The Monagas Fold-Thrust Belt of Eastern Venezuela. Part I: Structural and thermal modeling

The Eastern Venezuelan Basin (EVB) contains one of the largest hydrocarbon accumulations in the world. Main petroleum targets are buried structures of the Monagas Fold-Thrust Belt (MFTB) which forms the northeastern edge of the EVB. The objective of this study is to integrate the seismic and well data that has been acquired over the last 10 years across the MFTB and EVB, to create an updated structural model. Three regional cross sections 60-75 km long are presented across an area of 4000 km².Five structural domains are described: Amarilis, Furrial, Jusepín, Cotoperí and Pirital. They are characterized by thrusts and high-angle reverse faults. Structural style changes along strike are related to variations in depth of detachment levels and to the strike-slip component of the deformation. We have estimated a shortening between 43 and 59 km that increases eastward over a distance of 40 km.The evolution of the MFTB is divided in four episodes based on stratigraphic, structural and thermal maturity evidences: (1) Oligocene-early Miocene initial movement of Pirital thrust. (2) Early Miocene simultaneous movement on Pirital, Furrial and Cotoperí thrusts. (3) Middle Miocene increases in velocity and change in geometry of Pirital thrust, during an out of sequence period of thrusting. (4) Late Miocene to Holocene minor thrust activity. This evolution is consistent with the oblique convergence between the Caribbean and South American plates and the convergence between North and South America that affected Eastern Venezuela during the Cenozoic.By analyzing the along-strike variations in structural style, new exploratory opportunities have been identified. Under the Orocual and Santa Bárbara fields two untested duplex structures are proposed; they were developed during the middle Miocene. Other prospective hydrocarbon traps are associated to oblique transpressive faults that create anticline structures.     

The Monagas Fold-Thrust belt of Eastern Venezuela. Part II: Structural and palaeo-geographic controls on the turbidite reservoir potential of the middle Miocene foreland sequence

This paper presents a new structural-stratigraphic approach to constrain the reservoir potential of the middle Miocene turbidite systems within the Monagas Fold-Thrust Belt (MFTB) and Maturín Sub-Basin (MSB) of eastern Venezuela. In the frontal anticline structures of the MFTB (Amarilis Area) light hydrocarbons have been produced from these turbidite systems which were deposited in a foreland basin with a complex tectonostratigraphic evolution.In order to predict the location of other analogous reservoirs we used the structural model presented in Part I (Parra et al., 2010) to developed a palaeo-topographic reconstruction at early-middle Miocene. We have then used this reconstruction to constrain the palaeogeography of the middle Miocene foredeep where the turbidites were deposited. The area considered has 5000 km².By middle Miocene four regions are identified: 1) The southern basin margin dipped 1.5-2.5° north; 2) The foredeep axis had a southwest-northeast orientation. Within the foredeep the proto-structures of the MFTB created submerged highs that control the distribution of sediments; 3) The northern basin margin dipped 3-4° south; the coastline was controlled by the Pirital thrust sheet; 4) The main source of sediments was located towards the northwest on the Pirital thrust sheet and Serranía del Interior.Variations in shortening across the strike of the Pirital thrust were accommodated by a lateral ramp which controlled the location of a valley that acted as the main sediment pathway for the sediments that fed the turbidite system. This relationship between the thrust belt geomorphology and the location of turbidite sediment within the foredeep must be considered in order to assess the distribution of the Miocene turbidite reservoirs.     

