稀土矿床：基本特点与全球分布规律

本文介绍了全球稀土资源供需历史、现状和对未来的展望。从矿床成因视角切入，将稀土矿床分为内生和外生两大类型，其中内生稀土矿床包括碳酸岩型、碱性岩型、碱性岩型- 碳酸岩型、氧化铁铜金型、热液脉型，外生稀土矿床包括风化壳离子吸附型、沉积岩型、沉积矿产(煤矿、铝土矿和沉积磷矿)伴生型、砂矿和现代海洋底部含稀土的锰结核、结壳和软泥型。归纳总结了主要类型矿床的基本特点和时空分布；认为内生稀土矿床产出于四类构造环境，包括裂谷环境、碰撞后伸展环境、大陆碰撞环境和后俯冲伸展环境；从构造演化入手，探讨了在外生与内生地质过程中稀土元素的迁移和富集规律，建立了涵盖主要矿床类型的构造- 成矿模型。     

陕南勉略宁地区黑木林- 硖口驿新元古代镁铁质岩锆石U- Pb年代学、地球化学特征及其构造意义

对于扬子板块西北缘新元古代早—中期（835~720 Ma）岩浆岩形成的构造背景尚存在较大争议。本文对陕南勉略宁地区碧口微地块内黑木林- 硖口驿SSZ型（俯冲带上盘型）蛇绿混杂岩中的辉长岩、辉长闪长岩和变安山质玄武岩分别进行了锆石LA- ICP- MS U- Pb年代学、岩石学及岩石地球化学研究。研究结果表明，木瓜园辉长岩和变安山质玄武岩属岛弧拉斑玄武岩系列，稀土元素球粒陨石标准化配分曲线均呈右倾型，具有微弱的Eu负异常，微量元素原始地幔标准化图解显示其富集大离子亲石元素（LILE）和轻稀土元素（LREE）而亏损高场强元素（HFSE，如Nb、Ta等），与岛弧岩浆岩相似。黑木林、硖口驿辉长闪长岩属钙碱性系列。黑木林辉长闪长岩具与Bonin弧前玻安质岩石类似的地球化学特征，具较高的SiO2含量（54. 27%~56. 79%）、MgO含量（11. 10%~17. 04%）和较低的TiO2含量（0. 08%~0. 19%），富集大离子亲石元素Rb、Th、U和Pb，亏损高场强元素Nb、Ti，以及弱的Zr、Hf正异常等特征。硖口驿辉长闪长岩MgO含量较低（4. 24%~8. 91%），略低于玻安质岩石，其N- MORB（正常洋中脊玄武岩）标准化微量元素蜘蛛网图与Bonin弧前玻安岩类似，富集LILE、亏损HFSE，具低的Ti/Zr比值等特征，属于过渡类型的类玻安质岩石。锆石LA- ICP- MS U- Pb测年结果显示，黑木林- 硖口驿SSZ型蛇绿混杂岩的原岩形成时代为835~830左右。其中木瓜园辉长岩、黑木林和硖口驿辉长闪长岩的结晶年龄分别为835±4 Ma、830±2 Ma和830±11 Ma。结合前人关于扬子板块西北缘新元古代早—中期构造演化过程的研究，认为扬子板块西北缘在新元古代早—中期（950~720 Ma）处于长期的洋壳东南向俯冲的活动大陆边缘环境并发育俯冲增生造山作用，且新元古代早期（835~830 Ma）在扬子板块西北缘发生了洋内俯冲，形成黑木林- 硖口驿SSZ型蛇绿混杂岩，最终增生拼贴就位于碧口微地块。     

南海北部陆缘新生代玄武岩地球化学特征及成因

南海盆地及周缘地区新生代玄武岩对揭示南海盆地的演化历史至关重要，然而这些玄武岩的成因还存在争议。本文研究了位于南海北部陆缘的海南岛临高县多文组玄武岩岩石地球化学和矿物地球化学特征，并探讨其成因和构造背景。多文组玄武岩主要由橄榄石、单斜辉石、斜长石、斜方辉石、铬尖晶石和铁钛氧化物等组成。橄榄石Fo值变化于55. 5~71. 1之间，Ni的含量较低， Fe/Mn比值较高。铬尖晶石Cr#值为74. 1~82. 7，Mg#值为45. 5~63. 8， Ti的含量较高。斜方辉石Mg#值为63. 9~79. 6，单斜辉石为66. 0~80. 6。单斜辉石稀土配分曲线富集MREE，亏损LREE和HREE，呈拱形分布。斜长石以中- 拉长石为主(Ab36. 56~52. 78), 富集LREE、Ba、Sr和Eu。铁钛氧化物的TiO2含量为50. 19%~51. 46%。多文组玄武岩原始岩浆的主量和微量元素组成与夏威夷、峨眉山、塔里木等玄武岩组成一致，地幔源区包含了辉石岩的成分，而且其地幔潜在温度(＞1400℃)和氧逸度(ΔNNO)要高于大洋中脊玄武岩(N- MORB)，表明多文组玄武岩的形成与海南地幔柱活动有关。由于海南地幔柱形成时代明显晚于南海盆地的扩张时代，认为南海地幔柱是南海盆地伸展的被动响应。     

