Sector zoned aegirine from the Ilímaussaq alkaline intrusion,South Greenland

Sector zoned aegirine crystals occur in the interstices of peralkaline nepheline syenites in Ilímaussaq. The crystals have grass-green [001] sectors enriched in Ca and Fe²⁺ (as CaFeSi₂O₆), Mn and Zr; pale green {010} sectors enriched in Al (as NaAlSi₂O₆); blue-green {110} sectors enriched in Ti (as NaTi_0.5Fe _0.5 ²⁺ Si₂O₆); and light green {100} sectors enriched in Fe₃₊ (as NaFe³⁺ Si₂O₆).The crystals grew in the liquid with a rate that did not exceed the diffusion rate of most elements in the liquid. However. Fe³⁺ seems to have had diffusion rates lower than the crystal growth rate, and this probably caused the development of some sectors enriched in acmite and others enriched in the hedenbergite component. For Al, Ti and Zr a crystal structural control is envisaged although a recent structure-based model for sector zoning fails to explain the efficient separation of these elements into different sectors.Three more occurrences of sector zoned aegirine are noted, all from peralkaline nepheline syenites. The phenomenon is probably more widespread than hitherto realised.Contribution to the mineralogy of Ilímaussaq no. 62     

Revising the ‘host country standard’ principle: a step for China to align its overseas investment with the Paris Agreement

ABSTRACT

China’s overseas investment flows (US$ 183 billion) and stock (US$ 4.7 trillion) reached a record peak in 2016, second only to those of the US. A major cause for concern lies in the environmental sustainability of China’s overseas investment portfolio, which is compounded by the lack of transparency of China’s main development finance arms. We intend in this paper to give an update on the magnitude of green finance in China’s overseas investment and development finance portfolio on the basis of the best available estimates, and to put these figures into a broader perspective of multilateral development banks’ commitments and practices to combat climate change. We derive practical policy recommendations that Chinese development banks could take to further align China’s overseas investment with the 2°C target of the Paris Agreement, with the first step being to revise the ‘host country standard’ principle, to ensure that Chinese development banks use the most stringent of the two environmental standards, abroad or at home.

Key policy insights

• Chinese development banks lend, give or invest between US$ 38 billion and US$ 45 billion every year to developing countries, without either elaborating on, or integrating, the provisions of the Paris Agreement into their investment strategy.

• Regulations and safeguards are much more stringent for China’s domestic investment than for China’s overseas investment, and this stringency gap has been widening over recent years.

• As a step towards aligning Chinese overseas investment with the Paris Agreement, Chinese development banks could revise the ‘host country standard principle’. They could instead choose the highest among the two – recipient country or Chinese domestic – in terms of environmental stringency, consequently harmonizing overseas environmental regulation and safeguards with those that apply domestically.

     

A 10Be‐based reconstruction of the last deglaciation in southern Sweden

We present 23 cosmogenic surface exposure ages from 10 localities in southern Sweden. The new ¹⁰Be ages allow a direct correlation between the east and west coasts of southern Sweden, based on the same dating technique, and provide new information about the deglaciation of the Fennoscandian Ice Sheet in the circum‐Baltic area. In western Skåne, southernmost Sweden, a single cosmogenic surface exposure sample gave an age of 16.8±1.0 ka, whereas two samples from the central part of Skåne gave ages of 17.0±0.9 and 14.1±0.8 ka. Further northeast, in southern Småland, two localities gave ages ranging from 15.2±0.8 to 16.9±0.9 ka (n=5) indicating a somewhat earlier deglaciation of the area than has previously been suggested. Our third locality, in S Småland, gave ages ranging from 10.2±0.5 to 18.4±1.6 ka (n=3), which are probably not representative of the timing of deglaciation. In central Småland one locality was dated to 14.5±0.8 ka (n=3), whereas our northernmost locality, situated in northern Småland, was dated to 13.8±0.8 ka (n=3). Samples from the island of Gotland suggest deglaciation before 13 ka ago. We combined the new ¹⁰Be ages with previously published deglaciation ages to constrain the deglaciation chronology of southern Sweden. The combined deglaciation chronology suggests a rather steady deglaciation in southern Sweden starting at c. 17.9 cal. ka BP in NW Skåne and reaching northern Småland, ～200 km further north, c. 13.8 ka ago. Overall the new deglaciation ages agree reasonably well with existing deglaciation chronologies, but suggest a somewhat earlier deglaciation in Småland.     

Combining the modified discrete element method with the virtual element method for fracturing of porous media

Simulation of fracturing processes in porous rocks can be divided into two main branches: (i) modeling the rock as a continuum enhanced with special features to account for fractures or (ii) modeling the rock by a discrete (or discontinuous) approach that describes the material directly as a collection of separate blocks or particles, e.g., as in the discrete element method (DEM). In the modified discrete element (MDEM) method, the effective forces between virtual particles are modified so that they reproduce the discretization of a first-order finite element method (FEM) for linear elasticity. This provides an expression of the virtual forces in terms of general Hook’s macro-parameters. Previously, MDEM has been formulated through an analogy with linear elements for FEM. We show the connection between MDEM and the virtual element method (VEM), which is a generalization of FEM to polyhedral grids. Unlike standard FEM, which computes strain-states in a reference space, MDEM and VEM compute stress-states directly in real space. This connection leads us to a new derivation of the MDEM method. Moreover, it enables a direct coupling between (M)DEM and domains modeled by a grid made of polyhedral cells. Thus, this approach makes it possible to combine fine-scale (M)DEM behavior near the fracturing region with linear elasticity on complex reservoir grids in the far-field region without regridding. To demonstrate the simulation of hydraulic fracturing, the coupled (M)DEM-VEM method is implemented using the Matlab Reservoir Simulation Toolbox (MRST) and linked to an industry-standard reservoir simulator. Similar approaches have been presented previously using standard FEM, but due to the similarities in the approaches of VEM and MDEM, our work provides a more uniform approach and extends these previous works to general polyhedral grids for the non-fracturing domain.     

