Depositional processes of impactites from the YAX-1 drill core in the Chicxulub impact structure inferred from vertical profiles of PDF orientations and grain size distributions of shocked quartz

Core samples from the Chicxulub impact structure provide insights into the formation processes of a shallow-marine-target, complex crater. Although previous studies investigated the impactites (generally suevitic and polymict breccias) of the Yaxcopoil-1 (YAX-1) drill core in the Chicxulub impact structure, the interpretation of its deposition remains controversial. Here, we analyze planar deformation features (PDFs), grain size, and abundance of shocked quartz throughout the YAX-1 impactite sequence (794–895 m in depth). PDF orientations of most quartz grains in YAX-1 impactites show a distribution of both low angles ({104}, {103}, {102}) and high angles (orientations higher than 55° to c-axis), while the lower part of the impactite sequence contains quartz showing only PDF orientations of low angles. High-abundance, coarse-grained shocked quartz is found from the lower to middle parts of the impactites, whereas it abruptly changes to low-abundance, fine-grained shocked quartz within the upper part. In the uppermost part of the impactites, repeated oscillations in contents of these two components are observed. PDF orientation pattern suggests most of the shocked quartz grains experienced a range of shock pressure, except two samples in the lower part of impactites, which experienced only a high level of shock. We suggest that the base and lower part of the impactite sequence were formed by ejecta curtain and melt surge deposits, respectively. Our results are also consistent with the interpretation that the middle part of the impactite sequence is fallback ejecta from the impact plume. Additionally, we support the contention that massive seawater resurges into the crater occurred during the deposition of the upper and uppermost part of the impactites.     

The role of Fischer-Tropsch catalysis in the origin of methane-rich Titan

Fischer-Tropsch catalysis, which converts CO and H₂ into CH₄ on the surface of iron catalyst, has been proposed to produce the CH₄ on Titan during its formation process in a circum-planetary subnebula. However, Fischer-Tropsch reaction rate under the conditions of subnebula have not been measured quantitatively yet. In this study, we conduct laboratory experiments to determine CH₄ formation rate and also conduct theoretical calculation of clathrate formation to clarify the significance of Fischer-Tropsch catalysis in a subnebula. Our experimental result indicates that the range of conditions where Fischer-Tropsch catalysis proceeds efficiently is narrow (T∼500-600 K) in a subnebula because the catalysts are poisoned at temperatures above 600 K under the condition of subnebula (i.e., H₂/CO = 1000). This suggests that an entire subnebula may not become rich in CH₄ but rather that only limited region of a subnebula may enriched in CH₄ (i.e., CH₄-rich band formation). Our experimental result also suggests that both CO and CO₂ are converted into CH₄ within time significantly shorter than the lifetime of the solar nebula at the optimal temperatures around 550 K. The calculation result of clathration shows that CO₂-rich satellitesimals are formed in the catalytically inactive outer region of subnebula. In the catalytically active inner region, CH₄-rich satellitesimals are formed. The resulting CH₄-rich satellitesimals formed in this region play an important role in the origin of CH₄ on Titan. When our experimental data are applied to a high-pressure model for subnebula evolution, it would predict that there should be CO₂ underneath the Iapetus subsurface and no thick CO₂ ice layer on Titan's icy crust. Such surface and subsurface composition, which may be observed by Cassini-Huygens mission, would provide crucial information on the origin of icy satellites.     

Heat extraction through a geothermal reservoir on an oblique fault plane

The heat extraction through a geothermal reservoir on an oblique fault plane in the earth's crust is considered. The fault could be modelled mechanically as a frictional contact interface of two elastic bodies. The heat is recovered by circulating fluid through the reservoir, and then the surface of the reservoir is cooled by the fluid. The analysis is based on the two-dimensional theory of quasi-static thermoelasticity. It is concluded from numerical calculations that a geothermal reservoir can be created on an oblique fault plane, and the opened region, i.e. the fluid-filled region, increases gradually with time during the heat extraction. Also discussed are the effects of the fluid pressure and the coefficient of friction on the behaviour of the reservoir.     

The role of organic haze in Titan's atmospheric chemistry: I. Laboratory investigation on heterogeneous reaction of atomic hydrogen with Titan tholin

In Titan's atmosphere consisting of N₂ and CH₄, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N₂ and CH₄ gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×¹⁰⁻³×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry.     

Simulation of eutrophication and associated occurrence of hypoxic and anoxic condition in a coastal bay in Japan

A probabilistic method of calculating the occurrence of oxygen-depleted water within a combined hydrothermal and water quality model was presented in this paper to investigate the environmental impact of eutrophication on the living resources. The method was applied to an eutrophicated shallow coastal bay in western Japan, where the occurrence of red tides at the water surface and the onset of bottom hypoxic waters are observed every summer. Both meteorology and freshwater inflow contribute to the development of stratification of the bay, thus limiting the dissolved oxygen supply to bottom waters. The resulting hydrodynamics enhances the development of oxygen-depleted bottom waters by transporting organic matter produced by algal blooms to the inner bay, where it decomposes and exerts high SOD. During August, about 60% of the inner bay is hypoxic for prolonged durations and as a result most of the benthic biota and fish die. The method used here is a very useful and informative way to evaluate the spatial and temporal damage and severity caused by hypoxia on living resources. Moreover, the model results agreed very well with the observed hydrodynamics, thermal structure and water quality data of the stratified bay. The model can be used for other lakes and bays where knowledge of temperature and density stratification is important for assessing water quality.     

