Influence of climate, mineralogy and mineral processing on the weathering behaviour within two, low-sulfide, high-carbonate, gold mine tailings in the Eastern Desert of Egypt

Despite its importance within environmental management strategies, little concern is shown to sulfide oxidation and/or hardpan formation at neutral pH where dry condition prevails. Two gold mine tailings in Egypt, El Sid and Barramiya, were studied for their geochemical/mineralogical properties, and climate influence on hardpan formation. The tailings are characterised by homogeneous silt-sized sediments (>42%), have high carbonate, predominantly as calcite for El Sid and dolomite-ankerite for Barramiya, and low-sulfide contents, chiefly as pyrite, galena and sphalerite for El Sid, and arsenopyrite–pyrite for Barramiya. El Sid is characterised by high average concentrations of Pb (2,758 mg/Kg) and Zn (2,314 mg/Kg), its lower part dominated by mafics, overlaid by granitoids. Barramiya has higher As (average 2,836 mg/Kg) content and represents a mixture of mica-schists/mafics-ultramafics. During field investigations, no hardpans were identified, only bassanite and gypsum were found at the surface of El Sid tailings, forming thin layers and desiccation crack fillings. Column experiments showed a thin crust consisting of gypsum, halite and sodium sulfate formed at the top of the column of El Sid tailings after 2 weeks, this was not recognized in the column from Barramiya. The homogenous thickened tailings deposition in both areas did not favour hardpan formation, since the critical amounts of reacting sulfides were never achieved in individual lamina, due to missing mineral/grain size fractionation. The high-temperature/low-water availability, characteristic for desert climate regions did not allow significant sulfides oxidation. Therefore, both tailings will suffer from continuous erosion and spreading out of contaminants to the environment for a prolonged period of time by sporadic flash floods.     

Turbulence-particle interactions under surface gravity waves

The dispersion and transport of single inertial particles through an oscillatory turbulent aquatic environment are examined numerically by a Lagrangian particle tracking model using a series of idealised test cases. The turbulent mixing is incorporated into the Lagrangian model by the means of a stochastic scheme in which the inhomogeneous turbulent quantities are governed by a one-dimensional k- ε turbulence closure scheme. This vertical mixing model is further modified to include the effects of surface gravity waves including Coriolis-Stokes forcing, wave breaking, and Langmuir circulations. To simplify the complex interactions between the deterministic and the stochastic phases of flow, we assume a time-invariant turbulent flow field and exclude the hydrodynamic biases due to the effects of ambient mean current. The numerical results show that the inertial particles acquire perturbed oscillations traced out as time-varying sinking/rising orbits in the vicinity of the sea surface under linear and cnoidal waves and acquire a non-looping single arc superimposed with the high-frequency fluctuations beneath the nonlinear solitary waves. Furthermore, we briefly summarise some recipes through the course of this paper on the implementation of the stochastic particle tracking models to realistically describe the drift and suspension of inertial particles throughout the water column.     

A novel approach to estimate the variations in stresses and fault state due to depletion of reservoirs

Geomechanical changes may occur in reservoirs due to production from reservoirs. Study of these changes has an important role in upcoming operations. Frictional equilibrium is one of the items that should be determined during the depletion as it may vary with respect to time. Pre-existing faults and fractures will slide in regions where there is no frictional equilibrium. Hence, it may be concluded that reduction in pore pressure can initiate the sliding of faults. Whereas, it is also possible that faults will not exist after a certain time as production recovers the equilibrium. Casing shearing or lost circulation may be occurred due to faulting. In reservoirs which depletion leads to frictional equilibrium, decrease of fractures and faults leads to some variations in permeability. Hence, predicting the effect of depletion on frictional equilibrium is required in dealing with casing shearing or lost circulation in drilling of new wells. In addition, permeability modeling will be more precise during the life of reservoirs. Estimation of necessary time to create or vanish faults is vital to be successful in production from wells or drilling new wells. Achieving or loosing of equilibrium mainly depends on in situ stresses and rate of production. Estimation of the in situ stresses at the initiation state of reservoir is the key to study the state of faults. The next step is to predict the effects of depletion on in situ stresses. Different models are suggested in which decrease of horizontal stresses is predicted as function of pore pressure variation. In these models, different assumptions are made such as simplifying the poroelastic theory, ignoring the passing time, and considering the geometry of reservoir. In this article, a new model is proposed based on theory of inclusions and boundary element method. This state-of-the-art model considers the geometry of reservoir. In addition, changes of in situ are obtained as a function of time to reach to a more precise model capable of applying during the reservoir life. Finally, the model is imposed on real cases. The effect of depletion on faults is studied in reservoirs of normal and strike-slip stress regimes, and conventional and proposed models are compared. For this aim, in the first step, mechanical earth models of these two reservoirs are built using logging and coring data. Stress polygon method and poroelastic horizontal strain model are used for strike-slip and normal regimes, respectively. In reservoir 1 which is in a strike-slip stress regime, a fault is distinguished in formation microimaging (FMI) log. For this reservoir, the required time to achieve to frictional equilibrium is calculated. In the reservoir 2, the potential depth of fault sliding is analyzed and required time for faulting in that depth is predicted. The predicted time for satisfaction of frictional equilibrium using the proposed model has a significant difference with the predicted time using the previous methods. In addition, the proposed model predicts that different parts of reservoir 2 are willing for faulting during depletion. The previous model determines only one point that faulting may happen. It is necessary to use this new model to consider different important factors such as geometry and time to gain more accurate predictions.     

