Interannual and synoptic-scale features of two types of cold-air outbreaks over the East China Sea during 1988�C2006

For the 1988?C2006 cold seasons, we investigated the characteristic structures of two types of cold-air outbreaks over the East China Sea: Type N, for which a thick layer of northerly meridional wind was formed during the cold-air outbreak; and Type S, for which an initially thin layer of northerly meridional wind was gradually thickened as the cold-air outbreak developed. The emergence frequencies of Type N and Type S outbreaks are sensitive to winter monsoon intensity at the 500-hectopascal (hPa) level. Type S outbreaks are dominant during strong El Ni?o events, leading to enhanced southerly meridional flow at 500?hPa over the East China Sea. The development of the 500-hPa Pacific High strongly influences the synoptic-scale structures of the two different types of outbreaks over the East China Sea.     

Bioaccumulation of nitroarenes in bivalves at Osaka Bay, Japan

This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels.     

Japan’s Nation-Wide Electronic Geotechnical Database Systems by Japanese Geotechnical Society

On October 15, 2010, the Japanese Geotechnical Society (JGS) announced the public release of ‘Nation-wide Electronic Geotechnical Database Systems,’ which provides geotechnical information to the public on the internet. The information the system provides is a collection of ground models at 250 m by 250 m in plan built by using data from various geotechnical information databases. The paper first describes historical development of the geotechnical information databases in Japan, and introduces a 5-year project, ‘Integrated Geophysical and Geological Information Database in Japan,’ led by the National Research Institute for Earth Science and Disaster Prevention (NIED), and participated by the JGS. The paper then presents the JGS’ ‘Nation-wide Electronic Geotechnical Database Systems,’ and describes why such system was proposed and built, followed by the presentation of the examples for possible application of the system.     

Numerical simulations of mantle flow around slab edges

A simple kinematic-dynamic model of mantle flow around the slab-edge is constructed in order to understand the flow complexity there. The flow velocity on the top and the small boundary region around the shallow plate boundary is kinematically imposed in order to achieve a subduction-like feature and the flow in other part is dynamically calculated. The geometry of the plate mimics the region around the junction of Aleutian Islands and Kamchatka, that are examples of the convergent-transform fault plate boundaries. In a simple model in which the overlying plate is almost stationary, the lateral flow from the mantle under the subducting slab to the mantle under the neighboring plate is of minor importance, once the slab penetrates into the high viscosity layer where the downward flow encounters the resistance. Similar situation was found when the trench is advancing, that is, the trench moves toward the overlying plate. For the case with retreating trench, that is, the trench moves toward the subducting plate, a lateral flow exists even after the slab penetrates into the high viscosity layer, although its magnitude is significantly smaller than that of the plate velocity. The presence of a low viscosity layer just beneath the subducting plate may promote the emergence of lateral flow. A significant lateral flow is observed when the high temperature anomaly, that is, buoyant and low viscosity block carried by the movement of subducting plate, approaches the slab. These results may have important implications for the possible existence of trench parallel flow in the sub-slab mantle.     

Geochemical analyses of geological layers and groundwater flows

X-ray fluorescent spectroscope analysis easily finds ratios of geochemical elements in soil. Applying the method of ratio matching to measured ratios, the classification of geological layers, and the flow directions of groundwater can be determined. This method is applied to three hill slopes in Japan and the results are in good agreement with the observations and measurements of soil cores obtained by drilling. The classification of geological layers is found to be quantitatively connected with the rates of organic matter in soil cores. Received: 5 February 1999 · Accepted: 7 September 1999     

Ore mineralogy and sulfur isotope study of the massive sulfide deposit of Filon Norte,Tharsis Mine,Spain

The volcanogenic massive sulfide deposit of Filon Norte at Tharsis is hosted by carbonaceous black slate and connected only partly with stockwork veins. The massive ores are usually composed of fine-grained pyrite with subordinate amounts of sphalerite, chalcopyrite, galena and arsenopyrite. Monoclinic pyrrhotite sometimes occurs in massive pyritic ores in the apparently middle and upper horizons of the orebody, and siderite-rich ores are interstratified with compact pyritic ores in the apparently lower horizons. From the occurrence of monoclinic pyrrhotite, together with the FeS contents of sphalerite mostly ranging from 11 to 16 mol %, it is inferred that the sulfide minerals of the massive orebody were precipitated in euxinic muds on the sea-floor at temperatures below 250°C. The negatively shifted, highly variable ³⁴S values of the massive ores and their close similarity to those of the underlying black slates strongly suggest that the sulfide sulfur of the massive orebody and the slates is cognate and biogenic.     

