新疆西天山高硫化型京希-伊尔曼德金矿床的识别标志及其找矿意义

经过详细的野外地质勘查、热液蚀变及蚀变矿物学研究，流体包裹体和同位素研究，首次将西天山京希－伊尔曼德金矿床确定为高硫化型浅成低温热液金矿床。该矿床的主要识别标志为：发育以多孔状石英为特征的硅化蚀变带和高级泥化蚀变带；成矿流体性质为低盐度[W(NaCl)为0.3-4.2%]、低pH值（3－4）和高氧化态；氧同位素δ（^18O)为1.7 ‰-4.3‰,δ(D)为－60‰--80‰。金主要富集在高级泥化带和中心硅化蚀变带内。系统研究和总结了成矿地质－地球化学制约因素以及区域、靶区和勘探区尺度的找矿标志。     

Paleoecology of a Middle Wisconsin Deposit from Southern California

Analysis of a buried deposit in the Diamond Valley of southern California has revealed well-preserved pollen, wood, and diatom remains. Accelerator mass spectrometry dates of 41,200±2100 and 41,490±1380 ¹⁴C yr B.P. place this deposit in marine isotope stage 3. Diatoms suggest a shallow lacustrine environment. Pollen data suggest that several plant communities were present near the site, with grassland, scrub, chaparral, forest, and riparian communities represented. Comparison with modern pollen suggests similarities with montane forests in the nearby San Bernardino and San Jacinto ranges, indicating vegetation lowering by at least 900 m elevation and temperatures 4°–5°C cooler than today. An increase in high-elevation conifer pollen documents climatic cooling near the profile top. Early-profile diatoms are typical of warm water with high alkalinity and conductivity, whereas later diatoms suggest a higher flow regime and input of cooler water into the system. We suggest that the sequence is part of the cooling phase of an interstadial Dansgaard–Oeschger cycle. Records of the middle Wisconsin period are rare in southern California, but the Diamond Valley site is similar to records from Tulare Lake in the San Joaquin Valley and the ODP Site 893A record from Santa Barbara Basin. It is probable that the Diamond Valley assemblage is a local expression of a vegetation type widespread in the ranges and basins of southwestern California during the middle Wisconsin.     

A rifted inside corner massif on the Mid-Atlantic Ridge at 5°S

The structure of the Mid-Atlantic Ridge at 5°S was investigated during a recent cruise with the FS Meteor. A major dextral transform fault (hereafter the 5°S FZ) offsets the ridge left-laterally by 80 km. Just south of the transform and to the west of the median valley, the inside corner (IC – the region bounded by the ridge and the active transform) is marked by a major massif, characterized by a corrugated upper surface. Fossil IC massifs can also be identified further to the west. Unusually, a massif almost as high as the IC massif also characterizes the outside corner (OC) south of the inactive fracture zone and to the east of the median valley. This OC massif has axis-parallel dimensions identical to the IC massif and both are bounded on their sides closest to the spreading axis by abrupt, steep slopes. An axial volcanic ridge is well developed in the median valley both south of the IC/OC massifs and in an abandoned rift valley to the east of the OC massif, but is absent along the new ridge-axis segment between the IC and OC massifs. Wide-angle seismic data show that between the massifs, the crust of the median valley thins markedly towards the FZ. These observations are consistent with the formation of the OC massif by the rifting of an IC core complex and the development of a new spreading centre between the IC and OC massifs. The split IC massif presents an opportunity to study the internal structure of the footwall of a detachment fault, from the corrugated fault surface to deeper beneath the fault, without recourse to drilling. Preliminary dredging recovered gabbros from the scarp slope of the rifted IC massif, and serpentinites and gabbros from the intersection of this scarp with the corrugated surface. This is compatible with a concentration of serpentinites along the detachment surface, even where the massif internally is largely plutonic in nature.     

Crystal chemistry of titanite-structured compounds: the CaTi1-x Zr x OSiO4 (x≤0.5) series

Inhomogeneous aggregates of late-stage titanite enriched in Zr have been described recently from post-magmatic parageneses in silica-undersaturated rocks. In the natural samples, simple isovalent substitution of the large Zr (^[vi]R⁴⁺=0.72 Å) for Ti (^[vi]R⁴⁺=0.605 Å) is limited to an empirical maximum of 0.25 afu (15.3 wt.% ZrO₂). As the natural material is not suitable for crystallographic study, a series of CaTi_1-xZr_xOSiO₄ titanite samples have been synthesized by standard ceramic methods at ambient pressure in air, and their crystal structure determined by Rietveld refinement of laboratory powder X-ray diffraction patterns. All of the synthetic Zr-doped titanite varieties adopt space group A2/a and consist of distorted CaO₇ polyhedra together with less distorted (Ti_1-xZr_x)O₆ octahedra and SiO₄ tetrahedra. Cell dimensions and atomic coordinates together with volumes and distortion indices are given for all polyhedra. The empirical limit for Zr substitution in synthetic (F,OH)-free titanite is 0.5 afu (29.6 wt.% ZrO₂). The existence of a Zr analogue of titanite in nature is considered to be unlikely.     

Including spatial distribution in a data‐driven rainfall‐runoff model to improve reservoir inflow forecasting in Taiwan

Multi‐step ahead inflow forecasting has a critical role to play in reservoir operation and management in Taiwan during typhoons as statutory legislation requires a minimum of 3‐h warning to be issued before any reservoir releases are made. However, the complex spatial and temporal heterogeneity of typhoon rainfall, coupled with a remote and mountainous physiographic context, makes the development of real‐time rainfall‐runoff models that can accurately predict reservoir inflow several hours ahead of time challenging. Consequently, there is an urgent, operational requirement for models that can enhance reservoir inflow prediction at forecast horizons of more than 3 h. In this paper, we develop a novel semi‐distributed, data‐driven, rainfall‐runoff model for the Shihmen catchment, north Taiwan. A suite of Adaptive Network‐based Fuzzy Inference System solutions is created using various combinations of autoregressive, spatially lumped radar and point‐based rain gauge predictors. Different levels of spatially aggregated radar‐derived rainfall data are used to generate 4, 8 and 12 sub‐catchment input drivers. In general, the semi‐distributed radar rainfall models outperform their less complex counterparts in predictions of reservoir inflow at lead times greater than 3 h. Performance is found to be optimal when spatial aggregation is restricted to four sub‐catchments, with up to 30% improvements in the performance over lumped and point‐based models being evident at 5‐h lead times. The potential benefits of applying semi‐distributed, data‐driven models in reservoir inflow modelling specifically, and hydrological modelling more generally, are thus demonstrated. Copyright © 2012 John Wiley & Sons, Ltd.     

Middle Paleolithic occupation on a Marine Isotope Stage 5 lakeshore in the Nefud Desert,Saudi Arabia

Major hydrological variations associated with glacial and interglacial climates in North Africa and the Levant have been related to Middle Paleolithic occupations and dispersals, but suitable archaeological sites to explore such relationships are rare on the Arabian Peninsula. Here we report the discovery of Middle Paleolithic assemblages in the Nefud Desert of northern Arabia associated with stratified deposits dated to 75,000 years ago. The site is located in close proximity to a substantial relict lake and indicates that Middle Paleolithic hominins penetrated deeply into the Arabian Peninsula to inhabit landscapes vegetated by grasses and some trees. Our discovery supports the hypothesis of range expansion by Middle Paleolithic populations into Arabia during the final humid phase of Marine Isotope Stage 5, when environmental conditions were still favorable.