Effect of biogeochemical diagenesis on sediment fabric in shallow marine carbonate sediments near the Dry Tortugas, Florida

 Shallow marine carbonate sediments near the Dry Tortugas undergo extensive biogeochemical diagenesis upon deposition, resulting in postdepositional fabric comprised of micritic aggregates of clay-sized particles, a matrix of peloidal mud, and intraparticular cementation. Freshly deposited primary skeletons, mostly Halimeda fragments, yield micritic aggregates of clay-sized particles, which then form peloidal mud fabric upon compaction. The cryptocrystalline particles produced by micritization are later replaced by high magnesian calcite. Cementation is observed in the intra-particular microenvironment. However, no inter-particular, grain-binding cement was detected throughout the gravity core samples investigated.     

Heat capacity anomalies at incommensurate-normal transition of åkermanite solid solution (Ca,Sr)2(Mg,Co, Zn,Fe)Si2O7

The heat capacity of åkermanite solid solutions was measured by a small scale adiabatic calorimeter near the incommensurate-normal (I-N) transition. The heat capacity anomalies caused by the I-N transition show the type characteristic behavior implying the presence of dynamical fluctuations. The heat capacity anomalies were observed over the whole range of the åkermanite solid solutions Ca₂Mg_1-xCo_xSi₂O₇ and Ca₂Mg_1-x-Zn_xSi₂O₂. With increase of Co or Zn atoms, the transition temperature, T_i, rises linearly from ca. 83° C to 220° C and to 130° C, respectively. In the system Ca₂CoSi₂O₇-Ca₂FeSi₂O₇ and Ca₂MgSi₂O₇-Ca₂-FeSi₂O₇ electronic microscopy revealed that the temperature of the heat capacity anomaly decreases with increasing Fe content, whereas the T_i rises. This unusual behavior is ascribed to the microdomains observed in high resolution lattice images.     

Atmospheric helium isotope ratio: Possible temporal and spatial variations

The atmospheric ³He/⁴He ratio has been considered to be constant on a global scale, because the residence time of helium is significantly longer than the mixing time in the atmosphere. However, this ratio may be decreasing with time owing to the anthropogenic release of crustal helium from oil and natural gas wells, although this observation has been disputed. Here, we present the ³He/⁴He ratios of old air trapped in historical slags in Japan and of modern surface air samples collected at various sites around the world, measured with a newly developed analytical system. In air helium extracted from metallurgical slag found at refineries in operation between AD 1603 and 1907 in Japan, we determined a mean ³He/⁴He ratio of (5106 ± 108) × 10^-5 R_HESJ (where R_HESJ is the ³He/⁴He ratio of the Helium Standard of Japan), which is consistent with the previously reported value of (5077 ± 59) × 10^-5 R_HESJ for historical slags in France and United Arab Emirates and about 4% higher than that of average modern air, (4901 ± 4) × 10^-5 R_HESJ. This result implies that the air ³He/⁴He ratio has decreased with time as expected by anthropogenic causes. Our modern surface air samples revealed that the ³He/⁴He ratio increases from north to south at a rate of (0.16 ± 0.08) × 10^-5 R_HESJ/degree of latitude, suggesting that the low ³He/⁴He ratio originates in high-latitude regions of the northern hemisphere, which is consistent with the fact that most fossil fuel is extracted and consumed in the northern hemisphere.     

Timing of remanent magnetization acquisition in red beds: A case study from a syn-folding sedimentary basin

We propose to explain the origin of the double trend in seismicity of the Macas swarm in the Subandean Cordillera of Cutucú (Ecuador) and characterize the corresponding active deformation of that region. For that purpose, seismological and geological data have been used, with the deployment of a temporary seismological array, with geological field observations and image processing. We found that some earthquakes are aligned on a well known NNE–SSW trend corresponding to the orientation of the nodal planes of the reverse focal mechanism of the M_w=7.0 1995 Macas earthquake as for its aftershocks. Nevertheless, many smaller events are aligned on an unexpected NNW–SSE trend inside the Cutucú Cordillera. We interpret these two orientations of the Macas swarm as linked to Subandean basement thrusts inherited from the inversion tectonics of a NNE–SSW trending Triassic–Jurassic rift, which has been uplifted and partly extruded in the Cutucú Cordillera. The present partitioning of this part of the Subandean deformation is controlled by pre-existing NNE–SSW to NNW–SSE Triassic–Jurassic normal faults that have been subsequently compressed–transpressed and reactivated into reverse faults. Major boundary faults of the rift were NNE–SSW oriented and correspond now to some main Subandean thrusts as confirms the focal mechanism of the 1995 main shock located on the eastern border (Morona frontal thrust) and the orientation of its aftershocks. In the Cutucú Cordillera, the double orientation of present swarm can be interpreted as the result of accommodation of deformation along NNW–SSE pre-existing faults inside the inverted rift system, linked to the motion of the Morona frontal NNE–SSW thrust.     

