Self-diffusion studies of pore fluids in unconsolidated sediments by PFG NMR

The self-diffusion of water and hexadecane in medium and coarse sands from glacial sand deposits in central Germany were investigated by pulsed field gradient nuclear magnetic resonance (PFG NMR). Due to the restriction of the diffusion path at the pore/grain interface, the measured apparent self-diffusion coefficients (D(Δ)) in the pore space depend on the observation time (Δ) in the PFG NMR experiment. Although the bulk self-diffusion coefficients of water and hexadecane differ by about one order of magnitude, the apparent self-diffusion coefficients in the pore space obey the same characteristic time-behaviour, which depends only on geometrical properties of the pore system. Using the “short-time diffusion” model, surface-to-volume (S/V) ratios and inherent self-diffusion coefficients (D₀) of the pore fluids were extracted from these diffusion measurements. The S/V ratios obtained are independent of the pore fluid used and agree with known geometrical properties of the sand grains. Moreover, the D₀ values are consistent with the corresponding bulk self-diffusion coefficients measured separately. In contrast to these results of PFG NMR, simultaneous investigations of longitudinal (T₁) nuclear magnetic relaxation reveal that the relaxation time of the pore fluid is a less suitable parameter for a quantitative estimation of geometrical properties of the pore/grain interface in these unconsolidated sediments since it depends on chemical properties of the fluid/grain interface.     

Phosphorus input by upwelling in the eastern Gotland Basin (Baltic Sea) in summer and its effects on filamentous cyanobacteria

In July 2007, phosphorus input by an upwelling event along the east coast of Gotland Island and the response of filamentous cyanobacteria were studied to determine whether introduced phosphorus can intensify cyanobacterial bloom formation in the eastern Gotland Basin. Surface temperature, nutrient concentrations, phytoplankton biomass and its stoichiometry, as well as phosphate uptake rates were determined in two transects between the coasts of Gotland and Latvia and in a short grid offshore of Gotland. In the upwelling area, surface temperatures of 11–12 °C and average dissolved inorganic phosphorus (DIP) concentrations of 0.26 μM were measured. Outside the upwelling, surface temperatures were higher (15.5–16.6 °C) and DIP supplies in the upper 10 m layer were exhausted. Nitrite and nitrate concentrations (0.01–0.22 μM) were very low within and outside the upwelling region. Abundances of filamentous cyanobacteria were highly reduced in the upwelling area, accounting for only 1.4–6.0% of the total phytoplankton biomass, in contrast to 18–20% outside the upwelling. The C:P ratio of filamentous cyanobacteria varied between 32.8 and 310 in the upwelling region, most likely due to the introduction of phosphorus-depleted organisms into the upwelling water. These organisms accumulate DIP in upwelling water and have lower C:P ratios as long as they remain in DIP-rich water. Thus, diazotrophic cyanobacteria benefit from phosphorus input directly in the upwelling region. Outside the upwelling region, the C:P ratios of filamentous cyanobacteria varied widely, between 240 and 463, whereas those of particulate material in the water ranged only between 96 and 224. To reduce their C:P ratio from 300 to 35, cyanobacteria in the upwelling region had to take up 0.05 mmol m⁻³ DIP, which is about 20% of the available DIP. Thus, a larger biomass of filamentous cyanobacteria may be able to benefit from a given DIP input. As determined from the DIP uptake rates measured in upwelling cells, the time needed to reduce the C:P ratio from 300 to 35 was too long to explain the huge bloom formations that typically occur in summer. However, phosphorus uptake rates increased significantly with increasing C:P ratios, allowing phosphorus accumulation within 4–5 days, a span of time suitable for bloom formation in July and August.     

Adaptive Optics on a 3.6-Meter Telescope. The ADONIS System.

ADONIS is an adaptive optics (AO) user friendly instrument offered to the European astronomical community on the ESO 3.6-m telescope at La Silla. It is an upgraded version of COME-ON-PLUS, the VLT AO prototype, which already produced significative astrophysical results in a wide range of fields, from planetology to extragalactic astrophysics. ADONIS is now allowing the astronomer to use adaptive optics as a common user instrument thanks to the implementation of an open artificial intelligence software that handles the large number of parameters needed to optimise the AO correction. We will describe the ADONIS system, including the two dedicated infrared cameras, summarize its performances and discuss the observing procedures.     

