酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

沸石基储能基元的研究

以酸活化沸石为载体,十二醇为储能工质.制备沸石基储能基元,并采用X射线衍射、红外光谱和差示扫描量热等对沸石基储能基元进行表征.结果表明:储能基元在2θ=22.50时的衍射峰变强,相变储能材料十二醇和沸石栽体之间仅仅是简单的嵌合关系.储能基元的相变温度有一定的降低,并且熔融峰变宽.     

GVG采样线代表性检验

通过在实验区内设置不同类型的采样线,对GVG采样线的代表性进行检验.结果表明,高速公路和乡村道路类型的采样线对区域代表性的精度在95%以上;国道为86.726%;省道为65.447%.对于不同的缓冲区,高速公路、省道和乡村道路类型采样线,以200m缓冲区的代表性最好.而国道则以800m缓冲区的代表性最好.对于不同的作物而言,无论何种类型的采样线或者缓冲区,种植面积最大的棉花的精度是最好的.最低的是省道采样线1000m缓冲区,精度是78.146%,最好的是国道采样线800m缓冲区,精度是99.974%.除省道外,其他精度都在94.8%以上.这说明GVG采样线所获得的成数对于区域主要作物的代表性是很好的.     

山东三山岛金矿床流体包裹体特征及其地质意义

三山岛金矿床位于莱州市三山岛—仓上断裂带内,矿石主要为蚀变岩和含金石英脉2种类型。随着胶东金矿床研究的深入和三山岛金矿资源的不断减少,对三山岛金矿床的成矿作用及深部开发前景问题研究具有更重要的意义。针对上述问题,对三山岛金矿床2种类型矿石的成矿流体特征进行对比研究,认为代表成矿早—中期的蚀变岩型矿石形成于中温(均一温度为325～240℃)、低盐度(2.07%～6.88%)、低密度(0.720～0.868g/cm3)、酸碱性不均匀(pH=3.27～10.43)、以氟化物和氯化物为成矿物质载体的还原性流体;代表成矿中—晚期的含金石英脉型矿石形成于中—低温(均一温度为306～160℃)、低盐度(1.05%～9.73%)、低密度(0.739～0.962g/cm3)、碱性(pH=9.25～9.85)、以氯化物和硫化物为成矿物质载体的还原性流体。成矿流体性质的转变反映了成矿流体处于由比较封闭到比较开放的构造环境的转变期,且成矿流体早期以原生岩浆水为主,后期有变质水、大气降水以及海水的参与作用。三山岛金矿成矿深度为2.5～5km,根据目前的开采深度推算其深部还有一定的资源量可供开发。     

依托永久性建筑物建立测量标志的探讨

测量标志是国家空间地理信息的重要基础设施,针对当前永久性测量标志损坏严重的实际问题,提出依托永久性建筑物建立测量标志的概念,研究用GPS施测控制网的两种归心计算方法,导出用全站仪测图时偏心安置仪器的坐标计算公式,分析归心改正的计算精度,探讨依托永久性建筑物建立测量标志的可行性。     

Benthic nutrient fluxes in the intertidal flat within the Changjiang （Yangtze River） Estuary

In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang （Yangtze River） Estuary. Except for NH4^＋, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water （Dw） in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 （n=18）. These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification.     

Changes in nutrient uptake of phytoplankton under the interaction between sunlight and phosphate in the Changjiang （Yangtze） River Estuary

We conducted ship-board incubation experiments to investigate changes in nutrient uptake of phytoplankton under different phosphate concentrations and irradiances in the Changjiang River Estuary and its adjacent waters in China. Under 100% natural irradiance the uptake rates of phosphate, silicate, and nitrate were accelerated at high phosphate levels （1.84 μM）, while under low irradiance （about 50% natural irradiance） their uptake rates were restrained at the high but stimulated greatly at the intermediate phosphate concentrations （1.26 μM）, as the growth of phytoplankton, changes in nitrite and ammonium uptake didn＇t follow an obvious pattern. Our results also showed that there were linear relationships between nitrate, silicate and phosphate uptake at different phosphate concentrations under low and high irradiances, and the growth period of phytoplankton was prolonged both at the high phosphate concentrations under high irradiance and at the intermediate concentrations under low irradiance, suggesting that the limitation of phytoplankton growth mainly reflected changes in its growth period, and because no such environment （low irradiance and low phosphate concentrations） actually existed in a high turbidity zone, phytoplankton blooms hardly occurred there. In the absence of irradiance, denitrification occurred readily and phytoplankton was kept decreasing, which resulted in phosphate regeneration.     

<Superscript>40</Superscript>Ar-<Superscript>39</Superscript>Ar dating of lamprophyre dykes in the Baimazhai nickel deposit,Yunnan Province,China, and its geological significance

The Baimazhai nickel deposit, Yunnan Province, China, is located in the southern part of the Sanjiang （Tri-river） alkali-rich intrusive rock belt （Sanjiang ARIR）. In this paper was conducted ^40Ar-^39Ar dating of two phlogopites in lamprophyres which are, as dikes, widely distributed in the orefield, and two plateau ages were acquired, i.e., 32.46±0.62 Ma and 32.01±0.60 Ma, respectively （averaging 32.23±0.60 Ma）. The ages are obviously younger than those of the ore-hosted complex and mineralization of the Baimazhai nickel deposit. In combination with the characteristics, it is indicated that lamprophyres in the orefield and those in the Sanjiang ARIR are similar in tectonic setting, mineral assemblage and geochemistry. It is considered that lamprophyres in the orefield are the important component of the Sanjiang ARIR, and the lamprophyres and ore-hosted complex in the orefield represent the products of two times of different magmatic activity from different mantle sources. On the other hand, the age of lamprophyres in the orefield is older than that of the strike-slip shearing of the Ailaoshan-Honghe fault belt, suggesting that the strike-slip shearing of the Ailaoshan-Honghe fault belt is not the factor leading to magmatic activity of lamprophyres in the orefield, while it is more possible that magmatic activity of the Sanjiang ARIR promoted strike-slip shearing of the fault belt.     

浙江五亩山地区钨矿容矿构造及找矿方向

五亩山地区燕山期花岗岩侵入活动后,形成了高温热液裂隙石英脉型黑钨矿(白钨矿)矿床.矿化脉体多分布在区域断裂的裂隙构造中,矿化体在地表以中(或低)角度产出,向下以高角度产出,或者两者交替产出形成类似于倾斜的"阶梯"状.通过对含矿裂隙的测量和统计,确定了成矿前或成矿期的裂隙,NE向裂隙为钨矿的容矿构造,并提出了找矿方向.     

湘西沃溪钨锑金矿床成矿的独特性

沃溪钨锑金矿床位于NE向雪峰弧形构造带向北西凸出的转折部位东段,赋存于新元古界板溪群马底驿组紫红色板岩中,产在沃溪近EW向低角度拆离断层下盘沿层发育的层间剪切断裂系统,以层间石英脉型矿体为主,矿化作用在时间上和空间上具有一定的分带性和规律性.矿体沿倾向延深大于走向延长数倍至10余倍,并普遍存在侧伏延伸的规律.杂多酸络合物作为W,Sb,Au成矿组合的共同载体,使它们共同进入热液地球化学迁移,并生成钨锑金共生组合的金矿床,成为重要的成矿地球化学机制.