Optimization and Parametrical Investigation to Assess the Reconstitution of Different Types of Indian Sand Using Portable Travelling Pluviator

By using the air pluviation technique, it is aimed to achieve the desired relative density with uniform void ratio throughout the specimen in order to maintain the homogeneity and to avoid the spatial variability. Further, in order to achieve the maximum deposition intensity, a systematic optimization study has been carried out rigorously in a test tank to determine the diameter of the orifice to be employed for the sieve plates of different porosity and the number of sieve plates to be installed in the diffuser sieve sets. The study has been conducted with four different patterns of sieves with different porosity to achieve a wide range of relative densities for four different uniformly graded Indian sands. The dynamic penetrometer which is considered to be one of the cost effective instruments has been efficiently used to determine the soil resistance at various locations of the test tank for every given height of fall in order to check the uniformity of placement density throughout the sand bed. The study reveals that the sand beds of different relative densities could be achieved using different patterns of diffuser sieves at optimum sand flow rate without compromising the uniformity. The effect of height of fall as well as porosity of diffuser sieves on the relative density of different sands has been studied in detail. The deposition intensity and the relative density obtained from the present study are compared with the values available in the literature.     

Electro-chemical mineralization of recalcitrant indole by platinum-coated titanium electrode: multi-response optimization,mechanistic and sludge disposal study

Indole is a highly recalcitrant aromatic heterocyclic organic compound consisting of a five-membered nitrogen-containing pyrrole ring fused to a six-membered benzene ring. This study presents the results of the electro-chemical mineralization of indole in an aqueous solution using platinum-coated titanium (Pt/Ti) electrode. A central composite design was used to investigate the effect of four parameters namely initial pH (pH_o), current density (j), conductivity (k) and treatment time (t) at 5 levels. Multiple responses namely chemical oxygen demand (COD) removal (Y ₁) and specific energy consumption (Y ₂) were simultaneously maximized and minimized, respectively, by optimizing the parameters affecting the mineralization of indole by using the desirability function approach. At the operating conditions of pH 8.6, j = 161 A/m², k = 6.7 mS/cm and t = 150 min, 83.8% COD removal with specific energy consumption of 36.3 kWh/kg of COD removed was observed. Ultra performance liquid chromatography, UV–visible spectroscopy, Fourier transform infrared spectroscopy and cyclic voltammetry of the indole solution were performed at the optimum condition of the treatment so as to report a plausible mechanism of indole degradation. Field emission scanning electron microscopy analysis of electrodes before and after treatment was performed for determining the changes on anode surface during the treatment. Thermal analysis of the solid residue (scum) obtained was also performed for exploring its disposal prospects. Present study shows that electro-chemical oxidation can be used for mineralization of nitrogenous heterocyclic compounds such as indole.     

Relationship in metastasis of coal fire and land use/cover using thermal imagery and support vector machine classifier

The objective of the present study was to delineate temporal and spatial changes in the coal fire and land use/cover within Bastacolla area of Jharia coal field. Studying this variation helped to decipher interconnection among the dynamics of the coal fire and concomitant changes in land use/cover. The detection of coal fires during a span of 14 years along with transitioning land use/cover was cost-effective and enabled planning for management of coal resources and environment. Landsat series of satellite data of 2002, 2009, 2013, and 2016 were processed for generating land surface temperature profiles vis-a-vis classified land use/cover of the study area. A single cut-off temperature was derived for mapping of coal fires using land surface temperature profile from 2002 to 2016. The satellite images were classified using support vector machines, and for depicting land use/cover change, post-classification change detection was done. Classification accuracy obtained was excellent with kappa coefficient ranging from 0.897 for classified image of 2002 to 0.799 for classified image of 2016. Results revealed that coal fires had shifted to the central west part of the area. Furthermore, pockets of coal fire from northern and eastern part of the study area have diminished. OB dumps and coal quarry/coal dump may be attributed towards the spatial change in coal fire while; OB dumps showed connotation with the highest temperature zones. Ground verifications for temperature profiles and coal fires were carried out using thermal camera which enunciated good agreement with results.     

