The statistical relationship between unconfined compressive strengths and the frequency distributions of slope gradients — A case study in northern Hungary

This paper focuses on the question of whether there is a deterministic connection between the slope gradient and unconfined compression strength (UCS) as a lithological factor and on describing the nature of this connection. Moreover, the authors determined the sensitive statistical parameters in the statistical surface analyses. The surface analyses were carried out in an area extending over 1500 km² in northern Hungary and containing parts of the uplifted Palaeozoic and Mesozoic basement and the semi-consolidated material of the Palaeogene and Neogene molasse sediments.The 67 geological formations of the area were grouped into 10 petrophysical categories characterised by unconfined compressive strength as a petrophysical parameter. The geological database was the digitalized geological map of North Hungarian Region (1 : 100 000). The digital topographic database was based on 10 m contour lines of 1 : 50 000 maps, the digital elevation model was generated by kriging interpolation. Three topographic models were created with resolutions of 25 × 25, 50 × 50 and 100 × 100 m per pixels.Evident correlation can be shown between the UCS and the relative frequency of the slope gradient. The adequate regression procedure is the power regression for low slope category values while logarithmic regression is applicable at high slope angles. Based on the characteristic of the relationship and the value of r², slope category intervals can be identified the relative frequency of which is proven to be determined by the UCS. These intervals are found to be between 4–10%, 10–16%, 16–22%, 22–44% and over 44%.Using the determination equations of slope gradient between 4–10% and over 44%, the UCS of the bedrock can be calculated approximately as the average value of the two calculated results. So the quotient of the frequency of these two category intervals can be regarded as an important morphometric index for a given bedrock.From the aspect of petrophysical characteristics, the rock with UCS between 6 and 86 MPa were proven to be deterministic for the slope development i.e. in the determination of the slope category frequencies. Applying the relative frequency of slope gradients a relative erosion resistance of the petrophysical categories can be calculated.Considering the determination coefficients, among the statistical parameters of the distribution of slope category values the standard deviation, mode, mean and median proved to be determined by the UCS of the bedrock.     

Magmatic and phreatomagmatic volcanic activity at Mt. Takahe, West Antarctica, based on tephra layers in the Byrd ice core and field observations at Mt. Takahe

The morphology, grain size characteristics and composition of ash particles in 30 ka to 150 ka tephra layers from the Byrd ice core were examined to characterize the eruptions which produced them and to test the suggestion that they were erupted from Mt. Takahe, a shield volcano in Marie Byrd Land, West Antarctica. Volcanic deposits at Mt. Takahe were examined for evidence of recent activity which could correlate with the tephra layers in the ice core.Coarse- and fine-ash layers have been recognized in the Byrd ice core. The coarse-ash layers have a higher mass concentration than the fine-ash layers and are characterized by fresh glass shards > 50 μm diameter, many containing elongate pipe vesicles. The fine-ash layers have a lower mass concentration and contain a greater variety of particles, typically < 20 μm diameter. Many of these particles are aggregate grains composed of glass and crystal fragments showing S and Cl surface alteration. The grain-size distributions of the coarse and fine-ash layers overlap, in part because of the aggregate nature of grains in the fine-ash layers. The coarse-ash layers are interpreted as having formed by magmatic eruption whereas the fine-ash layers are believed to be hydrovolcanic in origin.Mt. Takahe is the favored source for the tephra because: (a) chemical analyses of samples from the volcano are distinctive, being peralkaline trachyte, and similar in composition to the analyzed tephra; (b) Mt. Takahe is a young volcano (< 0.3 Ma); (c) pyroclastic deposits on Mt. Takahe indicate styles of eruption similar to that inferred for the ice core tephra; and (d) Mt. Takahe is only about 350 km from the calculated site of tephra deposition.A speculative eruptive history for Mt. Takahe is established by combining observations from Mt. Takahe and the Byrd ice core tephra. Initial eruptions at Mt. Takahe were subglacial and then graded into alternating subaerial and subglacial activity. The tephra suggest alternating subaerial magmatic and hydrovolcanic eruptions from 30 to 20 ka B.P., followed by a sustained period of hydrovolcanic eruptions from 20 to 14 ka B.P., which peaked at 18 ka B.P.     

Are secular variations in seawater chemistry reflected in the compositions of basinal brines?

It has been proposed that brines in Phanerozoic sedimentary basins inherited their chemistries and salinities from evaporated paleoseawaters during times when the world oceans were Ca-rich and SO₄-poor, such as the Silurian and Devonian. However, the compositions of typical Silurian and Devonian-hosted brines in the Illinois and Michigan basins show significant deviations from calculated Silurian seawater evaporation trends, reflecting instead, diagenetic control of compositions. In addition, brines in many basins show evidence for the dissolution of halite being an important source of salinity in addition to, or instead of, evaporated seawater. As long as there is halite present, generation of salinity could continue to occur long after the deposition of evaporites and the influx of evaporated seawater. Thus, even the concept of assigning an age to a basinal brine is problematic given the dynamics of fluid flow, mixing, and solute transport which can occur in sedimentary sequences.     