Trace Elements in Sediments and Mussels – Spatial Distribution,Chemical Partitioning,and Risk Assessment

Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay.     

Algal community and pollution indicators for the assessment of water quality of Ismailia canal,Egypt

Stochastic Environmental Research and Risk Assessment - The phytoplankton community structure is affected by both ecological and spatial factors. Influences of these two factors on phytoplankton...     

Multi scenario seismic hazard assessment for Egypt

Egypt is located in the northeastern corner of Africa within a sensitive seismotectonic location. Earthquakes are concentrated along the active tectonic boundaries of African, Eurasian, and Arabian plates. The study area is characterized by northward increasing sediment thickness leading to more damage to structures in the north due to multiple reflections of seismic waves. Unfortunately, man-made constructions in Egypt were not designed to resist earthquake ground motions. So, it is important to evaluate the seismic hazard to reduce social and economic losses and preserve lives. The probabilistic seismic hazard assessment is used to evaluate the hazard using alternative seismotectonic models within a logic tree framework. Alternate seismotectonic models, magnitude-frequency relations, and various indigenous attenuation relationships were amended within a logic tree formulation to compute and develop the regional exposure on a set of hazard maps. Hazard contour maps are constructed for peak ground acceleration as well as 0.1-, 0.2-, 0.5-, 1-, and 2-s spectral periods for 100 and 475 years return periods for ground motion on rock. The results illustrate that Egypt is characterized by very low to high seismic activity grading from the west to the eastern part of the country. The uniform hazard spectra are estimated at some important cities distributed allover Egypt. The deaggregation of seismic hazard is estimated at some cities to identify the scenario events that contribute to a selected seismic hazard level. The results of this study can be used in seismic microzonation, risk mitigation, and earthquake engineering purposes.     

Time-dependent seismic hazard analysis for the Greater Tehran and surrounding areas

This study presents a time-dependent approach for seismic hazard in Tehran and surrounding areas. Hazard is evaluated by combining background seismic activity, and larger earthquakes may emanate from fault segments. Using available historical and paleoseismological data or empirical relation, the recurrence time and maximum magnitude of characteristic earthquakes for the major faults have been explored. The Brownian passage time (BPT) distribution has been used to calculate equivalent fictitious seismicity rate for major faults in the region. To include ground motion uncertainty, a logic tree and five ground motion prediction equations have been selected based on their applicability in the region. Finally, hazard maps have been presented.     

Chemometric Differentiation of Oil Families and Their Potential Source Rocks in the Gulf of Suez

Natural Resources Research - An oil–oil and oil–source rock correlation study was carried out using chemometric methods applied to geochemical data for 123 Upper Cretaceous—Lower...     

Investigation of hydraulics transport time scales within the Arvand River estuary,Iran

Transport time scales are key parameters for understanding the hydrodynamic and biochemical processes within estuaries. In this study, the flushing and residence times within the Arvand River estuary have been estimated using a two‐dimensional hydrodynamic model called CE‐QUAL‐W2. The model has been calibrated and verified by two different sets of field data and using the k‐ε vertical eddy diffusivity scheme. Flushing time has been estimated using different methods such as the tidal prism and fraction of freshwater methods. Moreover, residence times have been investigated using pulse residence time, estuarine residence time and remnant function approaches. The results have shown that different methods yield different time scales, and freshwater inflow has the greatest impact upon estimation of residence time, whereas tidal circulation hardly contributes to residence time at all. It has also been shown that the neap‐spring circulation and start phase of simulations have negligible effects on the Arvand's time scales. The investigation of bathymetry showed that two sills of the estuary tend to significantly increase residence time. Understanding the applicability of these time scales and their estimation approaches helps us to evaluate the water quality management of estuaries. Copyright © 2013 John Wiley & Sons, Ltd.