Interactions between Cd,Cu, Pb,and Zn and four different mine soils

The chemical associations of Cd, Cu, Pb, and Zn in four mine soil samples from the Amizour-Bejaia Pb/Zn mine (Algeria) have been investigated by a five-step sequential extraction procedure. Although Cd preferentially binds to carbonates, Cu, Pb, and Zn are mainly associated with the organic and reducible fractions. Batch adsorption experiments with either mono- or multi-metallic solutions are described with the Freundlich isotherm model. Whatever the nature of the soil sample, the sorption behavior for each given metal except Pb is very similar, indicating that the binding sites at the soil surface are progressively occupied by the metal from the solution. On each soil sample, the decreasing order of sorption can be established as Pb >> Cu > Cd > Zn. When the four metals are simultaneously applied to each soil sample, their specific behavior is strongly affected by their interactions and/or competition for the available surface sites: we generally observed isotherm curves with a slight maximum before the plateau at higher solution concentration. Although Cu is only slightly affected by the other metals, in the case of Pb, Cd, and Zn, the sorbed amounts strongly decreased.     

The main characteristics, problems, and prospects for Western European coastal seas

Located to the far West of Western Europe, France has a western maritime coastal zone of more than 3800 km, which is widely influenced by the North-eastern Atlantic. The English Channel, an epi-continental shallow sea with very strong tides, runs along 650 km of the French coast and 1100 km of the English coast. It is also a bio-geographical crossroad encompassing a much wider range of ecological conditions than other European seas. France's Atlantic coast north of the Gironde estuary is a succession of rocky and sandy shorelines, including a sizeable intertidal zone, a wide continental shelf, and two major estuaries (Loire and Gironde). South of the Gironde, the 260 km of coastline is low, sandy and straight, with a narrowing continental shelf further on South due to the presence of the Cape Breton canyon in the bathyal and abyssal zones. Interface between the continental and oceanic systems, these bordering seas--North Sea, English Channel and Atlantic Ocean--have been the subject of many recent research programmes (the European Mast-FLUXMANCHE and INTERREG programmes; the national coastal environment programme and the LITEAU programme in France), designed to improve comprehension of the functions, production, and dynamics of these seas as well as their future evolution. Given the many conflicting practices in these littoral zones, integrated coastal zone management appears to be essential in order to cope with both natural phenomena, such as the infilling of estuarine zones, cliff erosion, and rising sea levels, and chronic anthropogenic pressures, such as new harbour installations (container dikes, marinas), sea aggregate extraction for human constructions, and offshore wind mill farms. This article provides as complete an overview as possible of the research projects on these bordering seas, both those that have recently been accomplished and those that are currently in progress, in order to highlight the main characteristics of these ecosystems and to underline the future challenges for European marine research in terms of the integrated coastal zone management of these highly significant coastal zones.     

Modélisation de propagation d’écoulement entre lits mineur et majeur sur les fleuves Sénégal et Niger

In the Senegal River valley and Niger Inner Delta, the annual floods inundate a wide floodplain consisting of a complex network of lakes and channels, where topographic information needed by standard hydraulic models is difficult to obtain. To represent the flood propagation between mainstream and floodplain, we use a model designed for flood propagation in river mainstreams with flat bed and large overflow and without topographic data. Depending on the water level in the riverbed, the model calibrated on the levels observed at two stations gives the level in the floodplains and propagation time between stations. Several cases are tested for various types of hydraulic connections between mainstream and floodplain. The model could correctly reproduce the flood rise and fall in the floodplain, even for a lake connected by a single channel to the riverbed or in the case of a strong attenuation of the flood between very distant stations.     

War landform mapping and classification on the Verdun battlefield (France) using airborne LiDAR and multivariate analysis

Acting as efficient earth-movers, soldiers can be viewed as significant geomorphological drivers of landscape change when replaced in the recent debates on Anthropocene Geomorphology. ‘Polemoforms’, generated by military activities, correspond with a set of human-made landforms of various sizes and geometries. They are particularly common on the World War One battlefield of Verdun (France) which ranks among the largest battles of attrition along the Western Front. The artillery bombardments and building of defensive positions in that battle significantly altered the landscape, resulting in thousands of shell craters, dugouts, and gun positions that have altered both the meso and microtopography. This paper proposes an innovative methodology to make an exhaustive inventory of these small-scale conflict-induced landforms (excluding linear features such as trenches) using a digital terrain model (DTM) acquired by airborne LiDAR on the whole battlefield. Morphometric analysis was conducted using Kohonen's self-organizing maps (SOMs) and hierarchical agglomerative clustering (HAC) in order to quantify and classify the high number of war landforms. This combined approach allowed for mapping more than one million landforms which can be classified into eight different shapes including shell craters and various soldier-made landforms (i.e. shelters, gun positions, etc.). Detection quality evaluation using field observations revealed the algorithm successfully classified 93% of shell craters and 74% of anthropologically constructed landforms. Finally, the iconographic database and map series produced will help archaeologists and foresters to better manage the historic site of Verdun, today covered by a large forest of ~10 000 ha. © 2019 John Wiley & Sons, Ltd.     

