基于磷脂脂肪酸的热带西太平洋沉积物生源要素矿化过程探析

甄别生源要素参与的海洋沉积物矿化过程对探析生源要素的生物地球化学循环有重要的作用,矿化作用包括有氧呼吸、硝酸盐还原、铁锰异化还原及硫酸盐还原等多个过程,但如何区分这些过程一直是海洋沉积物矿化研究的难点。本研究采用气相色谱-质谱(GC-MS)联用对热带西太平洋沉积物中的磷脂脂肪酸(phospholipid fatty acid, PLFA)的组成进行了解析,并分析不同矿化过程中的主要PLFA种类及其影响因素,探究PLFA对沉积物矿化的指示作用。结果表明,PLFA总量在有氧呼吸过程中最高,而在硝酸盐还原过程中最低;且14:0、i14:0、i15:0和i19:0是有氧呼吸过程中微生物PLFA的主要组成,当其含量明显降低时可以指示沉积物矿化从有氧呼吸转变为硝酸盐还原;而10:0、17:0、20:0和22:0含量之和显著增加时则指示了硫酸盐还原过程的发生。在热带西太平洋沉积物中,总有机碳(TOC)和总有机氮(TON)含量以及间隙水NO₃-N含量是PLFA含量的重要影响因素,PLFA总量随着TOC和TON含量的减少而减少,并且TOC和TON的降解能够促进PLFA降解的发生,对PLFA组成有更直接的影响。     

四川盆地仪陇-平昌地区二叠系长兴组地震沉积学研究

为明确四川盆地仪陇-平昌地区长兴组地震相及沉积特征,运用地震岩性学和地震地貌学的综合分析技术,开展井-震结合及礁体三维识别研究,以阐明长兴组生物礁滩储集体的展布特征。研究结果表明,仪陇-平昌地区长兴组主要为四个沉积区带,开阔台地相对应平行-亚平行席状中弱断续地震相、台地边缘相对应平行-亚平行丘状或透镜状中弱地震相、台地前缘斜坡相对应前积席状弱地震相,海盆相对应平行-亚平行席状中强地震相,可细分为台缘礁、台内礁和台内滩亚相;30 Hz振幅调谐体切片揭示海盆岸线为北西向展布,25 Hz调谐体切片对于海盆线西侧的台缘带礁体和台内礁滩体反应明显;生物礁滩体的平面展布特征、发育规模受控于长兴组沉积期西南高、东北低的古地貌形态,台缘礁生长发育的有利区域为台地相带两排北西向凸起带。     

CO2 flux and seasonal variability in the turbidity maximum zone and surrounding area in the Changjiang River estuary

The turbidity maximum zone(TMZ) is one of the most important regions in an estuary.However,the high concentration of suspended material makes it difficult to measure the partial pressure of CO_2(pCO_2) in these regions.Therefore,very little data is available on the pCO_2 levels in TMZs.To relatively accurately evaluate the CO_2 flux in an example estuary,we studied the TMZ and surrounding area in the Changjiang(Yangtze) River estuary.From seasonal cruises during February,August,November 2010,and May 2012,the pCO_2 in the TMZ and surrounding area was calculated from pH and total alkalinity(TA)measured in situ,from which the CO_2 flux was calculated.Overall,the TMZ and surrounding area acted as a source of atmosphere CO_2 in February and November,and as a sink in May and August.The average FCO_2was-9,-16,5,and 5 mmol/(m~2·d) in May,August,November,and February,respectively.The TMZ's role as a source or sink of atmosphere CO_2 was quite different to the outer estuary.In the TMZ and surrounding area,suspended matter,phytoplankton,and pH were the main factors controlling the FCO_2,but here the influence of temperature,salinity,and total alkalinity on the FCO_2 was weak.Organic carbon decomposition in suspended matter was the main reason for the region acting as a CO_2 source in winter,and phytoplankton production was the main reason the region was a CO_2 sink in summer.     

兰州市大气降尘磁学特征及其环境意义

对兰州市大气降尘进行系统的环境磁学测量及分析.结果表明,兰州市大气降尘中磁性矿物总体含量较高,以假单畴磁铁矿为主,并伴有少量的磁赤铁矿、纤铁矿及赤铁矿,而且它们主要是来自人类活动产生的污染.过去研究表明,磁性矿物含量年内变化特征显著,冬季污染值高是由于供暖所致,但3月份虽然处于供暖期,它的污染值却明显低于其它供暖期,我们认为主要是兰州市特有的逆温现象:3月份贴地逆温强度低,利于污染物扩散所导致.4、5月份污染值全年最低,除了逆温层的作用以外,还与该月份频发的沙尘暴带来的低XIf值的稀释作用有关.近年来,随着污染防治工作的开展,兰州市大气污染状况有了较大改善,2010年xIf值比2007年降低了38％,证明环境磁学方法可以有效地监测城市污染.     