Interstellar cyanomethane

We have made an observational study of the newly identified cyanomethane radical CH2CN and the possibly related species CH3CN with the goals of (1) elucidating the possible role of reactions of the type CnHm(+) + N in astrochemistry, and (2) providing a possible test of Bates's models of dissociative electron recombination. We find a remarkably different abundance ratio CH2CN/CH3CN in TMC-1 and Sgr B2, which we deduce is a result of the large difference in temperature of these objects. Studies of CH2CN and CH3CN in other sources, including two new detections of CH2CN, support this conclusion and are consistent with a monotonic increase in the CH2CN/CH3CN ratio with decreasing temperature over the range 10-120 K. This behavior may be explained by the destruction of CH2CN by reaction with O. If this reaction does not proceed, then CH2CN and CH3CN are concluded to form via different chemical pathways. Thus, they do not provide a test of Bates's conjectures (they do not both form from CH3CNH+). CH2CN is then likely to form via C2H4(+) + N --> CH2CNH+, thus demonstrating the viability of this important reaction in astrochemistry. The T dependence of the CH2CN/CH3CN ratio would then reflect the increasing rate of the C2H4(+) + N reaction with decreasing temperature.     

Laboratory detection of a new interstellar free radical CH2CN(2B1)

An asymmetric-top free radical CH2CN, which as a 2B1 ground state, was detected for the first time by laboratory microwave spectroscopy. The radical was produced in a free-space absorption cell by a DC glow discharge in pure CH3CN gas. About 60 fine-structure components were observed for the N = 11-10 to 14-13 a-type rotational transitions in the frequency region of 220-260 GHz, and many hyperfine resolved components for the N = 4-3 and 5-4 transitions in the 80 and 100 GHz regions, respectively. The molecular constants, including the rotational constants, centrifugal distortion constants, and spin-rotation coupling constants with centrifugal distortion correction terms were determined from the fine-structure resolved transitions, and the hyperfine coupling constants due to the hydrogen and nitrogen nuclei were obtained from the low-N transitions. As a result we assigned U100602 and U80484 from Sgr B2, and U40240 and U20120 from TMC-1, to the N = 5-4, 4-3, 2-1, and 1-0 transitions with K-1 = 0 of the CH2CN radical.     

Ca isotopic compositions of dolomite, phosphorite and the oldest animal embryo fossils from the Neoproterozoic in Weng'an, South China

Deciphering the drastic changes of surface environment and the emergence of animals after the Neoproterozoic Snowball Earth event are important for understanding the changes of surface environment and its influence on the evolution of life through geologic time. Especially, the emergence of two types of Metazoan animals such as animal embryo fossils, cnidarians or sponges, and Ediacaran fauna in the late Neoproterozoic was one of the critical turning points in the biological evolution.Calcium is one of the essential elements for the growth of most animals. In this study, in order to evaluate the Ca cycles in the Neoproterozoic, we have measured Ca isotopic ratios (⁴⁴Ca/⁴²Ca and ⁴³Ca/⁴²Ca) for phosphorite, dolostone and phosphatic animal embryo fossils with a multiple collector, inductively coupled plasma-mass spectrometer (MC-ICP-MS). The resulting ⁴⁴Ca/⁴²Ca ratio defined by the relative deviation from the ratio of NIST SRM915a (δ^44/42Ca_NIST915) for phosphorite and dolostone ranges from 0.83 to 0.95‰, demonstrating that the fractionation between phosphorite/dolostone and seawater was very small. This evidence indicates that at the emergence of the Weng'an biota seawater was deficient in Ca probably due to mass deposition of phosphorite/dolostone and to the beginning of Ca-biomineralization.Three phosphatic animal embryo fossils have lower δ^44/42Ca values than the phosphorite and dolomite, implying that the precursor of the phosphatic embryo fossils was able to fractionate Ca isotopes through Ca-biomineralization, consistent with marine gastropods.