Tectonometamorphic Evolution of Jutulsessen,Gjelsvikfjella, cDML,East Antarctica

The Jutulsessen area, can provide a vital clue to the supercontinent assembly of Gondwana Land as it is situated within the Circum East Antarctic Mobile Belt just east of the Penksockett rift marking the divide between the central Dronning Maud Land from the Western Dronning Maud Land. This landmass is dominated by migmatitic quartzo-feldspathic rocks intruded by syn to post-tectonic granites. The work highlights the data from western part cDML area with a view to arrive at a more comprehensive model for the cDML and subsequently to the super continent assembly. Granitic and migmatitic gneisses comprising of amphibolitic and biotite rich enclaves. The gneisses show variations from quartzo-felspathic gneiss to amphibolitic gneiss. The area has witnessed complex geological history involving at different deformational episodes with concomitant metamorphism. The pervasive dominant foliation trends NW-SE with shallow to medium dips towards SW. In the Stabben area, a nonfoliated intrusive syenite-gabbro pluton limits the gneissic exposures. Compositionally, the orthogneisses plot in the monzogranitegranodiorite field where as the mafic dykes/enclaves plot in the basalt-andesite-rhyodacite field. The bulk geochemical characteristics suggest significant crustal contamination. Garnet-biotite Fe-Mg exchange thermometry gives peak metamorphic temperature of 483° C for the gneisses and 628° C for the dioritic enclave within gneisses. A peak metamorphic grade of upper amphibolite to granulite facies is deduced from the mineral assemblages. Widespread anatexis has led to extensive occurrence of migmatites in the area. Recent geochronological studies assign an age of 1170 Ma to 970 Ma for the migmatites/gneisses and an emplacement age of 501 Ma for the Stabben gabbro and syenite. The discriminant plots of the Jutulsessen rocks indicate diverse origin ranging from pre-plate collision to post-collision orogenic tectonic setting. The mafic enclaves/dykes show ocean island arc to MORB affinities. Voluminous addition of juvenile crust during the Pan-African orogeny strongly overprints earlier structures.     

Calibration of AGRS System Using Transportable Pads in India: An Application to AGRS Data of Aravalli Basin,Banswada Block,South Rajasthan

Calibration of airborne gamma ray spectrometric system (AGRS) over standard radioactive sources of known elemental abundances is essential before carrying out airborne surveys. In India, fixed calibration pads were constructed in 1985. Since then calibration of AGRS system was carried out over the fixed pads. However the fixed pads are expensive to build and maintain. Also the large pads are subject to variations in radiation output due to variable moisture content and radon loss. Alternate approach is to construct transportable calibration pads which are discussed in this paper.Atomic Minerals Directorate for Exploration & Research (AMD) under Department of Atomic Energy has recently constructed five transportable calibration pads. Three pads i.e. K, U and Th have been spiked with the respective radioelements while keeping the minor radioelements to the least in order to obtain pure spectra. A composite pad has been constructed which contains all the three radioelements. This helps in cross verifying the obtained calibration results. A background pad has also been constructed which is helpful to obtain the background values during calibration.Analysis of the data acquired over the transportable pads with airborne gamma ray spectrometer (16.8 ltr) has been carried out and presented in this paper. A comparison with the data acquired over the fixed calibration pads is also included. There is a good agreement of results which suggests the use of transportable pads in future.     