Peat depth as a control on Sphagnum moisture stress during seasonal drought

Peatlands are globally important long-term sinks of carbon, however there is concern that enhanced peat decomposition and moss moisture stress due to climate change mediated drought will reduce moss productivity making these ecosystems vulnerable to carbon loss and associated long-term degradation. Peatlands are resilient to summer drought moss stress because of negative ecohydrological feedbacks that generally maintain a wet peat surface, but where feedbacks may be contingent on peat depth. We tested this ‘survival of the deepest’ hypothesis by examining water table (WT) position, near-surface moisture content, and soil water tension in peatlands that differ in size, peat depth, and catchment area during a summer drought. All shallow sites (<40 cm depth) lost their WT (i.e., the groundwater well was dry) for considerable time during the drought period. Near-surface soil water tension increased dramatically at shallow sites following WT loss, increasing ~5–7.5× greater at shallow sites compared to deep sites (≥40 cm depth). During a mid-summer drought intensive field survey, we found that 60–67% of plots at shallow sites exceeded a 100 mb tension threshold used to infer moss water stress. Unlike the shallow sites, tension typically did not exceed this 100 mb threshold at the deep sites. Using species dependent water content – chlorophyll fluorescence thresholds and relations between volumetric water content and WT depth, Monte Carlo simulations suggest that moss had nearly twice the likelihood of being stressed at shallow sites (0.38 ± 0.24) compared to deep sites (0.22 ± 0.18). This study provides evidence that mosses in shallow peatland may be particularly vulnerable to warmer and drier climates in the future, but where species composition may play an important role. We argue that a critical ‘threshold’ peat depth specific for different hydrogeological and hydroclimatic regions can be used to assess what peatlands are especially vulnerable to climate change mediated drought.     

Propagating tsunami wave and subsequent resonant response signals detected by HF radar in the Kii Channel,Japan

Signals from the tsunami waves induced by the March 11, 2011 moment magnitude (M_w) 9.0 Tohoku-Oki earthquake and from subsequent resonances were detected as radial velocity variability by a high-frequency ocean surface radar (HF radar) installed on the eastern coast of the Kii Channel, at a range of about 1000 km from the epicenter along the eastern to southern coasts of Honshu Island. A time–distance diagram of band-passed (9–200 min) radial velocity along the beam reveals that the tsunami waves propagated from the continental shelf slope to the inner channel as progressive waves for the first three waves, and then natural oscillations were excited by the waves; and that the direction of the tsunami wave propagation and the axis of the natural oscillations differed from that of the radar beam. In addition, spectral analyses of the radial velocities and sea surface heights obtained in the channel and on the continental shelf slope suggest complex natural oscillation modes excited by the tsunami waves.     

The effect of long-term soil irrigation by wastewater on organic matter, polycyclic aromatic hydrocarbons, and heavy metals evolution: case study of Zaouit Sousse (Tunisia)

Irrigation by treated wastewater (TWW) can pollute the soil by different organic and inorganic compounds. The pollution level can depend on the irrigation period, soil nature, and wastewater characteristics. Since 1989, the Zaouit Sousse area (central Tunisian) has been irrigated by treated wastewater. The irrigation period and the mineralogy of soil composition change from one locality to another in Zaouit Sousse area. In this work, we are interested in organic compounds, polycyclic aromatic hydrocarbons (PAHs), and heavy metals (HMs) evolution. One control soil (S1) and four irrigated areas soil (S2, S3, S4, and S5) were chosen. The soil samples differ by the irrigation period and soil characteristics. Total PAHs content in control soil was 66.2 ng?g^?1 and in irrigated areas were between 46.23 and 129.51 ng?g^?1. The PAHs content in irrigated soil, except S5 which has been irrigated with wastewater for 20 years and contains the highest clay fraction percent, decreased with the irrigation period (from 0 to 20 years). The microbial degradation may decrease the PAHs concentrations in the soil thanks to bacterium brought by TWW and the important soil permeability. Concentration of heavy metals ranged from 24 to 1,320 μg?L^?1. The HMs (Cu, Cr, Zn, Fe, Ni, Pb, and Cd) contents decreased with the irrigation period (from 10 to 20 years). So, following the PAHs aerobic bio-degradation, this organic compound discharges their absorbed heavy metals which leached to deeper levels. The Cr, Cu, Al, Zn, and Cd mobility depend on the clay yield too. However, the PAHs and Pb mobility are also related to humic substance quantities. Cr and Cu have affinities both to clay and humic substance quantities.