Structure and dynamics of demersal fish assemblages over three decades (1985–2012) of increasing fishing pressure in Guinea

In a context of growing fishing pressures and recommendations for an ecosystem approach to fisheries, there is a need to monitor changes in fish communities over time. In this study, we analysed data from scientific trawl surveys carried out on the continental shelf off Guinea between 1985 and 2012. We performed factorial analyses and calculated biodiversity indices to characterise the changes in the structure and composition of fish communities that occurred over the 28-year period in this area, particularly given intensive fishing activities. We show that, over the study period, fish communities on the Guinean shelf were structured primarily according to spatial factors, with temporal changes being less pronounced than expected. However, a temporal analysis of biodiversity indices and species dominance showed that the intensification of fishing had significant effects on the general ecological features of the fish assemblages under study. There was a decrease in fish density and in mean trophic level. In addition, there were changes in species dominance, whereby large, slow-growing species with high commercial value were gradually replaced by smaller, fast-growing species of lesser commercial interest. These results from field observations are in line with some conclusions from previous modelling studies in the same geographical area, and provide further support for the hypothesis of a progressive ‘ecosystem effect of fishing’ occurring in Guinean waters.     

On the response of flexible risers to loads imposed by hydraulic collars

Even though hydraulic collars are largely used to install flexible risers, neither the loads imposed by this equipment nor the response of the risers to these loads have been previously studied. Hence, this paper presents a three-dimensional nonlinear finite element (FE) model to predict the response of flexible risers to loads imposed by hydraulic collars and also provides a set of equations to predict these loads. The FE model relies on an analogy between helical tendons and orthotropic shells to simulate the inner carcass and the pressure armour of flexible risers. Shell elements are used to represent the polymeric layers and three-dimensional beam elements simulate the wires of the tensile armours. Material, geometric and contact nonlinearities are addressed. Contact interactions between the layers of the riser are handled by surface to surface contact elements with a contact detection algorithm based on the pinball technique and contact forces evaluated with the augmented Lagrangian method. A 9.5″ flexible riser is analyzed and the numerical results are compared to those from the experimental tests. The agreement between all results indicates that the proposed FE model is an efficient approach to predict the response of flexible risers to loads imposed by hydraulic collars and, moreover, may be used to analyze the response of such structures to other types of loads.     

The precambrian evolution of South America

Zusammenfassung Mit Hilfe von ca. 1500 radiometrischen Zeitmessungen wird eine Synthese der prÄkambrischen Entwicklung Südamerikas aufgestellt. In Abb. 1 wird versucht, die Lage der spÄtprÄkambrischen orogenen Gürtel sowie ihre Plattformen darzustellen.Der grö\te alte Kern des Kontinents umfa\t den Guyana-Schild, das Basement des Amazonas-Sedimentbeckens und den Guaporé-Kraton im Süden, einen Raum von ungefÄhr 4,5 Mio. qkm. Die meisten Gesteine wurden von dem transamazonischen orogenen Zyklus erfa\t, dessen radiometrisches Alter etwa 2000 M. J. betrÄgt. Der etwa gleichaltrige SÃo-Francisco-Kraton in Ostbrasilien umfa\t ungefÄhr 1 Mio. qkm. Kleinere Kerne, die ebenfalls die Ereignisse des transamazonischen Zyklus' widerspiegeln, wurden nahe der Atlantikküste, östlich der Mündung des Amazonasflusses (SÃo-Luis-Kraton-Gebiet) und in der Umgebung des La-Plata-Flusses (Rio de la Plata-Kraton-Gebiet) gefunden.Die Kratone sind getrennt durch metamorphe Gürtel, die zum brasilianischen orogenen Zyklus spÄtprÄkambrischen Alters gehören. Der Caririan-Gürtel und die Sergipe-Geosynklinale liegen in der Nordostecke von Brasilien, und der Ribeira-Gürtel erstreckt sich entlang der Atlantikküste im Süden. Zwei symmetrische geosynklinale Einheiten wurden im zentralen Teil des Kontinents erkannt: der Brasilia- und der Paraguay-Araguaia-Gürtel.In den brasilianischen orogenen Gürteln treten an vielen Stellen transamazonische oder sogar Ältere Serien auf, Anzeichen für aufgearbeitetes altes Basement. Dies scheint zu zeigen, da\ die Sialkruste des südamerikanischen Kontinents vor 2000 M. J. schon eine rÄumliche Ausdehnung von mehr als 10 Mio. qkm hatte.

