Bulk organic δ13C and C/N ratios as palaeosalinity indicators within a Scottish isolation basin

Microfossils in isolation basin sediments are frequently used to reconstruct sea‐level change, but preservation problems and non‐analogue situations can limit their usefulness. Here we investigate the potential of stable carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter, as an alternative proxy of salinity within isolation basin sediments from a basin in northwest Scotland. Within the Holocene sediment δ¹³C and C/N are determined largely by the mean weighted values of the predominant source of the organic material. Analysis of modern materials and comparison with the diatom record shows that the marine parts of the sequence are dominated by high δ¹³C and variable C/N. In the fresh water sequences the organic material is a mixture of both freshwater aquatic and terrestrial plant input that have relatively low δ¹³C and high C/N. The application of δ¹³C and C/N ratios in the studied basin in general follow the environmental change recorded by the diatoms and shows the potential of bulk organic matter in the investigation of salinity change in isolation basins. Copyright © 2005 John Wiley & Sons, Ltd.     

The Qso Hosts I Zw 1 and 3C 48: Prototypes of a Merger-Driven Quasar Evolution?

I Zw 1 and 3C 48 are two neighboring template objects at a later stage of the hypothesized merger-driven evolutionary sequence from ultra-luminous infrared galaxies (ULIRGs) to quasi-stellar objects (QSOs). Since galaxy mergers are assumed to trigger the evolution, it is important to confirm the merger properties of transitionary objects. Using multi-wavelength observations and N-body simulations, the merger histories of I Zw 1 and 3C 48 have been investigated in two separate case studies. Here, the results from both studies are compared and their relevance for the evolutionary hypothesis is discussed.This research is partly based on observations with ISAAC at the Very Large Telescope (VLT) of the European Southern Observatory (ESO) under projects 67.B-0009 and 67.B-0019.     

Preliminary evaluation of the occurrence of herbicides and PAHs in the Wet Tropics region of the Great Barrier Reef, Australia, using passive samplers

The proximity of the Great Barrier Reef (GBR) Marine Park to areas of intensive agriculture and increasing urbanisation places the park under potential threat of contamination by land-based pollutants. Passive samplers were deployed at inshore reef and river mouth sites in the Wet Tropics region of the GBR during a dry and a wet season to measure levels of land-based organic pollutants in this environment. Two types of passive sampling devices were deployed: (i) a polar sampler, which can be used to monitor polar herbicides and (ii) semipermeable membrane devices (SPMDs) which sequester more hydrophobic compounds (e.g. PAHs, chlorpyrifos). Herbicides (diuron, simazine, atrazine, hexazinone and/or flumeturon) were detected at low concentrations (ng L⁻¹) at all sites sampled and in both seasons. Chlorpyrifos was not detected while PAHs were present in SPMDs at levels below limits of detection. The results show that the GBR environment does contain low levels of organic pollutants and that passive sampling provides a sensitive monitoring tool for measuring waterborne organic pollutants.     

Feeding Monsters – A Study of Active Galaxies

We present new interferometric observations of the molecular gas distribution and kinematics in the nuclei of different active galaxies at high angular resolution and high sensitivity carried out with the IRAM Plateau de Bure interferometer (PdBI). The observations cover galaxies in a redshift range of 0.03–1.4. We have so far observed five different active galaxies: NGC3718, NGC1068, HE1029–1831, 3C48 and Q0957+561. The first two objects belong to the NUGA (NUclei of GAlaxies) project – an international collaboration mainly between Spain, France and Germany – containing about 30 Seyfert and LINER galaxies. Both are at the same distance of 14Mpc and show a warped gas and dust disk. The new mosaic map of NGC3718 corrected for short-spacing effects with IRAM 30 m observations well demonstrates the existence of the warped gas disk with several secondary maxima in the projected gas distribution caused by orbit crowding effects. Based on these new data we have improved recent simulations of the warped disk in NGC3718. HE1029–1831 and 3C48 are nearby QSOs. HE1029–1831 is taken out of the Cologne nearby QSO sample. The maps of the integrated CO(1–0) and CO(2–1) emission clearly show that the molecular gas is mostly related to the central bulge with a non-negligible fraction distributed along the bar known from optical observations. Our new CO data of 3C48 unveil new information about the kinematics of its molecular gas complementing and improving further studies based on previous infrared observations and detailed multi-particle simulations. Finally, new measurements of the CO(1–0) line in Q0957+561 – a highly-red-shifted, gravitationally lensed quasar – will be presented as a link to earlier evolutionary stages of active galaxies and their hosts.     

Boosting for Mineral Prospectivity Modeling: A New GIS Toolbox

With an increasing demand for raw materials, predictive models that support successful mineral exploration targeting are of great importance. We evaluated different machine learning techniques with an emphasis on boosting algorithms and implemented them in an ArcGIS toolbox. Performance was tested on an exploration dataset from the Iberian Pyrite Belt (IPB) with respect to accuracy, performance, stability, and robustness. Boosting algorithms are ensemble methods used in supervised learning for regression and classification. They combine weak classifiers, i.e., classifiers that perform slightly better than random guessing to obtain robust classifiers. Each time a weak learner is added; the learning set is reweighted to give more importance to misclassified samples. Our test area, the IPB, is one of the oldest mining districts in the world and hosts giant volcanic-hosted massive sulfide (VMS) deposits. The spatial density of ore deposits, as well as the size and tonnage, makes the area unique, and due to the high data availability and number of known deposits, well-suited for testing machine learning algorithms. We combined several geophysical datasets, as well as layers derived from geological maps as predictors of the presence or absence of VMS deposits. Boosting algorithms such as BrownBoost and Adaboost were tested and compared to Logistic Regression (LR), Random Forests (RF) and Support Vector machines (SVM) in several experiments. We found performance results relatively similar, especially to BrownBoost, which slightly outperformed LR and SVM with respective accuracies of 0.96 compared to 0.89 and 0.93. Data augmentation by perturbing deposit location led to a 7% improvement in results. Variations in the split ratio of training and test data led to a reduction in the accuracy of the prediction result with relative stability occurring at a critical point at around 26 training samples out of 130 total samples. When lower numbers of training data were introduced accuracy dropped significantly. In comparison with other machine learning methods, Adaboost is user-friendly due to relatively short training and prediction times, the low likelihood of overfitting and the reduced number of hyperparameters for optimization. Boosting algorithms gave high predictive accuracies, making them a potential data-driven alternative for regional scale and/or brownfields mineral exploration.

