Permafrost occurrence during the Last Permafrost Maximum in the Western Carpathian Mountains of Slovakia as inferred from cryogenic cave carbonate

Coarse crystalline cryogenic cave carbonate (CCC) forms during the slow freezing of standing water pools and represents indirect proof of freezing temperature in the past. The dating by U‐series of CCC deposits from nine caves in the Western Carpathians Mountains of Slovakia suggests that freezing conditions, and possible permafrost conditions, occurred during the Last Permafrost Maximum (LPM, c. 20–18 ka BP). The CCC deposits occur in caves at elevations of between 800 and 1800 m a.s.l. They point to widespread alpine permafrost, the lower limit of discontinuous/sporadic permafrost being approximately 800 m a.s.l. The thickness of permafrost probably varied between 30 and 180 m. In the Vysoké Tatry Mountains at altitudes of ～1800 m a.s.l., one occurrence of CCC suggests that subzero temperatures may have penetrated to a depth of over 285 m.     

A first approach to calculate BIOCLIM variables and climate zones for Antarctica

Theoretical and Applied Climatology - For testing the hypothesis that macroclimatological factors determine the occurrence, biodiversity, and species specificity of both symbiotic partners of...     

Chemical characteristics of PM<Subscript>10</Subscript> aerosols and airmass trajectories over Bay of Bengal and Arabian Sea during ICARB

For the first time, chemical characterization of PM₁₀ aerosols was attempted over the Bay of Bengal (BoB) and Arabian Sea (AS) during the ICARB campaign. Dominance of SO ₄ ^2? , NH ₄ ⁺ and NO ₃ ^? was noticed over both the regions which indicated the presence of ammonium sulphate and ammonium nitrate as major water soluble particles playing a very important role in the radiation budget. It was observed that all the chemical constituents had higher concentrations over Bay of Bengal as compared to Arabian Sea. Higher concentrations were observed near the Indian coast showing influence of landmass indicating that gaseous pollutants like SO₂, NH₃ and NO _x are transported over to the sea regions which consequently contribute to higher SO ₄ ^2? , NH ₄ ⁺ and NO ₃ ^? aerosols respectively. The most polluted region over BoB was 13°?19°N and 70°?90°E while it was near 11°N and 75°E over AS. Although the concentrations were higher over Bay of Bengal for all the chemical constituents of PM₁₀ aerosols, per cent non-sea salt (nss) fraction (with respect to Na) was higher over Arabian Sea. Very low Ca2+ concentration was observed at Arabian Sea which led to higher atmospheric acidity as compared to BoB. Nss SO ₄ ^2? alone contributed 48% of total water soluble fraction over BoB as well as AS. Ratios SO ₄ ^2? /NO _? ³ over both the regions (7.8 and 9 over BoB and AS respectively) were very high as compared to reported values at land sites like Allahabad (0.63) and Kanpur (0.66) which may be due to very low NO.3 over sea regions as compared to land sites. Air trajectory analysis showed four classes: (i) airmass passing through Indian land, (ii) from oceanic region, (iii) northern Arabian Sea and Middle East and (iv) African continent. The highest nss SO ₄ ^2? was observed during airmasses coming from the Indian land side while lowest concentrations were observed when the air was coming from oceanic regions. Moderate concentrations of nss SO2. 4 were observed when air was seen moving from the Middle East and African continent. The pH of rainwater was observed to be in the range of 5.9–6.5 which is lower than the values reported over land sites. Similar feature was reported over the Indian Ocean during INDOEX indicating that marine atmosphere had more free acidity than land atmosphere.     

On the origin and the spreading of the shallow Mediterranean water core in the Iberian basin

The origin and the spreading of the shallow Mediterranean water core (Ms) in the Iberian basin is discussed with a quasi-synoptic hydrographic data set enhanced by chlorofluoromethane (CFM) measurements. Its characteristic density level is found to be σ_t = 27.4. Characterized by high temperature and CFM values, Ms enters the Iberian basin in the region of Cape St Vincent between depths of 500–750 dbar. A heat anomaly of >11.8 × 10⁹ J m⁻² is chosen as the boundary between the presence of Ms and the background field. The core is found in a tongue-like shape as well as in separate isolated eddies of both cyclonic and anticyclonic circulation. Using the optimum multiparameter analysis (Tomczak and Large, 1989, Journal of Geophysical Research, 94, 16141–16149), the North Atlantic Central Water (NACW), which mixes with the Mediterranean outflow to form Ms, turned out to be in the mean 1°C warmer and 0.11 saltier than in regions with minor Mediterranean influence. This points to the Gulf of Cadiz as the origin of Ms, where the Mediterranean oufflows is in contact with NACW of the appropriate characteristics.     