Regime shifts in the marine environment: the scientific basis and political context

Regime shifts in the marine environment have recently received much attention. To date, however, few large-scale meta-analyses have been carried out due to insufficient data coverage and integration between sustained observational datasets because of diverse methodologies used in data collection, recording and archival. Here we review the available data on regime shifts globally, followed by a review of current and planned policies with relevance to regime shifts.We then focus on the North and Baltic Seas, providing examples of existing efforts for data integration in the MarBEF Network of Excellence. Existing gaps in data coverage are identified, and the added value from meta-analyses of multiple datasets demonstrated using examples from the MarBEF integrated data project LargeNet. We discuss whether these efforts are addressing current policy needs and close with recommendations for future integrated data networks to increase our ability to understand, identify and predict recent and future regime shifts.     

New findings on the tectono-metamorphic history of the western Rhenish Massif (Germany) by K–Ar dating of metasedimentary illite

Metapelites, clay-rich sandstones and volcanics from Cambrian, Ordovician and Lower Devonian strata of the western Rhenish Massif underwent a complex regional Variscan tectono-thermal evolution, as shown by mineralogical and K–Ar isotopic analyses of the illite to mica components from three NW-SE transects. The metamorphic degree extended from an anchimetamorphic to an epimetamorphic intensity during two major episodes of illite crystallization at 328 ± 6 and 282 ± 12 Ma. A further late orogenic or post-orogenic extensional activity could also be detected, but not precisely, around 270 Ma, probably recorded by the precipitation of illite in new or reactivated extensional faults with upward moving heat flows.     

Expected damage from displacement of slow-moving slides

Facilities such as buildings, highways, railways, bridges, dams and pipelines often are built on natural slopes where the risk of landslides is not low. The vulnerability of these facilities to slow-moving slides has sometimes been underestimated, although the velocity of some classes of slow slides is uncontrollable. More than 50 cases of slow slides were compiled from the literature for this study. Some statistics about the movement trigger(s), the methods used to measure displacement, the material forming the rupture surface and the type of the vulnerable facilities are presented. It is shown that the expected degree of damage to urban settlements, highways, bridges and dams can be related to the slide velocity or accumulating displacement. Buildings and residential houses may tolerate higher slide velocities and total displacements than other facilities before experiencing serious damage. Movements as low as 100 mm may severely damage bridges, but such low rates may cause only moderate damage to urban communities. The relationship between movement and the expected extent of damage should be useful to geotechnical engineers who deal with different classes of slow slides and will help in the choice of appropriate mitigation measures based on preliminary estimates of movement rates.     

A heat flow and physical properties package for the surface of Mercury

European Space Agencies fifth cornerstone mission BepiColombo includes a ‘Surface Element’ to land a scientific payload on the surface of Mercury. The current strawman payload includes a heat flow and physical properties package (HP³), focussing on key thermal and mechanical properties of the near-surface material (down to a depth of 2–5 m) and the measurement of heat flow from Mercury's interior, an important constraining parameter for models of the planet's interior and evolution. We present here an overview of the HP³ experiment package and its possible accommodation in a self-inserting ‘mole’ device. A mole is considered to be the most appropriate deployment method for HP³, at least in the currently-assumed case of an airbag-assisted soft landing architecture for the Mercury Surface Element.     

GALACSI – The ground layer adaptive optics system for MUSE

MUSE, the Multi-Unit Spectroscopic Explorer, is an adaptive optics (AO)-assisted Integral Field Spectrograph, currently in the Preliminary Design Phase as a second generation instrument for the VLT. MUSE will feature two modes, each with an associated AO mode. The first mode is the wide field mode, mainly aiming at the study of high redshift galaxies. For this mode, the AO system has to deliver an improvement of at least a factor of two over the full 1′ × 1′ field of view. The second mode, the narrow field mode, aims at the high-resolution spectroscopy of nearby extended objects, for example, galaxies and globular clusters. For this mode, the AO system will have to deliver near-diffraction limited performance over a small field of view. In this paper, we discuss the trade-offs in the current design of GALACSI – the MUSE AO system – and illustrate with a number of simulations the expected performance in the wide- and narrow field modes.