Phase relationships in the system KAlSiO4-Mg2SiO4-SiO2-H2O as a model for hybridization between hydrous siliceous melts and peridotite

The system KAlSiO₄-Mg₂SiO₄-SiO₂-H₂O includes model representatives of (1) hydrous siliceous magma from subducted oceanic crust — the eutectic liquid in KAlSi₃O₈-SiO₂-H₂O, and (2) the overlying mantle peridotite — the assemblage forsterite+enstatite (Fo+En). In a series of partly schematic isobaric isothermal sections, the products of hybridization between the model materials at pressures between 20 and 30 kbar have been determined. The liquid dissolves peridotite components with little change in composition. Hybridization is not a simple mixing process, because of the incongruent melting of peridotitic assemblages with phlogopite (Ph). Hybridization causes solidification of the liquid, with products a sequence of three mineral assemblages: Ph, Ph+quartz (Qz), and Ph+En. The products represent an absolute geochemical separation and local concentration of all potassium from the liquid. Hybridization is accompanied by H₂O-saturation of melts, and evolution of aqueous fluid. Although there are significant differences between the melt composition and that of the magma rising from subducted oceanic slab, and between Fo+En and the mantle rock, extrapolation of the results suggests that the conclusions can probably be extended to mantle conditions with sodium in the melt, and jadeitic clinopyroxene included in the hybrid products.     

Shock-induced transformations in the system NaAlSiO4—SiO2: a new interpretation

New internally consistent interpretations of the phases represented by the high pressure phase shock wave data for an albite-rich rock, Jadeite, and nepheline in the system NaAlSiO₄-SiO₂, are obtained using the results of static high pressure investigations, and the recent discovery of the hollandite phase in a shocked meteorite. We conclude that nepheline transforms directly to the calcium ferrite structure, whereas albite transforms possibly to the hollandite structure. Shock Hugoniots for the other plagioclase and alkali feldspars also indicate that these transform to hollandite structures. The pressure-volume data at high pressure could alternatively represent the compression of an amorphous phase. Moreover, the shock Hugoniot data are expected to reflect the properties of the melt above shock stresses of 60–80 GPa. The third order Birch-Murnaghan equation of state parameters are: K_os=275±38 GPa and K_os=1.6±1.5 for the calcium ferrite type NaAlSiO₄, K_os=186±33 GPA and K_os=2.6±1.7 for the albite-rich hollandite, K_os=236±45 GPa and K_os=2.3±2.0 for the orthoclase-rich hollandite, and K_os=190 to 210 GPa and K_os2.2 for the anorthite-rich hollandite.     

Influence of Kuroshio Flow on the Horizontal Distribution of North Pacific Intermediate Water in the Shikoku Basin

The influence of the Kuroshio flow on the horizontal distribution of North Pacific Intermediate Water (NPIW) in the Shikoku Basin is examined based upon observational data collected by the training vessel “Seisui-maru” of Mie University together with oceanographic data compiled by the Japan Oceanographic Data Center (JODC). Although it has been stated that the NPIW with salinity less than 34.2 psu had been confined to the south of the Kuroshio main axis along the PT (KJ) Line on the eastern side of the Izu Ridge, a similar tendency can be detected on the western side of the Izu Ridge. Namely, the NPIW on the southern side of the Kuroshio main axis in the Shihoku Basin does not indicate a tendency to go northward across the Kuroshio main axis without an increase in salinity of more than 34.2 psu. However, the JODC data show that less saline water (<34.2 psu) was present on the northern side of the Kuroshio main axis south of the Kii Peninsula in May 1992. Satellite observed sea surface temperature (SST) data suggested that the Kuroshio approaches the Kii Peninsula after forming a small meander off Kyushu and some intrusions of the NPIW into the northern coastal side of the Kuroshio main axis occurred in this period. It is concluded that intrusion of the NPIW with salinity less than 34.2 psu to the northern coastal side through the Kuroshio main axis occurred during the decay period of the small meander path in May 1992. Based on these observational results, the source of the salinity minimum water on the northern coastal side of the Kuroshio main axis is discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Hydrographic structure of the Kuroshio large meander-cold water mass region down to the deeper layers of the ocean

The hydrographic structure of the region of large meander of the Kuroshio and the large cold water mass, which were formed in 1975, was observed down to the ocean bottom, during three cruises of the R/VHakuho Maru in September 1975, September 1976, and December 1977. The analysis of observed data indicates the following common features: the horizontal gradient of the specific volume anomaly exists down to a 3,500 db surface, corresponding to the existence of baroclinic geostrophic current down to this depth. These facts demonstrate that the current of the Kuroshio is not confined to the upper layer during periods of existence of the large meander. On a T-S diagram, the Kuroshio water and the water in the large cold water mass can be discriminated down to a 5°C surface, but there is evidence of mixing due to conspicuous interleaving between the two water masses, near the thermocline. Below the thermocline, water types defined by points on the T-S diagram can be traced from a deeper level in the Kuroshio water to a shallower level in the cold water mass, indicating that in the deeper layers the Kuroshio water continues to be uplifted toward the center of the cold water mass. The same inference is also obtained from the distribution of dissolved oxygen.