Modeling ground deformations of Panarea volcano hydrothermal/geothermal system (Aeolian Islands, Italy) from GPS data

Panarea volcano (Aeolian Islands, Italy) was considered extinct until November 3, 2002, when a submarine gas eruption began in the area of the islets of Lisca Bianca, Bottaro, Lisca Nera, Dattilo, and Panarelli, about 2.5 km east of Panarea Island. The gas eruption decreased to a state of low degassing by July 2003. Before 2002, the activity of Panarea volcano was characterized by mild degassing of hydrothermal fluid. The compositions of the 2002 gases and their isotopic signatures suggested that the emissions originated from a hydrothermal/geothermal reservoir fed by magmatic fluids. We investigate crustal deformation of Panarea volcano using the global positioning system (GPS) velocity field obtained by the combination of continuous and episodic site observations of the Panarea GPS network in the time span 1995–2007. We present a combined model of Okada sources, which explains the GPS results acquired in the area from December 2002. The kinematics of Panarea volcano show two distinct active crustal domains characterized by different styles of horizontal deformation, supported also by volcanological and structural evidence. Subsidence on order of several millimeters/year is affecting the entire Panarea volcano, and a shortening of 10⁻⁶ year⁻¹ has been estimated in the Islets area. Our model reveals that the degassing intensity and distribution are strongly influenced by geophysical-geochemical changes within the hydrothermal/geothermal system. These variations may be triggered by changes in the regional stress field as suggested by the geophysical and volcanological events which occurred in 2002 in the Southern Tyrrhenian area.     

ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.     

High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.     

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.     

The Holocene Secche di Lazzaro phreatomagmatic succession (Stromboli,Italy): evidence of pyroclastic density current origin deduced by facies analysis and AMS flow directions

The edifice of Stromboli volcano gravitationally collapsed several times during its volcanic history (>100 ka–present). The largest Holocene event occurred during the final stage of the Neostromboli activity (∼13–5 ka), and was accompanied by the emplacement of phreatomagmatic and lahar deposits, known as the Secche di Lazzaro succession. A stratigraphic and paleomagnetic study of the Secche di Lazzaro deposits allows the interpretation of the emplacement and the eruptive processes. We identify three main units within the succession that correspond to changing eruption conditions. The lower unit (UA) consists of accretionary lapilli-rich, thinly bedded, parallel- to cross-stratified ash deposits, interpreted to indicate the early stages of the eruption and emplacement of dilute pyroclastic density currents. Upward, the second unit (UB) of the deposit is more massive and the beds thicker, indicating an increase in the sedimentation rate from pyroclastic density currents. The upper unit (UC) caps the succession with thick, immediately post-eruptive lahars, which reworked ash deposited on the volcano’s slope. Flow directions obtained by Anisotropy of Magnetic Susceptibility (AMS) analysis of the basal bed of UA at the type locality suggest a provenance of pyroclastic currents from the sea. This is interpreted to be related to the initial base-surges associated with water–magma interaction that occurred immediately after the lateral collapse, which wrapped around the shoulder of the sector collapse scar. Upward in the stratigraphy (upper beds of UA and UB) paleoflow directions change and show a provenance from the summit vent, probably related to the multiple collapses of a vertical, pulsatory eruptive column.     

Volcanology,history and myths of the Lake Albano maar (Colli Albani volcano,Italy)