Upper Cretaceous bottom current deposits,north-east Greenland

Reported ancient bottom current deposits in deep marine settings are scarce and most of them remain contentious. This study describes sedimentological, ichnological and petrographical characteristics of a drill core that covers ca 10 Myr of Upper Cretaceous stratigraphy at Hold with Hope, north-east Greenland. The core is divided into four facies associations, which are interpreted to reflect deposition from bottom currents, turbidity flows and hemipelagic settling in slope and/or near slope environments. The evidence for bottom current influence is three-fold. Firstly, pervasive indications of winnowing such as marine bioclast-rich lags and outsized clasts on ‘mud on mud’ contacts are suggestive of low-sediment concentration flows capable of transporting up to pebble-sized clasts. Common Mn–Fe–Mg rich carbonate matrix cements and various types of hiatal chemogenic lag deposits showing glauconite, apatite and carbonate clasts also point to condensation, prolonged exposure at the sediment–water interface and recurrent phases of sea-floor erosion. Secondly, such deposits can show indicators for tidal processes such as double mud-drapes, tangential bottom sets in dune-scale cross-bedding and cyclic rhythmites. Thirdly, inverse to normal grading at various scales is common in fully marine, commonly seafloor-derived sediments. Ichnological data indicate considerable taxonomic variability in the bottom current deposits, but recurrent fabrics are characteristically dominated by morphologically simple burrows such as Thalassinoides and Planolites, with secondary Phycosiphon, Nereites, Zoophycos and/or Chondrites. In general, opportunistic taxa are common whereas mature composite ichnofabrics are rare. The omission surfaces are locally burrowed with stiffground to firmground trace fossil suites. The results contribute to establishing sedimentological, ichnological and mineralogical criteria for recognition of bottom current deposits as well as to the understanding of the Late Cretaceous palaeoenvironmental evolution of the Arctic region.     

Late Quaternary biotic and abiotic controls on long-term sediment flux in a northern Australian tropical river system

The modern distribution of monsoonal rainforest in the Australian tropics is patchy and is mainly associated with river corridors and groundwater springs, which indicates a strong dependence on hydrologic and geomorphic conditions. While their present distribution is well known, very little data exists on past spatial and temporal dynamics of these ecosystems, or their medium- to longer-term controls. Factors such as (i) fire frequency and type, and/or (ii) hydroclimatic conditions (e.g. droughts) have been proposed to control riverine corridor rainforest extent. Recent observations, however, also suggest an additional (iii) geomorphic control induced by alluvial knickpoint migration. Sediment sequences provide valuable archives for the reconstruction of longer-term (a) floodplain sedimentary dynamics, (b) local vegetation history, and (c) catchment-wide fire histories. This study investigates such a sediment sequence at Wangi Creek, and shows that a phase of aggradation, lasting ~4000 years, was recently disrupted by channel incision and floodplain erosion. The aggradational phase is characterized by sand deposition with average vertical floodplain accretion rates of 0.8 cm/yr and includes phases of soil development. The recent incisional phase has changed hydro-geomorphic conditions and caused widespread degradation of vegetation, erosion and lowering of the macro-channel surface. While there is no evidence in our data for an erosional event of similar magnitude since the onset of late Holocene floodplain aggradation, Wangi Creek experienced significant erosion and incision immediately before ~4000 years, providing the first evidence for a tropical cut-and-fill river system. We hence argue that phases of aggradation mainly controlled by biotic processes alternate and depend on feedbacks with incision phases controlled mainly by abiotic processes. The results show that eco-hydro-geomorphic feedbacks may play a crucial role in the medium- to longer-term history of tropical fluvial systems and need to be considered when interpreting fluvial archives with regards to climate, fire or human induced change. © 2019 John Wiley & Sons, Ltd.     

Impact melt rocks from the Late Paleocene Hiawatha impact structure,northwest Greenland

Impact melt rocks formed during hypervelocity impact events are ideal for studying impact structures. Here, we describe impact melt rock samples collected proximal to the 31 km wide 58 Ma Hiawatha impact structure, northwest Greenland, which is completely covered by the Greenland Ice Sheet. The melt rocks contain diagnostic shock indicators (e.g., planar deformation features [PDF] in quartz and shocked zircon) and form three groups based on melt textures and chemistry: (i) hypocrystalline, (ii) glassy, and (iii) carbonate-based melt rocks. The exposed foreland directly in front of the structure consists of metasedimentary successions and igneous plutons; however, the carbonate-based impactites indicate a mixed target sequence with a significant carbonate-rich component. Well-preserved organic material in some melt rocks indicates that North Greenland at the time of impact was host to abundant organic material, likely a dense high-latitude temperate forest. Geochemical signatures of platinum-group elements in selected samples indicate an extraterrestrial component and support previous identification of a highly fractionated iron impactor in glaciofluvial sand. Our results illustrate the possibility to study impact structures hidden beneath a thick ice sheet based on transported samples and this opens a new avenue for identifying other potential impact craters in Greenland and Antarctica.