铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

Channelled erosion through a marine dump site of dredge spoils at the mouth of the Puyallup River, Washington State, USA

Channels are relatively common on river-mouth deltas, but the process by which they arise from river sediment discharge is unclear because they can potentially be explained either by negatively buoyant (hyperpycnal) flows produced directly from the river outflow or by flows generated by repeated failure and mobilisation of sediment rapidly deposited at the delta front. Channels eroded through a dump site of dredge spoils are described here from multibeam and older sonar data collected in Commencement Bay, at the mouth of the Puyallup River. Shallow channels on the seaward upper surface of the dump site, away from any flows that could have been produced by delta front failures, suggest that at least some hyperpycnal flows were produced directly from the positively buoyant river outflow up to 200 m from the edge of the river mouth platform. The form of channel bed erosion is revealed by the longitudinal shape of the main eroded channel compared with the adjacent dump site profile. It suggests that the channel evolved by its steep front retreating, rather than by simple vertical entrenchment or diffusive-like evolution of the profile, a geometry interpreted as evidence that repeated failure of the bed occurred in response to shear stress imposed by bottom-travelling flows. Model calculations based on shear strengths back-calculated from the geometry of channel wall failures suggest that, if the main channel were eroded solely by hyperpycnal flows, their generation was remarkably efficient in order to create flows vigorous enough to cause channel bed failure. Besides the sediment concentration and discharge characteristics that have been considered to dictate the ability of rivers to produce hyperpycnal flows, it is suggested that the timing of floods with respect to the tidal cycle should also be important because extreme low tides may be needed to ensure that coarse sediment is transferred vigorously to the edge of river mouth platforms.     

Circulation and currents in the southwestern East/Japan Sea: Overview and review

A review is made of circulation and currents in the southwestern East/Japan Sea (the Ulleung Basin), and the Korea/Tsushima Strait which is a unique conduit for surface inflow into the Ulleung Basin. The review particularly concentrates on describing some preliminary results from recent extensive measurements made after 1996. Mean flow patterns are different in the upstream and downstream regions of the Korea/Tsushima Strait. A high velocity core occurs in the mid-section in the upstream region, and splits into two cores hugging the coasts of Korea and Japan, the downstream region, after passing around Tsushima Island located in the middle of the strait. Four-year mean transport into the East/Japan Sea through the Korea/Tsushima Strait based on submarine cable data calibrated by direct observations is 2.4 Sv (1 Sv = 10⁶ m³ s⁻¹). A wide range of variability occurs for the subtidal transport variation from subinertial (2–10 days) to interannual scales. While the subinertial variability is shown to arise from the atmospheric pressure disturbances, the longer period variation has been poorly understood.Mean upper circulation of the Ulleung Basin is characterized by the northward flowing East Korean Warm Current along the east coast of Korea and its meander eastward after the separation from the coast, the Offshore Branch along the coast of Japan, and the anticyclonic Ulleung Warm Eddy that forms from a meander of the East Korean Warm Current. Continuous acoustic travel-time measurements between June 1999 and June 2001 suggest five quasi-stable upper circulation patterns that persist for about 3–5 months with transitions between successive patterns occurring in a few months or days. Disappearance of the East Korean Warm Current is triggered by merging the Dok Cold Eddy, originating from the pinching-off of the meander trough, with the coastal cold water carried Southward by the North Korean Cold Current. The Ulleung Warm Eddy persisted for about 20 months in the middle of the Ulleung Basin with changes in its position and spatial scale associated with strengthening and weakening of the transport through the Korea/Tsushima Strait. The variability of upper circulation is partly related to the transport variation through the Korea/Tsushima Strait. Movements of the coastal cold water and the instability of the polar front also appear to be important factors affecting the variability.Deep circulation in the Ulleung Basin is primarily cyclonic and commonly consists of one or more cyclonic cells, and an anticyclonic cell centered near Ulleung Island. The cyclonic circulation is conjectured to be driven by a net inflow through the Ulleung Interplain Gap, which serves as a conduit for the exchange of deep waters between the Japan Basin in the northern East Sea and the Ulleung Basin. Deep currents are characterized by a short correlation scale and the predominance of mesoscale variability with periods of 20–40 days. Seasonality of deep currents is indistinct, and the coupling of upper and deep circulation has not been clarified yet.     

Velocity dispersion profiles ofN-body simulations

The time evolution of the velocity dispersion as a function of radius, called v-profiles, of threeN-body simulations of Wielen are presented in units ofr/R _G (whereR _G is the gravitational or virial radius) and discussed as a function of mass sample. The evolution of the radial and tangential components of the velocity dispersion is discussed, and each v-profile is fitted to a simple power law in the halo (0.15r/R _G2.0). Several structural features appear at late time intervals: (a) an upturn in the radial component of v which occurs in a decreasing shell (closer to the core) in time, (b) the v-profile of the massive particles mimics that of the total sample, since equipartition of kinetic energy does not obtain, and (c) a local minimum atr0.3–0.5R _G appears in one model which coincides with the local minimum in the number density profiles and possibly with feature (a).The line-of-sight v-profile, called LS-profile, of each model as a function of time and mass sample are also presented and discussed. They contain the same structural features as the v-profiles. Projection factors at small radii are also discussed. The LS-profiles of the models can be compared with the observed velocity dispersion profiles of clusters of galaxies in Struble (1979a).     

Use of radio-occultation data for ionospheric imaging during the April 2002 disturbances

In 1994, Hajj et al. (1994) proposed the use of radio occultation data in ionospheric imaging. The advantages gained by including this data source are examined in this paper. Many data sources including ground-based and satellite-based observations are available for the events of the April 2002 ionospheric disturbance. This period has been chosen to study simultaneous images of the disturbed ionosphere over the USA and Europe. A 4D tomographic imaging technique known as Multi-instrument Data Analysis System (MIDAS) (Mitchell and Spencer, 2003) is applied in this study. The primary purpose of the study is to compare images produced with and without the use of radio-occultation data. The work investigates whether GPS occultation combined with ground-based GPS data improves the determination of peak height and peak density in the images. The results indicate that the occultation data improve both the peak height and the peak density in the images. The use of ionosonde data is also examined and the results are compared between the USA and Europe.