Modulation of the inflow into the Caribbean Sea by North Brazil Current rings

A two-year long record from a triangular mooring array between the Lesser Antilles islands Tobago, Barbados, and St. Lucia is used to investigate the inflow into the Caribbean Sea, the amount of South Atlantic Water (SAW) carried with the inflow, and the role of North Brazil Current (NBC) rings in the observed variability. The data set consists of time series from temperature/conductivity recorders and current meters in the moorings, bottom-mounted inverted echo sounders at the Tobago and St. Lucia mooring positions, and supplementary shipboard measurements. The acoustic travel time measurements of the inverted echo sounders and the conductivity/temperature time series are used for continuous estimation of dynamic height profiles and geostrophic currents between the surface and 1000 dbar as well as the amount of SAW found at the mooring positions.The observations show a domination of intraseasonal variability between 0 and 15 Sv, superimposed on the long-term fluctuations. With time scales of one to three months, these represent the signature of the NBC rings. The baroclinic transport time series shows nine periods of increased variability, indicative of the rings interacting with the Lesser Antilles island arc; with the exception of one, these periods were associated with corresponding sea surface height anomalies. No marked seasonality was observed in the transport variability or the ring frequency.The arrival of individual rings leads to a weakening of the inflow into the Caribbean. Nevertheless, the rings carry large amounts of SAW into the area, and the immediate increase of the transport towards the end of a ring event suggests a subsequent flow of this SAW-rich water into the Caribbean. At St. Lucia, rings sometimes cause a short-term decrease of SAW content, indicative of an influx of northern hemispheric water and a blocking situation. The average transport of SAW into the Caribbean south of St. Lucia during the observations amounted to 5.5 Sv, with no significant seasonal cycle, but a small positive trend in SAW fraction as well as in transport of about 15% and 1 Sv, respectively; a corresponding trend in the baroclinic volume transport was not observed.     

Thermal expansion and decomposition of jarosite: a high-temperature neutron diffraction study

The structure of deuterated jarosite, KFe₃(SO₄)₂(OD)₆, was investigated using time-of-flight neutron diffraction up to its dehydroxylation temperature. Rietveld analysis reveals that with increasing temperature, its c dimension expands at a rate ~10 times greater than that for a. This anisotropy of thermal expansion is due to rapid increase in the thickness of the (001) sheet of [Fe(O,OH)₆] octahedra and [SO₄] tetrahedra with increasing temperature. Fitting of the measured cell volumes yields a coefficient of thermal expansion, α = α₀ + α₁ T, where α₀ = 1.01 × 10⁻⁴ K⁻¹ and α₁ = −1.15 × 10⁻⁷ K⁻². On heating, the hydrogen bonds, O1···D–O3, through which the (001) octahedral–tetrahedral sheets are held together, become weakened, as reflected by an increase in the D···O1 distance and a concomitant decrease in the O3–D distance with increasing temperature. On further heating to 575 K, jarosite starts to decompose into nanocrystalline yavapaiite and hematite (as well as water vapor), a direct result of the breaking of the hydrogen bonds that hold the jarosite structure together.     

Analysis of mobility data – A focus on Mobile Mapping Systems

ABSTRACT

The increasing availability of devices to capture the position of moving objects (and other environmental information) leads to a very large amount and variety of mobility data. In order to obtain important information about the objects, their behavior or the environment of the objects, an automatic analysis is required. This article highlights current research questions in the context of the analysis of mobility data and presents them on the basis of work carried out at the Institute of Cartography and Geoinformatics (ikg) at Leibniz University of Hannover, Germany. A focus is put on the analysis and exploitation of information from Mobile Mapping vehicles.     

On the use of anhysteretic remanent magnetization in paleointensity determination

The relative intensities of anhysteretic remanent magnetization (RAM) and thermoramanent magnetization (TRM) are strongly dependent on grain size, blocking temperature and applied field, and are poorly predicted by existing theories. Analog techniques that substitute ARM for TRM probably yield adequate relative paleointensities in suites of mineralogically similar rocks, but they yield uncertain estimates of absolute paleointensity.