Concentration of polychlorinated biphenyls (PCBs) in beached resin pellets: variability among individual particles and regional differences

Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater.     

Process of slip-surface development and formation of slip-surface clay in landslides in Tertiary volcanic rocks, Japan

Once landslide movement has been initiated, the sliding mass tends to move toward a more stable position. However, landslides that have occurred in some Tertiary volcanic rocks in Japan show recurrent movement. A possible reason for this behavior is that the mineral composition and properties of slip-surface materials results in better ‘lubrication’ along the slip surface as movement continues. In order to determine the causes, five landslides in Japanese Tertiary volcanics with different movement histories were studied. Based on geological investigation, the results presented in this paper were obtained by studying the development process and formation of slip surfaces and clays in landslides in these volcanics.

For rocks of similar types and mineralogies the clay content of slip-surface materials can be directly related to the displacement and history of slide movement. This study indicates that the type of slip surface ranges from: (1) striation type (showing only striations on bedrock without clay), to (2) brecciated type (clayey breccia), (3) mylonite type (clay with breccia), and to (4) clay type (clay without breccia). If the slip surface occurs in tuff or tuffaceous materials and is subjected to increasing slide movement, the smectite content in the slip-surface clay increases, while the silicate mineral content decreases. Furthermore, the smectite content is observed to increase within the same landslide from the head to the toe portion of the landslide (direction of groundwater flow). The groundwater along the slip surface (above the impervious zone) contains an increased concentration of Ca⁺⁺ ions. As the concentration of HCO₃⁻ ions exceeds 40 mg/l, an environment is created that promotes the formation of smectite. This process indicates that there is an active ion exchange within the groundwater near the slip surface that forms smectite. Thus, the formation of smectite in the slip surface requires the presence of tuff and a sufficient concentration of HCO₃⁻ ions in the groundwater.

The study results presented here indicate that frictional resistance decreases as clay content increases. The reason for repeated movement of Japanese landslides in Tertiary tuffs or tuffaceous rocks at or in the immediate vicinity of the slip surface is attributed to: (1) an increase in clay materials along the slip surface as the slide movement is repeated and (2) the presence of groundwater that promotes the formation of smectite. As is commonly known, smectite is one of the clay minerals that has lowest frictional resistance.     

Building Damage and Casualties after an Earthquake

The relationship between building damage patterns and human casualties in Nishinomiya City – one of the most heavily damaged cities in the 1995 Hanshin-Awaji Earthquake Disaster – was investigated using photographs of damaged buildings. First, the photographs of buildings in which casualties occurred were identified, and the building damage patterns were judged based on the photographs considering the existence of survival space. Then the relationship between the building damage pattern and casualty occurrence, and the characteristics of casualty distribution, were investigated. The main findings were as follows: Most casualties occurred in relatively old two-story wooden buildings in which the ground floor completely collapsed without survival space; casualties occurred at all building damage levels including ``no damage', and it can be seen that building damage is the major, but not the sole cause, of casualties in an earthquake; in Nishinomiya City, the regional distributions of casualties due to the collapse of buildings that left no survival space is similar to that of casualties due to other types of building damage.     

Broad-band power-law spectra of well-log data in Japan

For the purpose of revealing the statistical characteristics of P -wave velocity, S -wave velocity and density in the uppermost part of the crust, we analysed well-log data obtained from five deep wells in different tectonic regions in Japan: three wells through the mainly sedimentary rocks in the Kanto plain and two wells in the Kuju volcano group in Kyushu Island. In the Kanto plain, the power spectral density of fractional fluctuation of P -wave velocity and that of density are proportional to a power of the spatial wavelength from a few metres to 100 m. where the power index (slope of the power spectral density at double logarithmic scale) is 1.1-1.3. At the Kuju volcano group, that of P - and S -wave velocity and density also obey a power law, with a power index of 1.3-1.6 for wavelengths from a few metres to few hundred metres. Correcting the effect of the moving box-car observation window which corresponds to the separation of two receivers of the logging tool, we find that the power-law characteristics hold for wavelengths down to a few tens of centimetres. The 1-D sections of the elastic inhomogeneities follow a kind of band-limited self-affine random process. Comparing the power spectral densities, we find smaller values of the power index in stable areas and larger values in tectonically active areas. The difference in the power index arises from long-wavelength components.     

Gram Stain Index (GSI) of Bacterial and Archaeal Cells in the Natural Microbial Communities of Slightly and Extremely Saline Environments

The use of GSI (Gram Stain Index) was studied for natural microbial cells in slightly and extremely saline environments. The GSI spectra of archaeal cells in an extremely saline environment showed unique profiles, different from those of Bacteria. These profiles can be applied for structural analysis of the microbial communities in aquatic environments.     

Hydrographic structure of the Kuroshio large meander-cold water mass region down to the deeper layers of the ocean

The hydrographic structure of the region of large meander of the Kuroshio and the large cold water mass, which were formed in 1975, was observed down to the ocean bottom, during three cruises of the R/VHakuho Maru in September 1975, September 1976, and December 1977. The analysis of observed data indicates the following common features: the horizontal gradient of the specific volume anomaly exists down to a 3,500 db surface, corresponding to the existence of baroclinic geostrophic current down to this depth. These facts demonstrate that the current of the Kuroshio is not confined to the upper layer during periods of existence of the large meander. On a T-S diagram, the Kuroshio water and the water in the large cold water mass can be discriminated down to a 5°C surface, but there is evidence of mixing due to conspicuous interleaving between the two water masses, near the thermocline. Below the thermocline, water types defined by points on the T-S diagram can be traced from a deeper level in the Kuroshio water to a shallower level in the cold water mass, indicating that in the deeper layers the Kuroshio water continues to be uplifted toward the center of the cold water mass. The same inference is also obtained from the distribution of dissolved oxygen.     

The chemistry of sublimates collected directly from lava fountains at Kilauea Volcano,Hawaii

During 1970, it was occasionally feasible to collect sublimate from directly above the lava fountain in the crater of Mauna Ulu on the east rift zone of Kilauea Volcano, when the level of the lava pool had dropped within the crater. Collecting equipment was suspended down the steep wall to a position above the fountain. Collections were made on quartz wool held within open-ended quartz tubes and, for silica detection, on stainless steel wool in a stainless steel tube. The main components in the sublimate were, in order of decreasing concentration for the best sample, Na, Ca, Al, Fe, Mg, K, B, Si, Ti, Zn, H⁺, NH₄⁺, Cu, Ni in the form of sulfates, chlorides and fluorides.In order to investigate the forms in which the sublimate ions occur under different conditions of temperature and oxidation, the equilibrium compositions of the compounds most likely to be present were calculated. This was done for those important components for which thermodynamic data are available, using a computer program to calculate the minimum free energy for the mixture. The results indicate that, for primary conditions of high temperature and low oxygen partial pressure, the halides were the most likely form of the metallic compounds. Particulate sulfates appear under increasing oxidizing conditions caused by the access of air. These conclusions were reinforced by collections made from holes drilled through the thin crust of a lava lake formed during the same eruption.