Observations of borehole-source amplitude reduction due to casing

Theoretical results show that the amplitude of a borehole source is reduced when the well in which it is operated is cased and cemented. This reduction is a strong function of the formation velocity and is more weakly dependent on the direction of propagation of the wave travelling from source to receiver and on the diameter of the borehole itself. We have tested these predictions with data gathered in a cross-hole seismic experiment conducted in two stages in 1990 and 1991. The source and receivers were located in the MIT/Stech 1-21A and MIT/Burch 1-20B wells at the Earth Resources Laboratory (ERL) test site in Michigan (USA). Though the source well (MIT/Stech 1-21A) was uncased in 1990, a steel casing and cement were added prior to the collection of data in 1991. Several receiver positions were reoccupied to compare data collected with the source in open and cased holes. Using a velocity model for this area and borehole diameter measurements from a calliper log, a compensation factor can be computed that will adjust the data collected in 1991 to have amplitudes comparable to that collected in the first stage of the experiment. The accuracy of the results demonstrates the validity of the theory, which can be very useful in better understanding seismic waveforms recorded in cross-hole experiments.     

Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.     

Recent Progress and Future Prospects in Solar Physics, and Their Relevance for Planet Earth

Understanding our star, the Sun, is of fundamental interest for life on Earth. In this paper, the status of knowledge in solar physics of roughly two decades ago is summarised, and the most recent developments in this very active field are shown, many of them achieved by means of space based missions. The Sun–Earth connection is described and, finally, an outlook on future solar research is given.     

An experimental study of the formation of metallic iron in chondrules

The abundance of metallic iron is highly variable in different kinds of chondrites. The precise mechanism by which metal fractionation occurred and its place in time relative to chondrule formation are unknown. As metallic iron is abundant in most Type I (FeO-poor) chondrules, determining under what conditions metal could form in chondrules is of great interest. Assuming chondrules were formed from low temperature nebular condensate, we heated an anhydrous CI-like material at 1580°C in conditions similar to those of the canonical nebula (P_H2 = 1.3 × 10⁻⁵ atm). We reproduced many of the characteristics of Type IA and IIA chondrules but none of them contained any iron metal. In these experiments FeO was abundant in charges that were heated for as long as 6 h. At a lower temperature, 1350°C, dendritic/cellular metal crystallized from Fe-FeS melts during the evaporation of S. However, the silicate portion consisted of many relict grains and vesicles, not typical of chondrules.Evaporation experiments conducted at P_H2 = 1 atm and 1565°C produced charges containing metallic iron both as melt droplets and inclusions in olivine, similar to those found in chondrules. Formation of iron in these experiments was primarily the result of desulfurization of FeS. With long heating times Fe° was lost by evaporation. Apart from some reduction of FeO by kerogen to make metal inclusions within olivine grains, reduction of FeO to make Fe° in these charges was not observed.This study shows that under canonical nebular conditions FeS and iron-metal are extremely volatile so that metal-rich Type I chondrules could not form by melting “CI.” Under these conditions FeO is lost predominantly by hydrogen stripping and, due to the relative low abundance of hydrogen at low pressures, remains in the melt for as long as 6 h. Conversely, at higher total pressures (1-atm H₂) iron metal (produced mainly by the desulfurization of troilite) is less volatile and remains in the melt for longer times (at least 6 h). In addition, due to elevated pressures of hydrogen, FeO is stripped away much faster. These results suggest that chondrule formation occurred in environments with elevated pressures relative to the canonical nebula for iron metal to be present.     

Feldspathic clast populations in polymict ureilites: Stalking the missing basalts from the ureilite parent body

Polymict ureilites DaG 164/165, DaG 319, DaG 665, and EET 83309 are regolith breccias composed mainly of monomict ureilite-like material, but containing ∼2 vol% of feldspathic components. We characterized 171 feldspathic clasts in these meteorites in terms of texture, mineralogy, and mineral compositions. Based on this characterization we identified three populations of clasts, each of which appears to represent a common igneous (generally basaltic) lithology and whose mafic minerals show a normal igneous fractionation trend of near-constant Fe/Mn ratio over a range of Fe/Mg ratios that extend to much higher values than those in monomict ureilites. The melts represented by these populations are unlikely to be impact melts, because the ubiquitous presence of carbon in polymict ureilites (the regolith of the ureilite parent body) implies that impact melts would have crystallized under conditions of carbon redox control and therefore have highly magnesian mafic mineral compositions with constant Mn/Mg ratio. Therefore, these melts appear to be indigenous products of igneous differentiation on the ureilite parent body (UPB), complementary to the olivine-pigeonite residues represented by the majority of monomict ureilites.The most abundant population is characterized by albitic plagioclase in association with pyroxenes, phosphates, ilmenite, silica, and incompatible-element enriched glass. Model calculations suggest that it formed by extensive fractional crystallization of the earliest melt(s) of precursor materials from which the most magnesian (shallowest) olivine-pigeonite ureilites formed. A less abundant population, characterized by labradoritic plagioclase, may have formed from melts complementary to more ferroan olivine-pigeonite ureilites, and derived from deeper in the UPB. The third population, characterized by the presence of olivine and augite, could only have formed from melts produced at greater depths in the UPB than the olivine-pigeonite ureilites. Many other feldspathic clasts cannot be positively associated with any of these three populations, because their mafic mineral compositions exhibit carbon redox control. However, they may be products of early crystallization of basaltic melts produced on the UPB, before carbon was exhausted by reduction.Partial melting on the ureilite parent body was a fractional (or incremental) process. Melts were produced early in UPB history, and most likely extracted rapidly, thus preserving primitive chemical and oxygen isotopic signatures in the residues.     