Magnetic Mapping of Banded Iron Formation of Sandur Schist Belt,Dharwar Craton,India

High ground magnetic anomalies are observed at western basin of the Sandur schist belt (SSB) near Muraripura village, Karnataka. Sources for these anomalies are inferred due to presence of exposed banded iron formations hosted by metabasalts, arenaous and argillaceous rocks associated with the Donimali Formation of the schist belt. Two varieties of BIF bands are observed in the study area viz. Band 1 and Band 2. The bands 1 and 2 are displaced by lateral strike-slip fault. Band 1 is dominantly composed of banded iron formation, rich in iron ore minerals and silica chert. Band 2 is largely composed of ferruginous quartzite and quartz arenites. Qualitative analysis of the magnetic data indicates that the study area can be divided into three lithologically important BIF/BQ formations. Spectral and quantitative analysis of the magnetic data indicates, the average depth of band 1 is 70 m and band 2 is 130 m. The magnetic data results are well correlated with chemical analysis of borehole and surface rock samples data.     

Quantifying land use/land cover spatio-temporal landscape pattern dynamics from Hyperion using SVMs classifier and FRAGSTATS®

This study aims to quantify the landscape spatio-temporal dynamics including Land Use/Land Cover (LULC) changes occurred in a typical Mediterranean ecosystem of high ecological and cultural significance in central Greece covering a period of 9 years (2001–2009). Herein, we examined the synergistic operation among Hyperion hyperspectral satellite imagery with Support Vector Machines, the FRAGSTATS^® landscape spatial analysis programme and Principal Component Analysis (PCA) for this purpose. The change analysis showed that notable changes reported in the experimental region during the studied period, particularly for certain LULC classes. The analysis of accuracy indices suggested that all the three classification techniques are performing satisfactorily with overall accuracy of 86.62, 91.67 and 89.26% in years 2001, 2004 and 2009, respectively. Results evidenced the requirement for taking measures to conserve this forest-dominated natural ecosystem from human-induced pressures and/or natural hazards occurred in the area. To our knowledge, this is the first study of its kind, demonstrating the Hyperion capability in quantifying LULC changes with landscape metrics using FRAGSTATS^® programme and PCA for understanding the land surface fragmentation characteristics and their changes. The suggested approach is robust and flexible enough to be expanded further to other regions. Findings of this research can be of special importance in the context of the launch of spaceborne hyperspectral sensors that are already planned to be placed in orbit as the NASA’s HyspIRI sensor and EnMAP.     

Spatial–temporal variability and hydrologic connectivity of runoff generation areas in a North Alabama pasture—implications for phosphorus transport

This study delineated spatially and temporally variable runoff generation areas in the Sand Mountain region pasture of North Alabama under natural rainfall conditions, and demonstrated that hydrologic connectivity is important for generating hillslope response when infiltration‐excess (IE) runoff mechanism dominates. Data from six rainfall events (13·7–32·3 mm) on an intensively instrumented pasture hillslope (0·12 ha) were analysed. Analysis of data from surface runoff sensors, tipping bucket rain gauge and HS‐flume demonstrated spatial and temporal variability in runoff generation areas. Results showed that the maximum runoff generation area, which contributed to runoff at the outlet of the hillslope, varied between 67 and 100%. Furthermore, because IE was the main runoff generation mechanism on the hillslope, the data showed that as the rainfall intensity changed during a rainfall event, the runoff generation areas expanded or contracted. During rainfall events with high‐intensity short‐ to medium‐duration, 4–8% of total rainfall was converted to runoff at the outlet. Rainfall events with medium‐ to low‐intensity, medium‐duration were found less likely to generate runoff at the outlet. In situ soil hydraulic conductivity (k) was measured across the hillslope, which confirmed its effect on hydrologic connectivity of runoff generation areas. Combined surface runoff sensor and k‐interpolated data clearly showed that during a rainfall event, lower k areas generate runoff first, and then, depending on rainfall intensity, runoff at the outlet is generated by hydrologically connected areas. It was concluded that in IE‐runoff‐dominated areas, rainfall intensity and k can explain hydrologic response. The study demonstrated that only connected areas of low k values generate surface runoff during high‐intensity rainfall events. Identification of these areas would serve as an important foundation for controlling nonpoint source pollutant transport, especially phosphorus. The best management practices can be developed and implemented to reduce transport of phosphorus from these hydrologically connected areas. Copyright © 2009 John Wiley & Sons, Ltd.