Uranium and thorium isotope concentrations in foraminiferal calcite

Uranium and thorium isotope activities were measured by isotope dilution alpha spectrometry in four late Pleistocene and Holocene foraminiferal calcite samples. Sample cleaning methods were utilized to separate calcite tests from contaminating clay and surface oxide coatings. The maximum concentration of lattice bound uranium is 0.023 ppm (10 × 10^?9 moles U/mole Ca), consistent with the lowest reported value, 0.025 ppm [1].²³⁰Th/²³⁴U activity ratios in samples cleaned as described above are much greater than one, indicating that the cleaning methods used do not effectively remove²³⁰Th from the surfaces of the calcite. The upper limit for lattice bound²³²Th is 0.039 ppm (17 × 10^?9 moles Th/mole Ca).     

Pro-Am astronomy

The long history of close collaboration between amateur and professional in astronomy continued with an RAS discussion meeting held in September. Margaret Penston reports on the lively and enthusiastic discussion.     

Cases-97: Late-Morning Warming And Moistening Of The Convective Boundary Layer Over The Walnut River Watershed

Aircraft, radiosonde, surface-flux, and boundary-layer windprofiler data from the Cooperative Atmosphere Surface Exchange Study's 1997 field project, CASES-97, are combined with synoptic data to study the evolution of the vertically-averaged mixed-layerpotential temperature []and mixing-ratio [Q] onthree nearly-cloudless days from 1000 CST to 1200CST (local noon is approximately 1230 CST). This was achieved through examination of the terms in the time-tendency (`budget')equations for []and [Q]. We estimate three of the terms –local time rate of change, vertical flux divergence, andhorizontal advection. For the [Q]-budget, vertical flux divergence usually dominates, buthorizontal advection is significant on one of the three days. The [Q]-budget balances for two of the three days to within the large experimental error. For the -budget,vertical flux divergence accounts for most of the morningwarming, with horizontal advection of secondary importance.The residual in the -budget has the same sign for all three days, indicating that not all the heating is accounted for. We can balance the []-budgets to within experimental error on two of the three days by correcting the vertical-flux divergence for apparent low biases in the flux measurements of one of the aircraft and in the surface fluxes, and accounting for direct heating of the mixed layer by radiative flux divergence allowing for the effects of carbonaceous aerosols. The [];-budget with these corrections also balances on the third day if horizontal gradients from synoptic maps are used to estimate the horizontal advection. However, the corrected budget for this day does not balance if the horizontal gradient in the advection term is estimated using CASES-97aircraft and radiosondes; we suggest that persistent mesoscale circulations led to an overestimate of the horizontal gradient andhence horizontal advection.     

CO2 Snow on Mars and Early Earth: Experimental Constraints

Greenhouse warming due to carbon dioxide atmospheres may be responsible for maintaining the early Earth's surface temperature above freezing and may even have allowed for liquid water on early Mars. However, the high levels of CO₂ required for such warming should have also resulted in the formation of CO₂ clouds. These clouds, depending on their particle size, could lead to either warming or cooling. The particle size in turn is determined by the nucleation and growth conditions. Here we present laboratory studies of the nucleation and growth of carbon dioxide on water ice under martian atmospheric conditions. We find that a critical saturation, S=1.34, is required for nucleation, corresponding to a contact parameter between solid water and solid carbon dioxide of m=0.95. We also find that after nucleation occurs, growth of CO₂ is very rapid, and we report the growth rates at a number of supersaturations. Because growth would be expected to continue until the CO₂ pressure is lowered to its vapor pressure, we expect particles larger than those being currently suggested for the present and past martian atmospheres. Using this information in a microphysical model described in a companion paper, we find that CO₂ clouds are best described as “snow,” having a relatively small number of large particles.     

天坑形成的水力机制

大部分情况下,天坑都是现代暗河通道洞顶塌陷而成.塌陷的扩大造成暗河通道的阻塞和改道,使得水力梯度变陡,溶蚀和侵蚀增强.可以说,天坑大部分空间体积的形成都是地下河大规模搬运崩塌堆积物的结果.强烈变化的大流量是搬运崩塌堆积的最佳条件,而暗河通道的改道和扩大又进一步加强了塌陷作用.与区域裂隙模式不同,新的裂隙随着崩塌周围应力释放而扩张.与原始洞穴通道形成相比,大规模天坑的形成都是源于这些作用.     

A normative calculation technique for determining opal in deep-sea sediments

The opal content of deep-sea sediment can be estimated by subtracting non-biogenic silica, calculated from the aluminum and magnesium concentrations in the sediment, from the total silica content of the samples. Unlike most previously described methods, this calculation is capable of yielding reliable estimates of opal in pre-Pleistocene sediments because it is unaffected by structural changes that take place in opal as it ages.     

