Multi-metal contaminant dynamics in temporarily flooded soil under sulfate limitation

In many river basins, floodplain soils have accumulated a variety of metal contaminants, which might be released during periods of flooding. We investigated the dynamics of copper, cadmium, lead, zinc, and nickel in a contaminated freshwater floodplain soil under a realistic sulfate-limited flooding regime in microcosm experiments. We found that most contaminants were initially mobilized by processes driven by the reductive dissolution of Fe(III) and Mn(IV, III) (hydr)oxides. Subsequently, bacterial sulfate respiration resulted in the transformation of the entire available sulfate (2.3 mmol/kg) into chromous reducible sulfur (CRS). Cu K-edge X-ray absorption fine structure (XAFS) spectroscopy revealed that the soil Cu speciation changed from predominantly Cu(II) bound to soil organic matter (SOM) intermittently to 14% metallic Cu(0) and subsequently to 66% copper sulfide (Cu_xS). These Cu_xS precipitates accounted for most of the formed CRS, suggesting that Cu_xS was the dominant sulfide phase formed in the flooded soil. Sequential metal extractions, in agreement with CRS results, suggested that easily mobilizable Cd was completely and Pb partially sequestered in sulfide precipitates, controlling their dissolved concentrations to below detection limits. In contrast, Zn and Ni (as well as Fe) were hardly sequestered into sulfide phases, so that micromolar levels of dissolved Zn and Ni (and millimolar dissolved Fe(II)) persisted in the reduced soil. The finding that Cu, Cd, and Pb were sequestered (but hardly any Zn, Ni, and Fe) is consistent with the thermodynamically predicted sulfide ladder following the increasing solubility products of the respective metal sulfides. The observation that Cd and Pb were sequestered in sulfides despite the presence of remaining SOM-bound Cu(II) suggested that the kinetics of Cu(II) desorption, diffusion, and/or Cu_xS precipitation interfered with the sulfide ladder. We conclude that the dynamics of multiple metal contaminants are intimately coupled under sulfate limitation by the relative thermodynamic stabilities and formation kinetics of the respective metal sulfides.     

Clay minerals from the sedimentary cover from the Northwest Iberian shelf

The Northern Iberian margin is a typical example of a continental margin subjected to seasonal highly energetic regime (waves and tides) and receiving inputs of continental sediments via riverine discharges. The principal goal of this study has been to use clay minerals as indicators of sedimentary dynamics in the open shelf system. The distributions of clay mineral in the top layer of the sedimentary cover are shown to be related to their continental sources, but also reflect the influences of winter storms and longshore currents in determining the pathways of sediment transport.The mineralogical composition of the material issuing from the rivers is very similar to the general mineralogical composition of the fine fractions of the seabed sediments. Those deposits that are directly influenced by riverine discharges have higher contents of kaolinite (>20%), whereas those that are not have higher contents of illite (>80%). The available data indicate no significant quantities of terrigenous particles are being discharged from the Spanish rias. Therefore, we conclude that physical processes are controlling the clay mineral distributions and that, despite contributions from the Minho River, the main source of fine detrital particles to the shelf region is the Douro River discharge. These particles settle on the middle shelf, below the 60 m isobath. During storm events these particles are re-suspended and advected northwards to the Galician shelf or into deeper domains. Thus the distributions of the clays indicate there is a net transport of fine sediments both northwards and off-shelf.     

Correlation Between the Sunspot Number,the Total Solar Irradiance,and the Terrestrial Insolation

Our study deals with the correlations between the solar activity on the one hand and the solar irradiance above the Earth’s atmosphere and at ground level on the other. We analyzed the combined ACRIM I+II time series of the total solar irradiance (TSI), the Mauna Loa time series of terrestrial insolation data, and data of terrestrial cosmic ray fluxes. We find that the correlation between the TSI and the sunspot number is strongly non-linear. We interpret this as the net balance between brightening by faculae and darkening by sunspots where faculae dominate at low activity and sunspots dominate at high activity. Such a behavior is hitherto known from stellar analogs of the Sun in a statistical manner. We perform the same analysis for the Mauna Loa data of terrestrial insolation. Here we find that the linear relation between sunspot number and insolation shows more than 1% rise in insolation by sunspot number variations which is much stronger than for the TSI. Our conclusion is that the Earth atmosphere acts as an amplifier between space and ground, and that the amplification is probably controlled by solar activity. We suspect the cosmic rays intensity as the link between solar activity and atmospheric transparency. A Fourier analysis of the time series of insolation shows three dominant peaks: 10.5, 20.4, and 14.0 years. As a matter of fact, the cosmic rays data show the same pattern of significant peaks: 10.7, 22.4, and 14.9 years. This analogy supports our idea that the cosmic rays variation has influence on the transparency of the Earth atmosphere.     

