Uranium-lead isotope systematics of Mars inferred from the basaltic shergottite QUE 94201

Uranium-lead ratios (commonly represented as ²³⁸U/²⁰⁴Pb = μ) calculated for the sources of martian basalts preserve a record of petrogenetic processes that were active during early planetary differentiation and formation of martian geochemical reservoirs. To better define the range of μ values represented by the source regions of martian basalts, we completed U-Pb elemental and isotopic analyses on whole rock, mineral and leachate fractions from the martian meteorite Queen Alexandra Range 94201 (QUE 94201). The whole rock and silicate mineral fractions have unradiogenic Pb isotopic compositions that define a narrow range (²⁰⁶Pb/²⁰⁴Pb = 11.16-11.61). In contrast, the Pb isotopic compositions of weak HCl leachates are more variable and radiogenic. The intersection of the QUE 94201 data array with terrestrial Pb in ²⁰⁶Pb/²⁰⁴Pb-²⁰⁷Pb/²⁰⁴Pb-²⁰⁸Pb/²⁰⁴Pb compositional space is consistent with varying amounts of terrestrial contamination in these fractions. We calculate that only 1-7% contamination is present in the purified silicate mineral and whole rock fractions, whereas the HCl leachates contain up to 86% terrestrial Pb. This terrestrial Pb contamination generated a ²⁰⁶Pb-²⁰⁷Pb array in the QUE fractions that appears to represent an ancient age, which contrasts with a much younger crystallization age of 327 ± 10 Ma derived from Rb-Sr and Sm-Nd isochrons (Borg L. E., Nyquist L. E., Taylor L. A., Wiesmann H. and Shih C. -Y. (1997) Constraints on Martian differentiation processes from Rb-Sr and Sm-Nd isotopic analyses of the basaltic shergottite QUE 94201. Geochim. Cosmochim. Acta61, 4915-4931). Despite the contamination, and accepting 327 ± 10 Ma as the crystallization age, we use the U-Pb data to determine the initial ²⁰⁶Pb/²⁰⁴Pb of QUE 94201 to be 11.086 ± 0.008 and to calculate the μ value of its mantle source to be 1.82 ± 0.01. The μ value calculated for the QUE 94201 source is the lowest determined for any martian basalt source, and, when compared to the highest values determined for martian basalt sources, indicates that μ values in martian source reservoirs vary by at least a factor of two. Additionally, the range of source μ values indicates that the μ value of bulk silicate Mars is approximately three. The amount of variation in the μ values of the mantle sources (μ ∼ 2-4) is greater than can be explained by igneous processes involving silicate phases alone. We suggest the possibility that a small amount of sulfide crystallization may generate greater extents of U-Pb fractionation during formation of the mantle sources of martian basalts.     

Spalling Experiments on Large Hard Rock Specimens

Specimens of coarse-grained Äspö diorite were axially compressed to observe stress-induced spalling. The specimens had a novel design characterized by two manufactured large radius notches on opposite sides. The tangential stress occurring in the notches aimed to represent the tangential loading around a circular opening. Fracture stages were monitored by acoustic emission measurements. Rock chips were formed similar to those found in situ, which indicates a similar fracture process. Slabs were cut out from the specimens and impregnated using a fluorescent material to visualize the cracks. The cracks were subsequently examined by the naked eye and by means of microscopy images, from which fracture paths could be identified and related to different minerals and their crystallographic orientations. The microscopy analyses showed how the stress field and the microstructure interact. Parallel cracks were formed 2–4 mm below the surface, sub-parallel to the direction of the maximum principal stress. The crack initiation, the roles of minerals such as feldspar, biotite and quartz and their grain boundaries and crystallographic directions are thoroughly studied and discussed in this paper. Scale effects, which relate to the stress gradient and microstructure, are discussed.     

High‐resolution reconstruction of a coastal barrier system: impact of Holocene sea‐level change