Viruses as potential regulators of regional brown tide blooms caused by the alga,Aureococcus anophagefferens

Blooms of the brown tide organismAureccoccus anophagefferens have recurred in the coastal bays in New Jersey since 1995 and in the coastal bays of Long Island since 1985. Intracellular viral-like particles (VLPs) were documented during 1999–2000 brown tide blooms in Little Egg Harbor, New Jersey, but it was not determined whether cells were infected during the termination of the bloom. The objective of this study was to determine if VLPs infected and lysed natural populations ofA. anophagefferens in coastal bays of New Jersey and New York in 2002 with the same frequency as in 1999–2000 and especially at the termination of the bloom. Our results confirmed that the highest percentage (37.5%) of VLP-infected cells occurred at the termination of the brown tide bloom in New Jersey in 2002. Intracellular VLPs were present throughout the bloom event. The percentage of visibly infected cells was higher at the beginning of the bloom than during the peak of the bloom. The intracellular VLPs in natural populations ofA. anophagefferens were consistent in size and shape (approximately 140 nm in diameter) and comparable to those in previous studies. Concentrated viral isolates, prepared from waters during brown tide blooms in New York and New Jersey in 2002, infected healthy laboratoryA. anophagefferens cultures in vitro. The viral isolates associated with the highest laboratory viral activity (lysis positive) were concentrated from water samples having the highest viral and bacteria concentrations. The intracellular viruses in these virally infected laboratory cultures ofA. anophagefferens were similar in size and shape to those found in natural populations. The successful isolation of a virus specific toA. anophagefferens from a brown tide bloom in the field, the similarity of ultrastructure of VLPs infecting both natural populations and laboratory infected cultures, and the pattern of VLP infection during bloom activity in combination with the observed high percentage of VLP-infected cells during bloom termination, supports, the hypothesis that viruses may be a major source of mortality for brown tide blooms in regional coastal bays of New Jersey and New York.     

A parameterisation for the threshold shear velocity to initiate deflation of dry and wet sediment

A new parameterisation for the threshold shear velocity to initiate deflation of dry and wet particles is presented. It is based on the balance of moments acting on particles at the instant of particle motion. The model hence includes a term for the aerodynamic forces, including the drag force, the lift force and the aerodynamic-moment force, and a term for the interparticle forces. The effect of gravitation is incorporated in both terms. Rather than using an implicit function for the effect of the aerodynamic forces as reported earlier in literature, a constant aerodynamic coefficient was introduced. From consideration of the van der Waals force between two particles, it was further shown that the effect of the interparticle cohesion force between two dry particles on the deflation threshold should be inversely proportional to the particle diameter squared. The interparticle force was further extended to include wet bonding forces. The latter were considered as the sum of capillary forces and adhesive forces. A model that expresses the capillary force as a function of particle diameter squared and the inverse of capillary potential was deduced from consideration of the well-known model of Fisher and the Young–Laplace equation. The adhesive force was assumed to be equal to tensile strength, and a function which is proportional to particle diameter squared and the inverse of the potential due to adhesive forces was derived. By combining the capillary-force model and the adhesive force model, the interparticle force due to wet bonding was simplified and written as a function of particle diameter squared and the inverse of matric potential. The latter was loglinearly related to the gravimetric moisture content, a relationship that is valid in the low-moisture content range that is important in the light of deflation of sediment by wind. By introducing a correction to force the relationship to converge to zero moisture content at oven dryness, the matric potential–moisture content relationship contained only one unknown model parameter, viz. moisture content at −1.5 MPa. Working out the model led to a rather simple parameterisation containing only three coefficients. Two parameters were incorporated in the term that applies to dry sediment and were determined by using experimental data as reported by Iversen and White [Sedimentology 29 (1982) 111]. The third parameter for the wet-sediment part of the model was determined from wind-tunnel experiments on prewetted sand and sandy loam aggregates. The model was validated using data from wind-tunnel experiments on the same but dry sediment, and on data obtained from simulations with the model of Chepil [Soil Sci. Soc. Am. Proc. 20 (1956) 288]. The experiments showed that soil aggregates should be treated as individual particles with a density equal to their bulk density. Furthermore, it was shown that the surface had to dry to a moisture content of about 75% of the moisture content at −1.5 MPa before deflation became sustained. The threshold shear velocities simulated with our model were found to be in good agreement with own observations and with simulations using Chepil's model.