Between coercion and consent: the politics of “Cooperative Governance” at a time of “Austerity Localism” in London

At a time of “austerity localism”, this paper explores how local authorities in London, England, are simultaneously addressing the dual pressures of delivering fiscal retrenchment and of enrolling citizens in new participatory public service arrangements, asking whether “these trends pull against one another, in opposite directions, or whether they are the tough and tender dimensions of a singular process: austerian management” Drawing on empirical research into the London Borough of Lambeth’s Cooperative Council agenda, as well as Foucauldian and Gramscian critiques of participatory network governance theories and practice, this paper shows how participatory forms of governance can be folded into the logic of hierarchy and coercion through various governmental technologies of performance and agency (consent), and through tactics of administrative domination (coercion). As budget cuts continue to affect local government in England, this paper concludes that although small experiments in participatory governance may persist, the dominant mode of governance is likely to shift towards more hierarchical and coercive forms.     

Die Protoblastese

Ohne Zusammenfassung     

Macroseepage of methane and light alkanes at the La Brea tar pits in Los Angeles

Geologic seepage of methane and light (C₂-C₅) alkanes was measured at the La Brea Tar Pits in Los Angeles. Samples were collected using flux chambers with stainless steel canisters and analyzed using gas chromatography. Average seepage rates from individual seepage sites were 970 ± 330 mg/h of methane, 14.0 ± 5.5 mg/h of ethane, 9.1 ± 3.7 mg/h of propane, 3.7 ± 1.6 mg/h of i-butane, 0.33 ± 0.16 mg/h of n-butane, 260 ± 120 μg/h of i-pentane, and 5.3 ± 1.9 μg/h of n-pentane, while maximum seepage rates exceeded 17 g/h of methane, 270 mg/h of ethane, 190 mg/h of propane, 95 mg/h of i-butane, 10 mg/h of n-butane, 7 mg/h of i-pentane, and 0.1 mg/h of n-pentane. These absolute fluxes have an additional unknown amount of error associated with them due to sampling methodology, and should be taken as the lower limit of emissions. Samples collected revealed generally dry gas, with high methane emissions relative to the light alkanes. Overall emissions from the tar pits were found to come not only from the active geologic seepage, but also from the outgassing of the standing asphalt at the site. Using the gas ratios, which are negligibly affected by errors introduced by sampling methodology, observed in this study, daily emissions of C₂ – C₅ alkanes from the La Brea area were estimated to be 4.7 ± 1.6 Mg, which represents 2–3 % of total emissions in the entire Los Angeles region.     

Remarks on the Definition and Estimation of Friction Velocity

One of the mainscaling parameters in similarity theory of the atmospheric boundary layer is friction velocity. Unfortunately, several definitions of friction velocity exist in the literature. Some authors use the component of the horizontal Reynolds stress vector in the direction of the mean wind vector to define friction velocity. Others define the friction velocity by means of the absolute value of the horizontal Reynolds stress vector. The two definitions coincide only if the direction of the mean wind vector is parallel to the horizontal Reynolds stress vector. In general, the second definition gives larger values for the friction velocity. Over complex terrain the situation is further complicated by the fact that the terrain following flow is not necessarily horizontal. Thus, several authors have proposed to use terrain following coordinate systems for the definition of friction velocity. By means of a large dataset of fast-response wind measurements with an ultrasonic anemometer the friction velocities resulting from the different definitions are compared. Furthermore, it is shown that friction velocity can be well estimated from horizontal wind speed, and even better from simple horizontal or vertical turbulence parameters.