Landscape-scale analysis of ecosystem risk and returns: A new tool for ICZM

Management of the coastal zone often focuses on “islands” of high value ecosystems, in terms of economic value or conservation. However, integrated management requires landscape-level analysis of all ecosystem values. The biodiversity portfolio analysis (BPA) method is derived from the logic used in share (equity) portfolio management in terms of balancing within a portfolio the returns with the risks. Optimising the returns from a share portfolio, or a suite of ecosystems in a landscape, is dependent on the relationship between the units in terms of risk and return. Three case studies are then presented to test the applicability of the BPA method at the international (North West Europe), regional (Durham Heritage Coast, UK) and local (part of South Uist, Outer Hebrides, UK) spatial scale. The Biodiversity Portfolio Analysis for NW Europe showed that risk and return were highly correlated in the studied Member States. The ranking of risk and return, with the highest first, was Ireland > UK > France=Netherlands > Belgium. For these Member States the risks to ecosystem service provision were positively correlated with GNI (r=0.97, P<0.01); suggesting that the higher the economic importance of coastal and marine resources in a Member State the more at risk the resources are. The regional and local case studies were more focussed on providing information on which to base Integrated Coastal Zone Management (ICZM) decision making; both case studies used stakeholder participation to determine risks and returns. The conclusions from these two case studies show how the BPA method can be useful in terms of setting ICZM priorities and in addressing local coastal issues. The BPA involves making a number of assumptions, however, it does provide coastal managers with a potential tool to strategically plan due to increased awareness of the interaction between the ecosystems in the portfolio.There is a need for such techniques, which involve stakeholder participation and which create objective outcomes, to support the implementation of ICZM.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Climatic Trends and Temporal Patterns of Phytoplankton Composition, Abundance, and Succession in the Indian River Lagoon, Florida, USA

This paper describes the results of 10 years of water quality monitoring in the Indian River Lagoon Florida, with special emphasis on the relationships between trends in climatic conditions and the distribution, composition, and abundance of the phytoplankton community. The Indian River Lagoon, which spans 220 km of Florida’s east coast, is a region of particular concern because of the rapid rate of human development throughout the region and the hydrologically restricted character of the lagoon, which heightens the potential for algal bloom. Water sampling was carried out on a monthly to twice-monthly basis at six sites located in the northern and central lagoon. The 10-year study included both extended periods of below and above average rainfall. A number of ecologically distinct regions exist within the lagoon, which differ considerably in water exchange properties and watershed inputs. The northern lagoon is characterized by longer water residence times, lower phosphorus concentrations, higher nitrogen concentrations, and more stable salinity conditions than the central lagoon. Mean phytoplankton biovolumes were substantially higher at the sites in the northern lagoon than at the sites in the central lagoon, and algal blooms were more common and intense in the former region. Inter-annual patterns of phytoplankton biovolume were also different in the northern and central lagoon. In the northern lagoon, phytoplankton biovolumes were lowest during the drought period, from the autumn of 1998 to the spring of 2001. By contrast, algal bloom events in the central lagoon were not only less frequent but were not tied to periods of high rainfall. The most widespread and common bloom formers were the potentially toxic dinoflagellate Pyrodinium bahamense var. bahamense and two centric diatoms, Dactyliosolen fragilissimus and Cerataulina pelagica. Many of the biovolume peaks observed over the study period were attributable to these three species. The results of time series modeling of phytoplankton dynamics further highlighted the disparities between the two regions of the lagoon in terms of the suite of parameters that best predict the observed trends in the biomass of phytoplankton. Overall, the outcome of this initial modeling effort in the Indian River Lagoon suggests that time series approaches can help define the factors that influence phytoplankton dynamics.     

Warm‐temperate,marine, carbonate sedimentation in an Early Miocene,tide‐influenced,incised valley; Provence,south‐east France

The Saumane‐Venasque compound palaeovalley succession accumulated in a strongly tide‐influenced embayment or estuary. Warm‐temperate normal marine to brackish conditions led to deposition of extensive cross‐bedded biofragmental calcarenites. Echinoids, bryozoans, coralline algae, barnacles and benthic foraminifera were produced in seagrass meadows, on rocky substrates colonized by macroalgae and within subaqueous dune fields. There are two sequences, S1 and S2, the first of which contains three high‐frequency sequences (S1a, S1b and S1c). Sequence 1 is largely confined to the palaeovalley with its upper part covering interfluves. Each of these has a similar upward succession of deposits that includes: (i) a basal erosional surface that is bored and glauconitized; (ii) a discontinuous lagoonal lime mudstone or wackestone; (iii) a thin conglomerate generated by tidal ravinement; (iv) a transgressive systems tract series of cross‐bedded calcarenites; (v) a maximum flooding interval of argillaceous, muddy quartzose, open‐marine limestones; and (vi) a thin highstand systems tract of fine‐grained calcarenite. Tidal currents during stages S1a, S1b and S1c were accentuated by the constricted valley topography, whereas basin‐scale factors enhanced tidal currents during the deposition of S2. The upper part of the succession in all but S1c has been removed by later erosion. There is an overall upward temporal change with quartz, barnacles, encrusting corallines and epifaunal echinoids decreasing but bryozoans, articulated corallines and infaunal echinoids increasing. This trend is interpreted to be the result of changing oceanographic conditions as the valley was filled, bathymetric relief was reduced, rocky substrates were replaced as carbonate factories by seagrass meadows and subaqueous dunes, and the setting became progressively less confined and more open marine. These limestones are characteristic of a suite of similar cool‐water calcareous sand bodies in environments with little siliciclastic or fresh water input during times of high‐amplitude sea‐level change wherein complex inboard antecedent topography was flooded by a rising ocean.