     

Bacterial communities are sensitive indicators of contaminant stress

With many environments worldwide experiencing at least some degree of anthropogenic modification, there is great urgency to identify sensitive indicators of ecosystem stress. Estuarine organisms are particularly vulnerable to anthropogenic contaminants. This study presents bacterial communities as sensitive indicators of contaminant stress. Sediments were collected from multiple sites within inner and outer zones of three heavily modified and three relatively unmodified estuaries. Bacterial communities were censused using Automated Ribosomal Intergenic Spacer Analysis and analysed for a suite of metal and PAH contaminants. Shifts in both bacterial community composition and diversity showed strong associations with sediment contaminant concentrations, particularly with metals. Importantly, these changes are discernable from environmental variation inherent to highly complex estuarine environments. Moreover, variation in bacterial communities within sites was limited. This allowed for differences between sites, zones and estuaries to be explained by variables of interest such as contaminants that vary between, but not within individual sites.     

A sedimentary record of the rise and fall of the metal industry in Bergslagen,south central Sweden

Detailed stratigraphic analyses of sediments deposited in Lake Botjärnen, a small boreal forest lake in the shield terrain of central Sweden, clearly reflect progressively increasing human impact on terrestrial and aquatic ecosystems following settlement and establishment of an iron industry in the 17th century. Rising frequencies of pollen and spores from light-demanding plants provide evidence of extensive forest clearance for charcoal and timber production, which peaked in the early 20th century. An associated increase in catchment erosion is reflected by changing carbon and nitrogen elemental content and carbon–isotope composition of sediment organic matter and by increased magnetic susceptibility of the sediments. Records of air-borne pollutants (lead, zinc and sulphur) can be correlated to the development of local and regional mining and metal industry as inferred from historical accounts. Rapid recession of the iron industry led to re-forestation and recovery of the aquatic nutrient status to pre-industrial conditions over the past 100 years. The chronology of the sediment succession, which is based on ²¹⁰Pb and ¹³⁷Cs radionuclide data in combination with radiocarbon dating, is confirmed by historical lead pollution trends established for the region.     

High temperature gas–solid reactions in calc–silicate Cu–Au skarn formation; Ertsberg,Papua Province,Indonesia

The 2.7–3 Ma Ertsberg East Skarn System (Indonesia), adjacent to the giant Grasberg Porphyry Copper deposit, is part of the world’s largest system of Cu–Au skarn deposits. Published fluid inclusion and stable isotope data show that it formed through the flux of magma-derived fluid through contact metamorphosed carbonate rock sequences at temperatures well above 600° C and pressures of less than 50 MPa. Under these conditions, the fluid has very low density and the properties of a gas. Combining a range of micro-analytical techniques, high-resolution QEMSCAN mineral mapping and computer-assisted X-ray micro-tomography, an array of coupled gas–solid reactions may be identified that controlled reactive mass transfer through the ~ 1 km³ hydrothermal skarn system. Vacancy-driven mineral chemisorption reactions are identified as a new type of reactive transport process for high-temperature skarn alteration. These gas–solid reactions are maintained by the interaction of unsatisfied bonds on mineral surfaces and dipolar gas-phase reactants such as SO₂ and HCl that are continuously supplied through open fractures and intergranular diffusion. Principal reactions are (a) incongruent dissolution of almandine-grossular to andradite and anorthite (an alteration mineral not previously recognized at Ertsberg), and (b) sulfation of anorthite to anhydrite. These sulfation reactions also generate reduced sulfur with consequent co-deposition of metal sulfides. Diopside undergoes similar reactions with deposition of Fe-enriched pyroxene in crypto-veins and vein selvedges. The loss of calcium from contact metamorphic garnet to form vein anhydrite necessarily results in Fe-enrichment of wallrock, and does not require Fe-addition from a vein fluid as is commonly assumed.     

Assessment of drought over the past two millennia using near-shore sediment cores from a Canadian boreal lake

Lack of long-term studies on drought in the boreal region of northwest Ontario limits our ability to assess the vulnerability of this region to climate change. We investigated changes in diatoms, scaled chrysophytes, and sedimentary pigments in two near-shore cores from Gall Lake to infer limnological and water-level changes over the last two millennia. The two coring locations, at modern water depths of 7.5 and 11.5 m, were selected to contrast inferences for past lake level based on distance from the modern water-depth boundary between predominantly benthic and planktonic diatom assemblages in surface sediments (6.0 m). Diatom-inferred depth inferences were more variable in the core from 7.5-m water depth, consistent with the hypothesis that the greatest changes occurred at water depths closest to the benthic:planktonic boundary. Both sites revealed a pronounced drought from ~AD 950 to 1300, synchronous with the medieval climate anomaly (MCA). This finding suggests a northeast expansion of the arid MCA into northwest Ontario, extending the known spatial extent of this megadrought. Scaled chrysophytes and sedimentary pigments suggest a recent increase in thermal stratification. Our findings indicate this region is more susceptible to changes in moisture than was previously suspected based on the instrumental record for the past century.