This study presents a detailed reconstruction of the sedimentary effects of Holocene sea‐level rise on a modern coastal barrier system. Increasing concern over the evolution of coastal barrier systems due to future accelerated rates of sea‐level rise calls for a better understanding of coastal barrier response to sea‐level changes. The complex evolution and sequence stratigraphic framework of the investigated coastal barrier system is reconstructed using facies analysis, high‐resolution optically stimulated luminescence and radiocarbon dating. During the formation of the coastal barrier system starting 8 to 7 ka rapid relative sea‐level rise outpaced sediment accumulation. Not before rates of relative sea‐level rise had decreased to ca 2 mm yr^?1 did sediment accumulation outpace sea‐level rise. From ca 5·5 ka, rates of regionally averaged sediment accumulation increased to 4·3 mm yr^?1 and the back‐barrier basin was filled in. This increase in sediment accumulation resulted from retreat of the barrier island and probably also due to formation of a tidal inlet close to the study area. Continued transgression and shoreface retreat created a distinct hiatus and wave ravinement surface in the seaward part of the coastal barrier system before the barrier shoreline stabilized between 5·0 ka and 4·5 ka. Back‐barrier shoreline erosion due to sediment starvation in the back‐barrier basin was pronounced from 4·5 to 2·5 ka but, in the last 2·5 kyr, barrier sedimentation has kept up with and outpaced sea‐level. In the last 0·4 kyr the coastal barrier system has been prograding episodically. Sediment accumulation shows considerable variation, with periods of rapid sediment deposition and periods of non‐deposition or erosion resulting in a highly punctuated sediment record. The study demonstrates how core‐based facies interpretations supported by a high‐resolution chronology and a well‐documented sea‐level history allow identification of depositional environments, erosion surfaces and hiatuses within a very homogeneous stratigraphy, and allow a detailed temporal reconstruction of a coastal barrier system in relation to sea‐level rise and sediment supply.     

Global climate policy and deep decarbonization of energy-intensive industries

If we are to limit global warming to 2 °C, all sectors in all countries must reduce their emissions of GHGs to zero not later than 2060–2080. Zero-emission options have been less explored and are less developed in the energy-intensive basic materials industries than in other sectors. Current climate policies have not yet motivated major efforts to decarbonize this sector, and it has been largely protected from climate policy due to the perceived risks of carbon leakage and a focus on short-term reduction targets to 2020. We argue that the future global climate policy regime must develop along three interlinked and strategic lines to facilitate a deep decarbonization of energy-intensive industries. First, the principle of common but differentiated responsibility must be reinterpreted to allow for a dialogue on fairness and the right to development in relation to industry. Second, a greater focus on the development, deployment and transfer of technology in this sector is called for. Third, the potential conflicts between current free trade regimes and motivated industrial policies for deep decarbonization must be resolved. One way forward is to revisit the idea of sectoral approaches with a broader scope, including not only emission reductions, but recognizing the full complexity of low-carbon transitions in energy-intensive industries. A new approach could engage industrial stakeholders, support technology research, development and demonstration and facilitate deployment through reducing the risk for investors. The Paris Agreement allows the idea of sectoral approaches to be revisited in the interests of reaching our common climate goals.

Policy relevance

Deep decarbonization of energy-intensive industries will be necessary to meet the 2 °C target. This requires major innovation efforts over a long period. Energy-intensive industries face unique challenges from both innovation and technical perspectives due to the large scale of facilities, the character of their global markets and the potentially high mitigation costs. This article addresses these challenges and discusses ways in which the global climate policy framework should be developed after the Paris Agreement to better support transformative change in the energy-intensive industries.     

The relationship betweenG andh in a closed Universe

In a closed expanding-contracting Universe, matter will be subject to an inward acceleration large enough to prevent perpetual expansion. A closed Universe must also perform a simple harmonic motion, which might consist either of one single cycle or of an infinite series of oscillations about a central point. It is the purpose of this study to find the rate ofa ₀, the cosmic acceleration, from which the gravitational constantG can be determined. It will be shown from Ampère's equation and Planck's radiation law that it is possible to derivea ₀=7.623×10^–12 ms^–2, a value which also conforms with the uncertainty principle. The relationship betweena ₀ and electromagnetic radiation is based on the concept that charges (such as electrons) must emit radiation while accelerating. The rate ofa ₀ yields a universal gravitational constant ofG=6.645×10^–11 N m² kg^–2.     

Statistical arguments for asteroidal jet streams

The distribution of asteroid orbits in space is studied and a detailed investigation for Hirayama's Flora family is presented. Some tendencies to (5-dimensional) clustering are found by means of comparing actual with random distribution simulated on a computer.     

The ellipsoidal corrections to the topographic geoid effects

The topographic effects by Stokes formula are typically considered for a spherical approximation of sea level. For more precise determination of the geoid, sea level is better approximated by an ellipsoid, which justifies the consideration of the ellipsoidal corrections of topographic effects for improved geoid solutions. The aim of this study is to estimate the ellipsoidal effects of the combined topographic correction (direct plus indirect topographic effects) and the downward continuation effect. It is concluded that the ellipsoidal correction to the combined topographic effect on the geoid height is far less than 1 mm. On the contrary, the ellipsoidal correction to the effect of downward continuation of gravity anomaly to sea level may be significant at the 1-cm level in mountainous regions. Nevertheless, if Stokes formula is modified and the integration of gravity anomalies is limited to a cap of a few degrees radius around the computation point, nor this effect is likely to be significant.AcknowledgementsThe author is grateful for constructive remarks by J Ågren and the three reviewers.