanic eruptions or warnings, and short-term preparedness levels are low. Respondents appear uncertain about how to respond to threatening lava flows and overestimate the minimum time available to react, suggesting that personal risk levels are unnecessarily high. A successful volcanic warning plan in Kona must be tailored to meet the unique situation there.     

Constraints on clinopyroxene/melt partitioning of REE, Rb, Sr, Ti, Cr, Zr, and Nb during mantle melting: First insights from direct peridotite melting experiments at 1.0 GPa

Earlier piston-cylinder experiments in our laboratory produced a collection of mantle melting run products at 1.0 GPa that have now been analyzed by ion probe for selected REE, Ti, Cr, Rb, Sr, Y, Zr, and Nb. Natural starting materials were used and experiments were run in graphite-lined Pt capsules with the melt separated from the residual minerals into a layer of vitreous carbon spheres (VCS) to circumvent quench modification. The glass phase in 18 run products, representing melt percentages of ∼2-20 wt%, yielded excellent data that were inverted to yield the first estimates ever of clinopyroxene/melt distribution coefficients, Ds, derived from direct peridotite partial melting experiments. Uncertainties were estimated with a Monte Carlo method.For the REE and Y, these Ds were then compared to Ds calculated with the widely-used model of Wood and Blundy (1997) and the two sets overlap at the ±2σ level in 123 of 128 cases (∼96%). This indicates to us that: 1) the experiments analyzed here are well equilibrated with respect to major and trace element distributions, thus supporting the efficacy of the VCS technique and its variation involving diamond (e.g., Baker and Stolper, “Determining the composition of high-pressure mantle melts using diamond aggregates” [1994], Geochim. Cosmochim. Acta58, 2811-2827); 2) the model of Wood and Blundy (1997), calibrated largely on the basis of large melt fraction, inverse- or sandwich-type experiments, describes REE and Y partitioning during peridotite melting well, even very near the solidus; and it suggests that the cpx/melt Ds derived here for other elements, not modeled by the Wood and Blundy formulation, are probably also correct for peridotite melting to within their ±2σ uncertainties. D^sp/liq and D^cpx/liq values for Cr calculated directly from electron microprobe data decrease by about a factor of five with increasing temperature and melt percentage.The degree to which our experiments appear to have equilibrated seems at odds with recent measurements of the diffusivities of REE in diopside which suggest that relatively small percentages of our starting mineral grains should have equilibrated diffusively. Instead, we suggest that equilibration occurs much more rapidly through the processes of recrystallization and grain coarsening, accomplished through dissolution and reprecipitation. This suggestion is supported by the observation that our final grain sizes are typically 5-10 times larger than the ∼10 μm starting sizes, indicating that substantial mass transfer occurred in our experiments, probably mediated by the melt phase in which diffusion is faster.     

Rhinocerotid tooth enamel 18O/16O variability between 23 and 12 Ma in southwestern France

The relationship between the oxygen isotope ratio of mammal tooth enamel and that of drinking water was used to reconstruct changes in the Miocene oxygen isotope ratio of rainfall (meteoric water ${\delta }^{18}$O_MW). These, in turn, are related to climatic parameters (temperature, precipitation and evaporation rate). ${\delta }^{18}$O values of rhinocerotid teeth from the Aquitaine Basin (southwestern France) suggest a significant climatic change between 17 and 12 Ma, characterized by cooling together with precipitation increase, in agreement with other terrestrial and oceanic records. To cite this article: I. Bentaleb et al., C. R. Geoscience 338 (2006).