近海核电厂核素地下水释放通量的模型计算方法

为了定量计算陵区近海核电站排水管线泄漏情景下核素通过地下水途径向海洋环境的释放通量，以某近海核电站为例进行研究。首先，应用GOCAD软件建立三维地形地质模型，刻画地层的分布、剥蚀以及倾向等特点；然后，运用地下水数值模拟软件FEFLOW精细刻画丘陵区地下水系统的补给、径流和排泄特征；最后，以不被吸附滞留的核素³H和被吸附滞留的核素⁹⁰Sr、¹³⁷Cs为对象，通过实验测定了⁹⁰Sr、¹³⁷Cs在不同岩土介质中的分配系数，模拟计算了排水管线连续渗漏60 a后³H、⁹⁰Sr、¹³⁷Cs在地下水中的放射性分布及释放。结果表明：³H迁移速度基本与地下水流速一致，地下水中的最大放射性浓度为0.285 0 Bq/L，第20 000天时向收纳水域的释放通量达到最大值，约526 Bq/d；⁹⁰Sr吸附性能相对较弱，最大迁移距离约80 m，地下水中的最大放射性浓度为0.032 1 Bq/L；¹³⁷Cs吸附能力较强，相当长的时间内被滞留在管线附近，地下水中最大放射性浓度分别为6.840×10^-3 Bq/L，释放通量为0 Bq/d。由弥散度的不确定分析可知，弥散度越大，地下水中³H的最大放射性浓度越小，向海洋环境的释放通量越多。     

秦岭南缘勉略带构造属性及晚古生代地质背景:来自碎屑锆石U-Pb年代学的制约

勉略构造带作为秦岭造山带内重要的构造边界,关于其构造属性及晚古生代以来的地质背景,一直是学术界争论的焦点。碎屑锆石U-Pb年代学在限定地层单元的最大沉积年龄、研究区域构造岩浆事件及约束构造地质背景等方面行之有效。基于此,通过对勉略带内五郎坪北侧两河口变沉积地层和侵入其中的变形花岗岩脉体进行LA-ICP-MS锆石U-Pb年代学研究。获得2件变形花岗岩脉的结晶年龄均为406±1Ma。碎屑锆石主年龄谱分别为422～456Ma和558～826Ma,峰值年龄为441Ma和771Ma、813Ma,次级年龄谱分别为942～1495Ma和1658～2981Ma,峰值年龄不明显。依据最小一组碎屑锆石的峰值年龄(441Ma),和侵入其中的变形花岗岩脉(406±0.6Ma),限定该变沉积地层形成时代为406～441Ma(S_1-D_1)。碎屑锆石年龄谱显示该套变沉积地层物质来源较为复杂,其中秦岭造山带及扬子板块北缘早古生代、新元古代岩浆岩为其提供了74%±的物源,古老变质基底为其提供了26%±的物源。通过与区域上已有资料对比,认为勉略构造带内晚古生代沉积地层形成环境与邻区大致相同,且本次所获得的变沉积岩碎屑锆石年龄谱也与邻区泥盆系相似。综合认为,勉略构造带与邻区在晚古生代应属同一构造环境,晚古生代"勉略海盆"应当包括整个南秦岭。     

Flux determination over a smooth surface under strongly unstable conditions

Careful micrometeorological measurements on an empty parking lot allowed determination of the surface fluxes of sensible heatH and of momentum by applying profile equations derived from Monin-Obukhov similarity theory with two sets of the stability correction function for momentum _m and sensible heat _h . These fluxes were compared with reference values ofH independently determined by means of an eddy correlation technique. In general, better agreement was found betweenH values derived from profiles with the stability functions of Brutsaert (1992) and referenceH values, than when the Businger-Dyer functions were used to deriveH. The disagreement in the latter comparison was especially serious under strongly unstable conditions, with the value ofy=–z/L (wherez is the height andL is the Obukhov length) larger than 10. A closer look at the procedure for calculatingH from the profiles revealed that the large differences between theH values derived with these two different versions of the stability correction functions were caused by the small differences of the _h values, and not by the larger differences of the _m values. This result stems from the strong sensitivity of the resultingH values on the choice of _h .     

地震前水氡短临异常判别指标及预报三要素的方法探讨

本文分析了中国大陆(重点是南北地震带北段)水氧异常变化,深入研究了有震与无震异常的时空分布特征、异常总频次、起始异常时间差等,发现有震异常往往呈现“同步性”或“群体性”特征,而大部分“零散性”异常则属于非地震异常。根据上述研究,本文还提出了利用水氡异常预报地震的发震时间、地点和震级的初步方法。     

Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.     

库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

Influence of sedimentary environments on mechanical properties of clastic rocks

The sedimentary environments are the intrinsic factor controlling the mechanical properties of clastic rocks. Examining the relationship between rock sedimentary environments and rock mechanical properties gives a better understanding of rock deformation and failure mechanisms. In this study, more than 55 samples in coal measures were taken from seven different lithologic formations in eastern China. Using the optical microscope the sedimentary characteristics, such as components of clastic rocks and sizes of clastic grains were quantitatively tested and analyzed. The corresponding mechanical parameters were tested using the servo-controlled testing system. Different lithologic attributes in the sedimentary rocks sampled different stress–strain behaviors and failure characteristics under different confining pressures, mainly due to different compositions and textures. Results demonstrate that clastic rocks have the linear best-fit for Mohr-Coulomb failure criterion. The elastic moduli in clastic rocks are highly dependent upon confining pressures, unlike hard rocks. The envelope lines of the mechanical properties versus the contents of quartz, detritus of the grain diameter of more than 0.03 mm, and grain size in clastic rocks are given. The compressive strength or elastic modulus and the grain diameter have a non-monotonic relation and demonstrate the “grain-diameter softening” effect.