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A general synthesis of the precambrian evolution of South America has been made with the aid of about 1500 radiometric age determinations. In Fig. 1, the position of the late precambrian orogenic belts, as well as their platforms, is tentatively outlined.The largest ancient core of the continent includes the Guyana Shield, the basement of the Amazon sedimentary basin, and the Guaporé craton, to the south, covering an area of about 4.5 million square kilometers. Most of the rocks were affected by the Trans-Amazonian orogenic cycle, whose radiometric ages are close to 2000 m. y. The SÃo Francisco craton of similar age outcrops over an area of about one million square kilometers, in eastern Brazil. Smaller ancient nucleii, also reflecting the events of the Tranz-Amazonian cycle, were found near the Atlantic coast, east of the mouth of the Amazon river (SÃo Luis cratonic area), and surrounding the La Plata river (Rio de la Plata cratonic area).The old cratonic areas are separated from each other by metamorphic belts which belong to the Brazilian orogenic cycle of late precambrian age. The Caririan belt, and the Sergipe geosyncline, occur at the northeastern corner of Brazil, and the Ribeira belt along the Atlantic coast, to the south. Two symmetrical geosynclinal units were recognized in the central part of the continent: the Brasilia and the Paraguay-Araguaia belts.Within the areas of the Brazilian orogenic belts, in many places Trans-Amazonian or even older ages occur, indicating remobilized ancient basement. This seems to demonstrate that the sialic crust of the South American continent, 2000 m. y. ago, already exhibited an areal extent of more than 10 million square kilometers.

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Résumé Une synthèse générale de l'évolution précambrienne de l'Amérique du Sud a été faite à l'aide de 1500 déterminations d'âge radiométrique. La fig. 1 présente un essai sur la répartition des zones orogéniques du Précambrien supérieur et de leurs platesformes.Le noyau ancien du continent, qui est le plus vaste, comprend le bouclier de la Guyane, le socle du bassin sédimentaire de l'Amazone et le Craton de Guaporé, au Sud, couvrant une aire d'environ 4,5 millions de Km². La plupart des roches ont été affectées par le cycle orogénique Trans-Amazonien dont l'âge radiométrique est d'environ 2000 millions. Le craton de SÃo Francisco d'âge semblable, affleure sur une étendue d'environ 1 million de Km², dans l'Est du Brésil. Des noyaux anciens plus petits, affectés également par le cycle Trans-Amazonien, ont été trouvés près de la cÔte Atlantique, à l'Est de l'embouchure de l'Amazone (région cratonique de SÃo Luis), et aux environs du fleuve la Plata (région cratonique du Rio de la Plata).Les régions cratoniques anciennes sont séparées les unes des autres par des zones métamorphiques appartenant au cycle orogénique brésilien, d'âge Précambrien supérieur. La zone caririenne et le géosynclinal de Sergipe affleurent dans l'extrémité NE du Brésil, et la zone de Ribeira, le long de la cÔte Atlantique au S. Deux unités géosynclinales symétriques ont été reconnues dans la partie centrale du continent: les zones de Brasilia et de Paraguay-Araguaia.Dans les régions occupées par les ceintures orogéniques Brésiliennes, il existe en beaucoup d'endroits des roches d'âge Trans-Amazonien et mÊme plus ancien, indices d'un socle ancien remobilisé. Ceci semble démontrer que la croûte sialique du continent Sud Américain montrait déjà, il y a environ 2000 millions d'années, une étendue de plus de 10 millions de Km².

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1500 . . 1 , , . , Guaporé , . . 4,5 . , 2000 . Sao Francisco 1 . . , , , ( Sao Luis) la Plata ( (Rio de la Plata). , . Caririan Sergipe , Paraiba . : Brasilia Paraguay-Araguaia. , . , , , - , 10 . 2000 .

