Particulate Thiol Peptides Along a Salinity Gradient of a Metal-Contaminated Estuary

The thiol peptide phytochelatins (PC2; the polymer with n = 2) are efficient metal-chelating compounds produced by phytoplankton and higher plants. Both PC2 and their precursor glutathione (GSH) are related to detoxification mechanisms. GSH and PC2 were quantified using liquid chromatography with fluorescent detection and observed in the particulate phase along a salinity gradient of the Tamar Estuary (SW UK), a heavily metal impacted site, at concentrations up to 274 and 16.5 μmol (g chl a)⁻¹, respectively. The peptides predominated within low (0–5) and mid-salinities (5–20). Down-estuary, at sites farther from metal sources and salinities higher than 20, PC2 showed a sharp decrease or were not detected. High PC2/GSH ratios indicated areas with augmented concentrations of bioavailable metals at the tidal limit, near Cu mines and the mid-estuary where resuspension of sediments occurs. By following typical partitioning patterns previously reported for dissolved Cu and Zn, the production of thiol peptides, notably PC2, reflected a rapid interaction between the particulate and dissolved phases.     

Potential of submarine-cave sediments and oxygen isotope composition of cavernicolous micro-bivalve as a late Holocene paleoenvironmental record

A sediment layer (43 cm thick) and surface sediments (5 cm thick) in a submarine limestone cave (31 m water depth) on the fore-reef slope of Ie Island, off Okinawa mainland, Japan, were examined by visual, mineralogical and geochemical means. Oxygen isotope analysis was performed on the cavernicolous micro-bivalve Carditella iejimensis from both cored sediments and surface sediments, and the water temperature within the cave was recorded for nearly one year. These data show that: (1) water temperature within the cave is equal to that at 30 m deep in the open sea; (2) the biotic and non-biotic environments within the cave have persisted for the past 2000 years; (3) mud-size carbonate detritus is a major constituent of the submarine-cave deposit, and may have come mainly from the suspended carbonate mud produced on the emergent Holocene reef flat over the past two millennia; (4) the δ¹⁸O-derived temperature (T_δ18_O) of C. iejimensis suggests that the species grows between April and July; (5) the T_δ18_O of C. iejimensis from cored sediments implies that there were two warmer intervals, at AD 340 ± 40 and AD 1000 ± 40, which correspond to the Roman Warm Period and Medieval Warm Period, respectively. These suggest that submarine-cave sediments provide unique information for Holocene reef development. In addition, oxygen isotope records of cavernicolous C. iejimensis are a useful tool to reconstruct century-scale climatic variability for the Okinawa Islands during the Holocene.     

Seismic wave propagation analysis in vertical arrays at Kashiwazaki–Kariwa nuclear power plant site by using modified normalized input–output minimization (mod‐NIOM) method

A new approach on numerical modeling of wave propagation is introduced and is used to analyze the effect of earthquake magnitudes (ground motion amplitudes) on wave propagation. In this method, the sum of the maximum amplitudes of the first output model at time 0 s and rest of the output models at different times are normalized to unity. Considering this as a constraint, the sum of the weighted‐squared Fourier amplitudes is minimized by using the Lagrange multiplier method. The proposed method can reveal the relationship of actual time histories by showing simple clear peaks. This method is used to analyze the time histories of various earthquake events at different vertical array sites of the Kashiwazaki–Kariwa nuclear power plant of Tokyo electric power company (TEPCO). The wave arrival times obtained from this method and down‐hole measurements are compared. The results show increase in the arrival times at surface layer when the magnitude of earthquake is large. The results reveal that the amplitudes of small magnitude earthquakes at depths are small and are largely amplified at surface, whereas in case of large magnitude earthquakes, the amplitudes are large at depths and are deamplified at surface reflecting the effects of the strain‐dependent soil properties that result in non‐linear site response to strong shaking. The results also show that the reflected peak amplitudes are higher for small magnitude earthquakes than for large magnitude earthquakes. Copyright © 2010 John Wiley & Sons, Ltd.     

