Alpine metamorphism of low-grade schists from the Slavonian Mountains (Croatia): new P-T and geochronological constraints

Low-grade schists from the Slavonian Mountains (Tisia Mega-Unit, Mt Papuk, Croatia), previously assigned to Precambrian to Lower Palaeozoic metamorphism, have been subjected to geochemical investigations, P-T modelling, and in situ age dating of monazite. The studied fine-grained metasediments consist of chlorite (5–15 vol.%), K white-mica (40–55 vol.%), quartz (20–35 vol.%), feldspar (albite 15–20 vol.%), opaques (<2 vol.%), and accessory minerals. According to their whole-rock geochemistry, the detritus of the former sediments came from upper crustal felsic rocks as they occur, for instance, at Mt Papuk. The schists show a complex microtectonic fabric, including well-developed schistosity systems. P-T pseudosections in the system MnNCKFMASHTO, constructed for typical schists of the study area, resulted in peak P-T conditions of 445–465 °C and 4.6–6.0 kbar for a sample from Kutjevo (eastern part of the study area) and 450–460 °C and 5.2–6.0 for a Vranovo sample (western part). Electron microprobe (EMP) dating of monazite in the schists gave a weighted average age of 109.0 ± 13.1 Ma (2σ) eventually with three subgroups of ages at 225 ± 63 (two analyses), 114 ± 24 and 83 ± 22 Ma. We conclude that the metamorphism of the studied schists at depths of c. 20 km is due to an Alpine collisional event.     

Upper Jurassic Rock Depositional Settings in the Baidar Valley and Evolution of the Crimean Carbonate Platform

The paper presents results of the lithological study of Upper Jurassic limestones, flyschoids and limestone breccias on the southern side of the Baidar Valley in the Crimean Mountains. Study of the microfacies revealed that the limestones are represented by deposits on lagoons, platform edge shoals, reefs, and forereef aprons on the carbonate platform slope. Flyschoids include deposits in the distributive turbidite channels and hemipelagic sediments in the deep-water part of the basin. Limestone breccias were formed by gravitation flows on the carbonate platform toe-of-slope and slope. The presence of gravitation deposits in the Upper Jurassic carbonate complexes of the Crimean Mountains can testify to the primary clinoform structure of this sedimentary sequence. Comparison of the obtained sedimentological data made it possible to reconstruct the facies model of the Crimean carbonate platform and main episodes of its formation. Development of the carbonate shelf was related to two transgressive-regressive cycles. A dome-shaped reef was formed away from the coast at the initial (Oxfordian) stage. The carbonate platform was formed at the early Kimmeridgian lowstand stage when sediments were deposited in the internal part of the platform adjacent to land. In the late Kimmeridgian and early Tithonian, configuration of the carbonate platform profile resembled a distally steepened ramp, and its active progradation and shelf expansion took place in the course of transgression. Regression in the late Tithonian–early Berriasian led to regressive transformation of the ramp into platform with a flattened shallow-water shelf. Tectonic deformations at the Jurassic/Cretaceous transition promoted the formation of megabreccias on the carbonate platform foreslope. The tectonically reworked rock sequence of the “extinct” carbonate platform was overlapped transgressively by the upper Berriasian or lower Valanginian, relatively deep-water deposits of the Cretaceous platform cover.     

Impoverishment of recent floodplain forest mollusc fauna in the lower Ohře River (Czech Republic) as a result of prehistoric human impact

Analyses of fossil mollusc successions have rarely been used to study the development of floodplain forests during the Holocene. The Oh?e River, located in a prehistorically settled chernozem area in the Czech Republic, is partly situated in Cretaceous marlstones, yielding sediments suitable for fossilization directly in floodplain deposits. We analysed five fossil mollusc successions situated in the lower stretch of the Oh?e River and compared the results with recent mollusc assemblages studied along the entire 256 km of the river. Fossil samples were composed mostly of open‐country species throughout the Holocene or the whole preserved succession. Only some samples also contained woodland assemblages, but these were always greatly impoverished, with a very low frequency of strictly woodland species. Although the natural‐looking appearance of the present‐day floodplain forests of the lower river stretch has resulted in its being declared a nature reserve, modern floodplain forest mollusc assemblages there are also impoverished. This reduction in the distribution of strictly woodland species compared with modern assemblages in the upper stretch of the river seems to be the result of an ancient human settlement and continuous disturbances of the floodplain forest development since the Neolithic. Thus, fully developed floodplain forest assemblages occur recently only in the upper non‐impacted stretch of the river. Based on the studied fossil successions we can conclude that the lower Oh?e River floodplain was probably a mosaic of open and disturbed forest habitats throughout the Holocene. This area is part of a central European landscape island, where forests probably never fully developed and open patches from the early Holocene continually developed into an agricultural landscape.     

On the relation between solar motion and the long term variability of solar activity

Summary The Sun's motion round the barycentre of the solar system was found to consist of two basic alternately repeating elements of the noose and of the arc. The mean time for solar motion around each of these elements was found to be 9.93 yr. The relation between solar motion and solar variability was determined as follows: Approximately coincident periodicities ranging from 60 to 2200 yr were traced in both phenomena and a coincidence of all prolonged minima in solar activity with the epochs of the highest deviations from the Jupiter—Saturn order was found over a time interval of 3100 yr.

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Thermo-elastic deformations due to the annual temperature variation at the tidal station in Vyhne

Summary The thermo-elastic deformations due to the annual temperature variation are computed. The time variation of these deformations is compared with the variation of the slow deformations observed at the tidal station in Vyhne.

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Dedicated to RNDr Jan Pícha, CSc on his 70th birthday     

The boundary integral calculations of the forward problem for D.C. sounding and MMR methods for a 3-D body near a vertical contact

Summary The paper presents comprehensive theory based on the boundary integral method for calculations of the electric potential, electric field and corresponding magnetic field due to a pair of D.C. source electrodes near a vertical resistivity contact in the halfspace, indlucing a 3-D disturbing body in the vicinity of the contact. Special attention is paid to the case when the disturbing body touches the vertical contact. Results of numerical calculations are presented in the form of sounding curves and a set of isoline graphs for potential, components of the electric and magnetic field (total and anomalous) on the surface of the Earth. It is shown that the presence of the disturbing body at the contact is most pronounced in the electrical characteristics. Anomalies in the magnetic field are small in comparison to the field due to the electric current in the electrode cable and primary currents flowing from the electrodes.     

The photoelectron spectra of some Tl-Sb sulphosalts

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.     

Eddy energy dissipation rate and puff diffusion during calms

The paper considers a puff diffusion in its inertial stage when particle separation obeys the laws of the inertial subrange and depends only on eddy energy dissipation rate . The can be determined in the surface layer by the turbulent kinetic energy equation. Similarity equations connect with diffusion measure .A simple analytical model has been deduced to estimate pollutants diffusion during calms.