     

Effects of age on the chemical structure of paleosol humic acids and fulvic acids

Humic acids and fulvic acids were extracted from six paleosols in Southern Italy. Humic acids (HAs) constituted between 96.5 and 99.2% of the total extracts; the remaining materials consisted of fulvic acids (FAs). Radiocarbon ages of the HAs ranged from about 6,000 to close to 29,000 years B.P., δ¹³C values averaged $\text{?25.6 ± 0.3‰}$ The HAs were characterized by chemical (elemental and functional group analyses) and spectroscopic (IR, ESR, ¹³CNMR, E₄/E₆ ratios) methods. FAs were characterized by chemical methods, E₄/E₆ ratios and IR spectra.The chemical and spectroscopic analyses showed practically no differences in the chemical structure and composition of the six HAs and FAs, so that age appeared to have little effect on these parameters. The paleosols were found to be closed systems with low polysaccharide and protein contents, thus providing unfavorable substrates for microbial activity. The preservation of the humic materials in the paleosols may have been due to low biological activity and/or to retention by amorphous minerals. The HAs did not appear to be affected by temperatures higher than 170–200°C over the 23,000 year period which we observed.     

Using Ontologies for Integrated Geographic Information Systems

Today, there is a huge amount of data gathered about the Earth, not only from new spatial information systems, but also from new and more sophisticated data collection technologies. This scenario leads to a number of interesting research challenges, such as how to integrate geographic information of different kinds. The basic motivation of this paper is to introduce a GIS architecture that can enable geographic information integration in a seamless and flexible way based on its semantic value and regardless of its representation. The proposed solution is an ontology-driven geographic information system that acts as a system integrator. In this system, an ontology is a component, such as the database, cooperating to fulfill the system's objectives. By browsing through ontologies the users can be provided with information about the embedded knowledge of the system. Special emphasis is given to the case of remote sensing systems and geographic information systems. The levels of ontologies can be used to guide processes for the extraction of more general or more detailed information. The use of multiple ontologies allows the extraction of information in different stages of classification. The semantic integration of aerial images and GIS is a crucial step towards better geospatial modeling.     

Thermal expansion and phase transitions in åkermanite and gehlenite

Thermal expansion has been measured by laboratory and synchrotron X-ray powder diffraction for end-member åkermanite (ak, Ca₂MgSi₂O₇) and gehlenite (ge, Ca₂Al₂SiO₇) in the range 20–1,500 K. In ak in the range 340–390 K, there is a negative linear thermal expansion in [001] direction. This is related to the phase transition from an incommensurate modulated structure (IC) to a normal one (N). The volumetric mean thermal expansion coefficients for ak and ge, obtained with a linear fit of the experimental data in the temperature range 298–1,400 K, are respectively 32.1×10^–6 and 28.3×10^–6 K^–1 . The variation of the c/a ratio with temperature, due to different thermal expansion along the crystallographic axes, can be related to the different behaviour of the tetrahedral layers in the N and IC phases. Analysis of the variation of the superstructure peaks intensity across the phase transition confirms the tricritical behaviour of the IC/N transition in ak.     

Probabilistic inversion of Rayleigh-wave dispersion data: an application to Mt. Etna, Italy

We present a methodology for determining the elastic properties of the shallow crust from inversion of surface wave dispersion characteristics through a fully nonlinear procedure. Using volcanic tremor data recorded by a small-aperture seismic array on Mount Etna, we measured the surface waves dispersion curves with the multiple signal classification technique. The large number of measurements allows the determination of an a priori probability density function without the need of making any assumption about the uncertainties on the observations. Using this information, we successively conducted the inversion of phase velocities using a probabilistic approach. Using a wave-number integration method, we calculated the predicted dispersion function for thousands of 1-D models through a systematic grid search investigation of shear-wave velocities in individual layers. We joined this set of theoretical dispersion curves to the experimental probability density function (PDF), thus obtaining the desired structural model in terms of an a posteriori PDF of model parameters. This process allowed the representation of the objective function, showing the non-uniqueness of the solutions and providing a quantitative view of the uncertainties associated with the estimation of each parameter. We then compared the solution with the surface wave group velocities derived from diffuse noise Green’s functions calculated at pairs of widely spaced (~5–10 km) stations. In their gross features, results from the two different approaches are comparable, and are in turn consistent with the models presented in several earlier studies.