Variations in ground surface temperature histories in the Thompson Belt, Manitoba, Canada: environment and climate changes

Several temperature–depth profiles recorded at Pipe Mine, 32 km southwest of Thompson, Manitoba, in central Canada, exhibit a marked departure from the equilibrium gradient. These profiles could be interpreted as indicating strong warming (up to 4.5 K) of the ground surface during the last 200 years. All the temperature profiles at Pipe Mine show perturbations stronger than at the others sites in the Thompson Nickel Belt. Temperature profiles recorded near the town of Thompson show a moderate warming (≈1–2 K) trend, while temperature profiles at Soab, 45 km southwest of Pipe Mine, indicate very moderate cooling (≈0.5 K). There was little human activity in this part of Manitoba before the development of the mining camp of Thompson in the late 1950s. Our study shows the variability of ground surface temperature histories at a very local scale (i.e. <1 km) with much stronger signals at some of the Pipe Mine drill holes than at others. These holes are located within 500 m of the highway and a power line built after 1955, at ≈3 km from the now abandoned open pit mine. The ground surface temperature history (GSTH) obtained by the inversion of Pipe Mine temperature profiles suggests that a recent (50 years) and strong (≈1–2 K) ground surface warming is superimposed on a 1–2 K warming trend that started 200 years ago, without any indication of a cold (little ice ages) episode before. The recent warming (40 years) at Pipe Mine is only a local effect and is likely to be related to the presence of the highway. Before 1960, the ground surface temperature history for Pipe is similar to other sites in the Thompson region. Ground surface temperature histories from other profiles within and near the city of Thompson seem less affected by environmental perturbations and their trends are parallel to that of the meteorological records in the Canadian Prairies.     

Ground temperature histories in eastern and central Canada from geothermal measurements: evidence of climatic change

Inverse and direct methods have been used to analyze a large number of borehole temperature logs in order to infer past climatic changes. Results indicate a warming of 1–2°C in eastern and central Canada during the past 150 years. A period of cooling between 500 and 200 years before present, corresponding to the time of the “Little Ice Age”, has also been identified in the same areas. A regional ground temperature history is estimated for eastern and central Canada from the simultaneous inversion of several temperature logs. The inferred temperature changes appear correlated with the concentration of atmospheric carbon dioxide as reported from a Greenland ice core, and agree with existing meteorological and dendrochronological records for the area.     

An analytical electron microscopy (AEM) investigation of opaque inclusions in some type 6 ordinary chondrites

Abstract— A large number of ordinary chondrites contains micron-sized particles of metal and/or troilite dispersed in their silicate grains. Such metallic phases are responsible for the so-called darkening of the silicate grains and might be either precipitates, which formed during reduction of the silicates, or inclusions injected as a melt during a shock event. We have investigated these tiny foreign phases by analytical transmission electron microscopy in three unweathered, metamorphosed ordinary chondrites (Saint Séverin, LL6, Tsarev, L6 and Kernouvé, H6). We also looked for remnant shock indices. Our TEM observations suggest the following sequence of events in the three meteorites. First, a number of relatively strong shock events occurred on the parent body/bodies producing an Fe-FeS melt that was injected into silicate grains along a dense network of open fractures. Most of these shock defects were subsequently erased by high-temperature (700–900 °C) thermal metamorphism. Some remnants of the shock events are the observed trails of tiny metal and/or sulfide inclusions that formed as a result of fracture healing. Chemical homogenization of the silicates and limited oxidation of the metallic blebs also occurred during this high-temperature annealing event, resulting in Ni-rich inclusions. This effect was especially pronounced in the L and LL-chondrites studied. During subsequent cooling of the body/bodies, inclusions of chromite and phosphate precipitated, nucleating preferentially on lattice defects (dislocations, subgrain boundaries) and on the metal and sulfide inclusions. A later shock event of moderate intensity, probably corresponding to the separation of the meteorite from its parent body, produced new shock features in the silicate grains of the Saint Séverin meteorite, including mechanical twins in diopside and straight free screw dislocations in olivine.     

An investigation by transmission electron microscopy of planar deformation features in naturally shocked quartz

We have investigated by Transmission Electron Microscopy (TEM) the planar deformation features(PDF) in quartz from various sites where shock metamorphism has been detected optically: impact sites; the Vredefort complex (South Africa) and the K/T boundary at Raton Basin (Colorado). PDFs are straight narrow bands of glass or microtwins or huge densities of dislocations. Such contrasting microstructures must reflect different shock scenarios. In the Vredefort complex the post-shock thermal history has strongly overprinted the shock-induced defects. In the Raton Basin samples very tiny bubbles have precipitated on the dislocations, strongly suggesting a lengthy annealing at moderate pressure and temperature. This new information should be taken into account in any model of the origin of the K/T transition. In any case, observation of PDFs by optical microscopy alone is not sufficient to unambiguously conclude on their origin.