The polygenetic Albano maar is the most recent centre of the Colli Albani volcano, located just few kilometres to the south-east of Roma. Presently the maar hosts a 167.5 m deep crater lake, the deepest in Europe. The maar is to be considered quiescent, as phreatic activity is documented throughout the Holocene. This paper illustrates the close relationships between the activity of the maar and the history of settlement in the Roman region as recorded in the geology, archaeology, history and legends of the area. Severe fluctuations of the groundwater table and catastrophic overflows of the Lake Albano from the maar rim had occurred prior to and after the early prehistoric settlements dated in the maar area at the Eneolithic times (ca. III millennium B.C.). Repeated lahars occurred along the northwestern slope of the maar filling in the paleodrainage network and forming a vast plain. Paleohydraulic analyses on fluvial and lahar deposits originated from the Holocene phreatic activity of the Albano maar indicate sediment–water flows in excess of hundreds of cubic metres per second. Absolute age determinations of the paleosoil underlying one of the most recent deposits of the lahar succession at 5800 ± 100 yr B.P. (¹⁴C CAL) are in perfect agreement with the age of the overlying Eneolithic age settlements. The last catastrophic overflow is described in the Roman literature as a consequence of the anger of Poseidon against the Romans in 398 B.C. for their war against the Etruscans. In 394 B.C. the Romans decided to prevent the repetition of such events by the excavation through the maar crater wall of a 1.5 km long drain tunnel, which is still operational, keeping the lake 70 m below the lowest point of the maar rim. This tunnel drain may be regarded as the first prevention device for volcanic hazard in history and shows an unprecedented development of the engineering technology under the pressure of hazard perception. The surprising and still largely unknown results of this study are very important to redefine the hazard of the Roman region.     

Volcanoes and human history

The study of volcanic hazards leads inevitably to questions of how past cultures have lived in volcanically active regions of the world. Here we summarize linkages between volcanological, archaeological and anthropological studies of historic and prehistoric volcanic eruptions, with the goal of evaluating the impact of past eruptions on human populations to better prepare for future events. We use examples from papers collected in this volume to illustrate ways in which volcanological studies aid archaeological investigations by providing basic stratigraphic markers and information about the nature and timing of specific volcanic events. We then turn to archaeological perspectives, which provide physical evidence of the direct impacts of volcanic eruptions, such as site abandonment and human migration, as well as indirect impacts on local cultures as reflected in human artifacts. Finally we review anthropological studies of societal responses to past and recent volcanic eruptions. We pay particular attention to both the psychological impact of catastrophic events and records of these impacts encoded within oral traditions. Taken together these studies record drastic short-term eruption impacts but adaptation to volcanic activity over the longer term, largely through strategies of adaptive land use.     

Places of the Holocaust: Towards a model of GIS of place

Progress toward developing a GIS of place can only follow from an understanding of what place is, and this understanding draws on geographical theory. Here—following Agnew, Tuan, and others—we consider place as being made up of three components—location, locale, and sense of place—which are recognizable at multiple scales and vary historically as a product of social and political processes. Using the testimonies of two survivors of the Holocaust, we sketch the components of a model for a GIS of place that allows for this theory of place to be visualized and analyzed. The model is, crucially, both multi‐scalar and sensitive to uncertainty, as a GIS of place needs to be able to zoom in and out of the different scales at which place is experienced, as well as capture both uncertain data and uncertainty as data. We see potential in the representations proposed for scaling up from the anecdotal to the general in the sense that any narrative can be grouped and classified according to places and scales as shown here. The challenge in developing a GIS of place along the lines we propose here is to design a new set of functionalities that can do so.     

Changes of cloud microphysical properties during the transition from supercooled to mixed-phase conditions during CIME

A ground-based seeding experiment using carbon dioxide and propane sprayed from pressurized bottles was carried out under supercooled cloud conditions on a small spatial and short time scale. Water vapor deposition on the artificially generated dry ice and propane ice germs as the main ice formation process (nucleation and growth) is consistent with the experimental results. After nucleation, diffusional growth of the ice particles, partly at the expense of evaporating small droplets, was identified during the mixing of the seeding line with the ambient supercooled cloud. Within the seeding plume, ice water contents up to 80% of the total condensed water are observed, although the size of the formed ice particles did not exceed 25 μm. From the changes of the ice and supercooled liquid phase with time under mixed-phase conditions, liquid water content (LWC) evaporation, ice water content (IWC) formation, and ice crystal growth rates are estimated, which are not affected by the artificial nucleation process. Thus, these rates are assessed to be applicable for a growing ice phase of small ice particles in a young mixed-phase cloud, where other growth mechanisms, like riming or aggregation, are negligible.     

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.