Inter-manufacturer Difference and Temperature Dependency of the Fall-Rate of T-5 Expendable Bathythermograph

The fall-rate of the T-5 expendable bathythermograph (XBT) produced by Tsurumi Seiki (TSK) Co., Ltd and that by Sippican Inc., are intercompared by a series of contemporaneous and colocated measurements with conductivity-temperature-depth (CTD) profilers. It is confirmed that the fall-rates of the two manufacturers' T-5 differ by about 5 percent, despite the fact that they had been believed to be identical for many years. The cause of the difference is discussed on the basis of a detailed cross-examination of the two T-5 models. It is found for the first time that the two models are different in several respects. The manufacturer's fall-rate equation is only applicable to the Sippican T-5, for which Boyd and Linzell's (1993) equation seems to be slightly more accurate. Kizu et al.'s (2005) equation gives a clearly less biased depth than the manufacturers' equation for the TSK T-5. It is also found that the fall-rates of both T-5 models are dependent on water temperature, perhaps because of viscosity. The temperature-dependency of the fall-rate of the TSK T-5 is larger than that of the Sippican T-5.     

CCD surface photometry of an outburst of P/Schwassmann-Wachmann 1 comet

We have observed an outburst of P/Schwassmann-Wachmann 1 (SW1) on 25–26 July 1987 using a CCD imager with R-band filter. The total brightness increased from 15.5 mg (25d) to 14.4 mag (26d) during tabout 24 hrs. The southward elongated coma of 25 was detected. The radial surface brightness (B) profiles are plotted against apparent distance p from the nucleus. The logarithmic derivative k = d ln B/d ln p for the inner coma is found to have steepened from k = –1.40 (25d) to k = –1.69 (26d), whereas that for the outer coma showed no appreciable change (k = –1.19 ~ –1.22). The ellipticity of the isophotal contour of the inner coma increased about 15% fro 25d to 6d. It is concluded that the scale of this outburst was smaller than the typical ones whose magnitude change is 5–8 mag. From recent findings on the outburst natur eof SW1 including ours, a working model of the nuclues is proposed.     

High-resolution seismic stratigraphy of the Yamato Basin, Japan Sea and its geological application

Abstract High-resolution seismic stratigraphy of the Yamato Basin, Japan Sea, was successfully established using core-log-seismic data integration. The construction of synthetic seismograms by the combination of physical properties and well-log data from the Ocean Drilling Program (ODP) Site 797 was the key to accomplishing the high-resolution seismic stratigraphy. To achieve resolution comparable with well-log data and core lithology, single channel seismic reflection data taken from ODP underway geophysics were reprocessed, and then carefully compared with synthetic seismogram, core and well log profiles to identify seismic units. Ten seismic stratigraphic units were identified at the site, and seismic stratigraphic interpretation was successfully extended from the site to the nearby area along the Yamato Basin margin. The opal-A/opal-CT (biogenic silica/metastable diagenetic silica) boundary has different appearances at places from strong to weak, and mostly discontinuous. One of the significant results achieved from this study is clear distinction of the opal-A/CT boundary from a very strong reflector, which appears at 22 m below the opal-A/CT boundary. Through well-log and physical properties characterization of the different units, resistivity was found to be the best indicator of diatom content and with gamma-ray it also is an indicator of chert layers in the opal-CT zone. Velocity is not greatly effected by diatom ooze in the opal-A zone, however, it shows strong peaks and has an indirect relationship with gamma-ray in the opal-CT zone. Finally, successful correlation of Gamma-ray Attenuation Porosity Evaluator density and resistivity peaks with strong seismic reflectors from upper and lower stratified layers may provide new information on the late Neogene paleoceanography of the Japan Sea in high-resolution scale.     

