Geochemistry of magnesian ilmenites from kimberlites in South Africa and Lesotho

Magnesium ilmenite from discrete nodules and lamellar intergrowths with pyroxene from the Kao, Sekameng, Frank Smith, and Monastery kimberlites has been analysed for Ti, Fe, Mg, Nb, Zr, Cr, Cu, Zn, Mn, Co, and Ni. Each kimberlite contains discrete ilmenites which exhibit a wide compositional range within the ilmenite-geikeilite series. Lamellar ilmenites from Frank Smith and Monastery differ in composition but both show a limited range in composition which lies within the compositional range shown by discrete ilmenites from these pipes. The ilmenites are enriched in Nb, Zr, Cr, Co, and Ni and depleted in Mn, Cu, and Zn relative to Mg-poor ilmenites from basic intrusions. Nb, Zr, and Ni correlate with Fe, Ti and Mg variations but the abundances of the other trace elements are independent of major element variation. R-mode factor analysis is interpreted to imply that the geochemistry cannot be interpreted in terms of a differentiation hypothesis in which trace elements are removed from or concentrated in residua. Factor scores and major element abundances indicate that each pipe is characterized by a particular suite of discrete ilmenite nodules, which are considered to be phenocrysts in a proto-kimberlite magma. Lamellar ilmenite-pyroxene intergrowths are unlikely to have had a eutectic origin, and show no simple relationship to the discrete ilmenites.     

Last interglacial climates of south-eastern Australia: plant and beetle-based reconstructions from Yarra Creek,King Island,Tasmania

This paper explores the palaeoclimatic significance of a fossil plant and insect record from Yarra Creek, on King Island, between Tasmania and the Australian mainland. The record dates, based upon a thermoluminescence chronology and other evidence, to Marine Isotope Stage 5 (MIS 5); the exact timing is impossible to ascertain given the resolution of the thermoluminescence results and the presence of an unconformity in the dated section. The presence of a cool-temperate rainforest flora, outside its modern range, and other independent evidence, suggest the sequence may represent the last interglacial (MIS 5e) rather than a later MIS 5 substage. Using coexistence methods that compare modern climatic ranges of the taxa in the assemblage we reconstruct independent beetle and plant based annual and seasonal temperate and precipitation parameters. The results imply the assemblage was deposited under a wetter summer climate and suggest conditions of enhanced temperature seasonality. It is probable that enhanced temperature seasonality is a methodological artefact reflecting the rarity of extremely equable climates (like King Island) in modern climate space. This would indicate a limitation of most methods of palaeoclimatic reconstruction that rely on modern datasets – it is only possible to reconstruct past climates as being within the range of values in that currently exist in modern climate space.     

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.     

Search for Phobos and Deimos gas/dust tori using in situ observations from Mars Global Surveyor MAG/ER

More than 490 elliptical aerobraking and science phasing orbits made by Mars Global Surveyor (MGS) in 1997 and 1998 provide unprecedented coverage of the solar wind in the vicinity of the orbits of the martian moons Phobos and Deimos. We have performed a comprehensive survey of magnetic field perturbations in the solar wind to search for possible signatures of solar wind interaction with dust or gas escaping from the moons. A total of 1246 solar wind disturbance events were identified and their distribution was examined relative to Phobos, the Phobos orbit, and the Deimos orbit. We find that the spatial distribution of solar wind perturbations does not increase near or downstream of Phobos, Phobos’ orbit, or Deimos’ orbit, which would have been expected if there is significant outgassing or dust escape from the martian moons. Of the 1246 magnetic field perturbation events found in the MGS data set, 11 events were found within 2000 km of the Phobos orbit, while three events were found within 2000 km of the Deimos orbit. These events were analyzed in detail and found to likely have other causes than outgassing/dust escape from the martian moons. Thus we conclude that the amount of gas/dust escaping the martian moons is not significant enough to induce detectable magnetic field perturbations in the solar wind. In essence we have not found any clear evidence in the MGS magnetic field data for outgassing or dust escape from the martian moons.     

Oxygen consumption in the epilimnia and hypolimnia of two eutrophic,warm‐monomictic lakes

Oxygen consumption was estimated for two eutrophic New Zealand lakes using a simple 2‐layer model, from estimates of net changes in oxygen, phytoplankton photosynthesis, inflow and outflow, diffusion, eddy diffusion, and changes in the depth of the thermocline. Of the total oxygen consumption, 75–85% occurred in the epilimnia. Epilimetic oxygen consumption per m³ and per m² in Lake Johnson were higher than in Lake Hayes, reflecting known differences in the trophic status of the lakes, but estimates for the hypolimnia of the two lakes were similar. Daily hypolimnetic areal deficits were sensitive to both the depths and time intervals chosen.

In the epilimnia, monthly oxygen production by photosynthesis averaged 1.1 and 1.8 times the initial oxygen content in Lakes Hayes and Johnson respectively. Diffusion appeared to be of similar magnitude to photosynthesis in the isothermal period, but was less important during stratification. Losses to the hypolimnia by eddy diffusion were less than 10% of photosynthesis. Photosynthesis in the hypolimnia contributed 30–40% of the oxygen consumed there and eddy diffusion supplied a further 20%.

In Lake Johnson a 3–5 m stratum of water in the metalimnion became anoxic for 2–3 months each summer while there were still up to 5.2 g.rer³ of oxygen remaining in the hypolimnion. Metalimnetic anoxia is attributed largely to oxygen consumption in situ, resulting from the highly eutrophic state of the lake and intense thermal stratification. Zooplankton respiration accounted for less than 10% of the maximum net decline in metalimnetic oxygen in 1970–71, but was more important in the other 2 years.

Changes in the oxygen content of the hypolimnion indicate that Lake Hayes has become more eutrophic since 1954–55. In Lake Johnson low oxygen concentrations at the autumn overturn (<5 g.m^‐3) represent a threat to the trout population.     

Volcanic hazard communication using maps: an evaluation of their effectiveness

Hazard maps are considered essential tools in the communication of volcanic risk between scientists, the local authorities and the public. This study investigates the efficacy of such maps for the volcanic island of Montserrat in the West Indies using both quantitative and qualitative research techniques. Normal plan view maps, which have been used on the island over the last 10 years of the crisis, are evaluated against specially produced three-dimensional (3D) maps and perspective photographs. Thirty-two demographically representative respondents of mixed backgrounds, sex, education and location were interviewed and asked to complete a range of tasks and identification on the maps and photographs. The overall results show that ordinary people have problems interpreting their environment as a mapped representation. We found respondents’ ability to locate and orientate themselves as well as convey information relating to volcanic hazards was improved when using aerial photographs rather than traditional plan view contour maps. There was a slight improvement in the use of the 3D maps, especially in terms of topographic recognition. However, the most striking increase in effectiveness was found with the perspective photographs, which enabled people to identify features and their orientation much more readily. For Montserrat it appears that well labelled aerial and perspective photographs are the most effective geo-spatial method of communicating volcanic risks.

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.