Geochemical Characteristics of Particulate Organic Carbon in the Kocebu Seamount Waters of the Western Pacific Ocean in Spring 2018

The study of the geochemical characteristics of the POC in the seamount area will be of great significance for further understanding the material cycle process in the seamount ecosystem. Based on a comprehensive survey of the Kocebu seamount in the Western Pacific Ocean in March, 2018, the distribution, source and composition of Particulate Organic Carbon (POC) in the seawater of the Kocebu seamount area were discussed. The results showed that the concentration of POC in the Kocebu seamount area gradually decreased with the increasing water depth, and slightly rose in the water layers near the bottom of the seamount. The average concentration of POC in each water mass was sorted from high to low in the order of North Pacific Tropic Water, North Pacific Intermediate Water and Deep Water (DW), and the concentration of POC at stations near the seamount summit was lower than that far from the seamount in the DW. There was upwelling at the water layers of 750~1 500 m above the seamount summit, causing the uplift of the 12.50 μg/L POC isoline in this region, however, no “seamount effect” was formed. The POC was mainly imported from the sea with an average POC/PON of 3.75. At the water layers of 0~300 m, only the POC/chlorophyll a (Chl a) at deep chlorophyll maximum layer was less than 200, indicating that the POC in this region was mainly in a form of life, while at the water layer of 300 m, the POC/Chl a increased sharply, indicating that the non-living POC contributed the most to the total POC.     

三维虚拟校园的设计与实现

提出了通过CCGIS5.0中VRModel模块对地物进行三维建模,利用Visual C 6.0 GeoLOD5.0控件实现交互式三维虚拟校园系统的方法,并以东北林业大学为例,实现了三维虚拟校园的设计和开发,取得了较好的实时性、交互性和良好的视觉效果.     

中太平洋海山富钴结壳中水羟锰矿的超结构

采自中太平洋海山富钴结壳主要由水羟锰矿组成,在XRD衍射图谱上,该矿物缺少(001)和(002)底面衍射,其原因是水羟锰矿包含了两种对称型的八面体层,即三斜对称和六方对称的八面体层,它们沿c轴方向无序排列。部分样品中的水羟锰矿在低角度区具有d>2.0nm的超结构衍射峰,它在实质上反映了矿物结构层的长程有序性,即两种层片的排列具有某种周期性或规律性。部分样品原先没有,但在加热后出现超结构衍射峰,可能是因为样品在空气中加热,使三斜层片中的Mn(III)被氧化成Mn(IV),从而转变为六方层片,继而改变了水羟锰矿的有序性。富钴结壳中水羟锰矿的超结构,在一定程度上反映了矿物形成环境的变化。     

胶州湾沉积物中氮的地球化学特征及其环境意义*

通过分级浸取的方法获得了胶州湾沉积物中不同形态的氮,将可转化态氮分为离子交换态(IEF-N)、弱酸浸取态 (WAEF-N)、强碱浸取态(SAEF-N)和强氧化剂浸取态(SOEF-N),讨论了其地球化学特征和控制因素,并结合²¹⁰ Pb测年计算了不同年代氮的埋藏通量。在此基础上,分析了胶州湾沉积物中氮给出的环境信息。结果表明,强氧化剂浸取态氮是胶州湾沉积物中可转化态氮主要赋存形态,NO₃-N是胶州湾沉积物中氮的优势形态,氮的含量及埋藏通量的分布受到pH、盐度、温度、生物扰动、沉积物粒度、沉积速率等多种因素的影响。受人为活动的影响,目前每年排入胶州湾的固体垃圾和污水中的悬浮颗粒物的量已超过河流来沙,成为胶州湾主要的沉积物来源。在20世纪初由于污染情况较轻,并且受人为活动的影响较小,胶州湾沉积物各形态氮的埋藏通量较低,但自从20世纪80年代开始,环胶州湾地区的工农业迅猛发展,氮的埋藏通量急剧增加,胶州湾地区的环境一度恶化,但由于近年来采取的较为得力的治污与排放措施,胶州湾的环境状况已有明显改观。     

Spatial and temporal variations in pH and total alkalinity at the beginning of the rainy season in the Changjiang Estuary, China

The results of field observation carried out in May 2003 were used to examine pH and total alkalinity behaviors in the Changjiang Estuary. It was showed that pH and total alkalinity took on clear spatial variations in values with the minima in the low salinity region. Like salinity, transect distributions of pH and total alkalinity （TA） in a downriver direction had a sharp gradient each. These gradients appeared in such a sequence that the TA gradient was earlier than salinity and pH gradients, and the salinity gradient was earlier than the pH gradient. These distribution characteristics seemed to be strongly influenced by the mixing process of freshwater and seawater, for both pH and total alkalinity had significant linear relationships with salinity and temperature. For pH, phytoplankton activities also had a significant impact upon its spatial distribution. During a period of 48 h, pH and total alkalinity changed within wide ranges for every layer of the two anchor stations, namely, Stas 13 and 20, which were located at the mixed water mass and seawater mass, respectively. For both Stas 13 and 20, pH and TA fluctuation of every layer could be very wide during a 4 h period. As a whole, the data of the two anchor stations showed that neither variations in salinity and temperature nor phytoplankton activities were the main factors strongly influencing the total alkalinity temporal variability on a small time scale. The data of Sta. 20 implied that both salinity variation and phytoplankton activities had a significant influence on pH temporal variability, but the same conclusion could not be drawn from the data of Sta. 13.     

Erratum to: Analysis of differences in nutrients chemistry in seamount seawaters in the Kocebu and M5 seamounts in Western Pacific Ocean

Journal of Oceanology and Limnology - Comprehensive surveys were conducted in the Kocebu deep seamount and the M4 shallow seamount in the Western Pacific Ocean in March 2018 and May 2019,...