Analysis of Patterns in Diadromous Fish Distributions Using GIS

Understanding the factors limiting migratory behaviour is fundamental to conservation of diadromous fish. Applications of indices of habitat suitability are problematic for diadromous fish because fish presence and abundance in relation to habitat quality are confounded by barriers to fish migration. An alternative approach is to assess diadromous fish distributions in proportion to distance inland and altitude above mean sea level, and subsequently generate trajectories for the various species. This approach, however, may be problematic. We show that river distance inland and elevation are only weakly correlated in our study area. Thus, in areas where steep slopes are not encountered, fish migrations to significant elevations and inland distances can be expected. In other areas, coastal cliffs and geologic fault lines provide for steep stream gradients close to the sea, and fish do not migrate far inland. To solve this issue, we developed methods for improving species trajectory approaches to explain the distribution of diadromous fish using a GIS. We adjusted distance and altitude categories so that each stratum was represented by the same number of site records, with flexible intervals for each stratum. For species capable of forming land‐locked populations we manipulated input values for elevation and river distance inland to account for migrations from lakes, rather than sea. Additionally, a new GIS derived variable was introduced to better explain the distribution of diadromous fish; the maximum stream slope a fish would encounter during upstream migration. This new slope variable, independent of distance inland and elevation, is likely to be a better predictor of migratory fish occurrences than elevation above mean sea level, as the different species will have different slope‐thresholds that they can overcome.     

Structure of a sunspot

From enlargements of patrol photographs of the disk passage of the sunspot of July 20 – August 2, 1966, intensity profiles across the spot are obtained at several positions near the disk-center and at each limb. It is found that these profiles show asymmetric features near each limb (increasingly sharp limb-side penumbra and poorly resolved disk-side penumbra) which are similar to those reported in Paper III of this series. It is suggested that these profile asymmetries are the essential feature of the center-limb variations in the appearance of a sunspot which have become known as the Wilson effect.Conventionally the Wilson effect is described as the extreme foreshortening and eventual disappearance of the disk-side penumbra and, recently, Suzuki has referred to this as the occultation of the penumbra by the photosphere. We find no evidence at all for the disappearance of the disk-side penumbra at the limb in this spot. Defining half-height points on the profile curves as the umbral and penumbral boundaries, we find that, near the west limb where the spot is stable and regular, the limb-side penumbra increases by about 10% at the expense of the umbra. This result qualitatively supports the results reported in Paper III although it is smaller in magnitude.Other observations of sunspots which appear to exhibit the conventional Wilson effect are discussed and it is concluded that in no case yet published is the resolution and seeing of sufficient quality to demonstrate unambiguously the disappearance of the disk-side penumbra.     

A geochemical and isotopic assessment of hydraulic connectivity of a stacked aquifer system in the Lisbon Valley,Utah (USA), and critical evaluation of environmental tracers

Hydrogeology Journal - This study investigates hydraulic connectivity of a stacked aquifer system in the Lisbon Valley of southeastern Utah (USA), within the Paradox Basin, where numerous faults...     

Commingled Fluids in Abandoned Boreholes: Proximity Analysis of a Hidden Liability

The interactions between old abandoned wellbores of suspect well integrity with hydraulic fracturing (HF), enhanced oil recovery (EOR), or salt water disposal (SWD) operations can result in upward leakage of deep aqueous liquids into overlying aquifers. This potential for upward fluid migration is largely unquantified as monitoring abandoned wells is rarely done, and leakage may go unnoticed especially when in deeper aquifers. This study performs a proximity analysis between old abandoned wells and HF, EOR, and SWD wells, and identifies commingled old abandoned wellbores, which are those wells where groundwater may flow from one aquifer to one or more other aquifers, to identify the locations with the greatest potential for upward aqueous fluid migration at three study sites in the Western Canadian Sedimentary Basin. Our analysis indicates that at all three study sites there are several locations where HF, EOR, or SWD operations are located in close proximity to a given old abandoned well. Much of this overlap occurs in formations above typically produced hydrocarbon reservoirs but below exploited potable aquifers, otherwise known as the intermediate zone, which is often connected between abandonment plugs in old abandoned wells. Information on the intermediate zone is often lacking, and this study suggests that unanticipated alterations to groundwater flow systems within the intermediate zone may be occurring. Results indicate the need for more field-based research on the intermediate zone.     

The effects of oil exploration and production in the Fladen Ground: composition and concentration of hydrocarbons in sediment samples collected during 2001 and their comparison with sediment samples collected in 1989

Due to the potentially accumulative nature of the Fladen Ground, an area of intense oil activity in the North Sea, a survey was carried out in 1989 to map the distribution of contamination in relation to these oil activities. All the sediments collected were screened by ultraviolet fluorescence (UVF) for polycyclic aromatic hydrocarbons (PAHs) and selected samples were analysed for n-alkanes (by GC-FID), PAHs and biomarkers (by GC-MSD). This survey was repeated in 2001, with all the 1989 sites being resampled. All of these sediments were analysed for UVF oil equivalents, PAHs, n-alkanes and biomarkers. The concentrations of these parameters decreased between 1989 and 2001, with average decreases ranging from 43% to 88%. In addition, no significant difference was found, for all the parameters, between near field (<5 km from an oil installation) and far field (>5 km from an oil installation) sites in 2001 indicating that the Fladen Ground is approaching a 'steady state' or background concentration for contamination.     

Different levels of mussel (Mytilus edulis) DNA strand breaks following chronic field and acute laboratory exposure to polycyclic aromatic hydrocarbons

Levels of polycyclic aromatic hydrocarbons (PAHs) including benzo[a]pyrene (B[a]P) were at least seven-fold higher in mussels sampled from a polluted site (Loch Leven, in Scotland, UK) compared to a nearby clean reference site (Loch Etive) throughout the year 2000. Levels of DNA strand breaks (alkaline COMET assay) using both gill and digestive gland nuclei were similar at both sites despite the difference in contaminant load (total PAH). In contrast, mussels collected from a reference site (Port Quin, Cornwall, UK) had an increase in DNA strand breaks in digestive gland cells following laboratory exposure to B[a]P-dosed Isochrysis galbana. However, after 14 days high dose (20 ppb-exposed diet) animals had returned to levels similar to the controls. There was no evidence of increased necrosis or apoptosis after treatments. The results from these two studies suggest that an adaptive response may prevent ongoing DNA damage in mussels exposed to high levels of B[a]P and PAH contamination.