Seismotectonics of the Median Tectonic Line in southwest Japan: Implications for coupling among major fault systems

The relationship between the slip activity and occurrence of historical earthquakes along the Median Tectonic Line (MTL), together with that of the fault systems extending eastward has been examined. The MTL is divided into three segments, each containing diagnostic active faults. No historical earthquakes have been recorded along the central segment, although the segment has faster Quaternary slip rates compared with the other segments that have generated historical earthquakes. This discrepancy between earthquake generation and slip rate can be explained by a microplate model of southwest Japan. The microplate model also provides spatial and temporal coupling of slip on adjacent fault systems. In the context of this model, slip on adjacent faults reduces the normal stress on the MTL. Historical data and paleoseismic evidence indicate that slip on this segment occurs without significant strong ground motion. We interpret this as indicating anomalously slow seismic slip or aseismic slip. Slip on the central segment of the MTL creates transpressional regions at the eastern and western segments where historical earthquakes were recorded. Alternatively, the earthquakes at the eastern and western segments were triggered and concentrated shear stress at the edge of the segments resulted in postseismic slip along the central segment. The sequence of historical events suggests that the MTL characteristically does not produce great earthquakes. The microplate model also provides a tectonic framework for coupling of events among the MTL, the adjacent fault systems and the Nankai trough.     

Earthquake physical damage and functional serviceability of lifeline network models

The connectivity of lifeline systems is studied in this paper in terms of two ratios: ‘damage ratio’, which is the degree of physical damage to the system, and is defined as the expected number of failures per unit length or per link; and ‘service ratio’, which is a measurement of system operation. First, the relationship between the two ratios in a historic event is examined. Second, a method is developed for determining this relationship in simple network systems immediately following an earthquake. Density function, expected value and covariance of service ratio are calculated as functions of the damage ratio. Even in a simple checkerboard-type network, the density function of the service ratio has two peaks. Third, the variation in reliability of the network is examined with respect to difference in scale and configuration of the network, which may accompany growth of the community. When the damage ratio is small, the service ratio of a complex network is as large as, or larger, than that of a simple network. This pattern is, however, reversed for larger damage ratios. Finally, the relationship prior to operation restoration is examined. During the initial stages of restoration, the service ratio increases steeply, almost linearly, with decrease in the damage ratio. The increase then slows in the last stages of restoration.     

Using sulfur isotopes to determine the sources of vermillion in ancient burial mounds in Japan

This study represents an attempt to determine the sources of vermillion found in ancient Japanese burial mounds of the 1st–6th centuries A.D., by comparing their ratios of sulfur isotopes with those of cinnabar ore samples collected in Japan and China. Cinnabar ore samples were taken from three mines in central Japan (Niu in Mie, Yamato in Nara, and Sui in Tokushima prefectures), and from Wanshan in China, where mining activity has been recorded back to the 6th century A.D. and earlier. When the ratios of a ³⁴S and ³²S were compared with the Canyon Diablo meteorite standard, a high δ³⁴S value of +22.6 ± 3.6‰ was found for the Wanshan mine, as opposed to low values ranging from −7.3 ± 1.9 to −2.1 ± 1.6‰ for the Japanese mines. The ratios of sulfur isotopes in vermillion collected from ancient Japanese burial mounds also divided into two groups. High ratios (+11.1 to +22.8‰) were found in 1st‐ and 2nd‐ century burials in the western regions of northern Kyushu and San'in, suggesting that local, powerful chiefs obtained vermillion through relations with China. Lower ratios (−8.4 to −2.0‰) were found in burials of the 2nd through 6th centuries in central Japan, where the ancient Yamato dynasty emerged as the first unified polity around the end of the 2nd century A.D. We, therefore, conclude that the Yamato dynasty exploited local sources of vermillion, rather than depending solely on China. The present study demonstrates the feasibility of determining sources of vermillion using sulfur isotope ratios, and the relevance of such findings for archaeological research. © 2005 Wiley Periodicals, Inc.     

A modified normalized input-output minimization （Mod-NIOM） method for seismic wave propagation modeling

A new method for wave propagation modeling is introduced in this paper. By using the constraint optimization (Lagrange multiplier) method, the sum of weighted squared Fourier amplitudes is minimized when subjected to a constraint. The sum of the maximum amplitudes obtained from all output models is normalized to unity and is taken as a constraint. In this method, all the actual time histories are considered as outputs and dealt with equally. Independently of the combinations of time histories (or the first ...