Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.     

Classifying knowledge on climate change impacts, adaptation, and vulnerability in Europe for informing adaptation research and decision-making: A conceptual meta-analysis

Knowledge on climate change impacts, adaptation, and vulnerability is fragmented, because it is found in disparate case studies which use inconsistent terminology and focus on distinct aspects relevant to adaptation. While large-scale syntheses such as the Assessment Reports of the Intergovernmental Panel on Climate Change provide a high level overview and are useful for international decision-making, there is a need for systematic and flexible access to this research-based knowledge in order to aid future adaptation research and decision-making. Against this background, we present a ‘conceptual’ meta-analysis, a novel approach to meta-analyse studies on climate change impacts, adaptation, and vulnerability in Europe. The meta-analysis results in a classification scheme for relating the diverse studies. This scheme consists of (i) a classification of studies according to the type of adaptation-relevant results they produce and (ii) a hierarchical classification of the regional and thematic context of studies. The implementation of this scheme, for example in the form of a database, overcomes some of the identified gaps of current adaptation knowledge representation. We furthermore present a quantitative analysis of the classified studies that exemplifies how the developed classification scheme can be applied to get a systematic and quantitative overview of the knowledge they contain. Thus, the conceptual meta-analysis and the classification scheme represent a first step towards a systematisation of knowledge on climate change impacts, adaptation, and vulnerability and may be seen as a useful complement to qualitative literature reviews.     

Quantitative multi-risk analysis for natural hazards: a framework for multi-risk modelling

This paper introduces a generic framework for multi-risk modelling developed in the project ‘Regional RiskScape’ by the Research Organizations GNS Science and the National Institute of Water and Atmospheric Research Ltd. (NIWA) in New Zealand. Our goal was to develop a generic technology for modelling risks from different natural hazards and for various elements at risk. The technical framework is not dependent on the specific nature of the individual hazard nor the vulnerability and the type of the individual assets. Based on this generic framework, a software prototype has been developed, which is capable of ‘plugging in’ various natural hazards and assets without reconfiguring or adapting the generic software framework. To achieve that, we developed a set of standards for treating the fundamental components of a risk model: hazards, assets (elements at risk) and vulnerability models (or fragility functions). Thus, the developed prototype system is able to accommodate any hazard, asset or fragility model, which is provided to the system according to that standard. The software prototype was tested by modelling earthquake, volcanic ashfall, flood, wind, and tsunami risks for several urban centres and small communities in New Zealand.     

Vertical geochemical variations and arsenic mobilization in the shallow alluvial aquifers of the Chapai-Nawabganj District, northwestern Bangladesh: implication of siderite precipitation

Core sediments from three disturbed boreholes (JOR, GHAT, and RAJ) and two undisturbed boreholes (DW1 and DW2) were collected in the study area of the Chapai-Nawabganj district of northwestern Bangladesh for geochemical analyses. In the study area, groundwater samples from fourteen As-contained private wells and five nested piezometers at both the DW1 and DW2 boreholes were also collected and analyzed. The groundwater arsenic concentrations in the uppermost aquifer (10–40 m of depth) range from 3 to 315 μg/L (mean 47.73 ± 73.41 μg/L), while the arsenic content in sediments range from 2 to 14 mg/kg (mean 4.36 ± 3.34 mg/kg). An environmental scanning electron microscope (ESEM) with an energy dispersive X-ray spectrometer was used to investigate the presence of major and trace elements in the sediments. Groundwaters in the study area are generally the Ca–HCO₃ type with high concentrations of As, but low levels of Fe, Mn, NO₃ ^? and SO ₄ ^?2 . The concentrations of As, Fe, Mn decrease with depth in the groundwater, showing vertical geochemical variations in the study area. Statistical analysis clearly shows that As is closely associated with Fe and Mn in the sediments of the JOR core (r = 0.87, p < 0.05 for Fe and r = 0.78, p < 0.05 for Mn) and GHAT core (r = 0.95, p < 0.05 for Fe and r = 0.93, p < 0.05 for Mn), while As is not correlated with Fe and Mn in groundwater. The comparatively low Fe and Mn concentrations in some groundwater and the ESEM image revealed that siderite precipitated as a secondary mineral on the surface of the sediment particles. The correlations along with results of sequential extraction experiments indicated that reductive dissolution of FeOOH and MnOOH represents a mechanism for releasing arsenic into the groundwater.     

A GIS-based DRASTIC model for assessing groundwater vulnerability in the Ordos Plateau, China

Groundwater plays a key role in arid regions as the majority of water is supplied by it. Groundwater pollution is a major issue, because it is susceptible to contamination from land use and other anthropogenic impacts. A study was carried out to build a vulnerability map for the Ordos Plateau using the DRASTIC model in a GIS environment. The map was designed to show the areas of the highest potential for groundwater pollution based on hydrogeological conditions. Seven environmental parameters, such as depth to water table, net recharge, aquifer media, soil media, topography, impact of the vadose zone media, and hydraulic conductivity of the aquifer, were incorporated into the DRASTIC model and GIS was used to create a groundwater vulnerability map by overlaying the available data. The results of this study show that 24.8 % of the study area has high pollution potential, 24.2 % has moderate pollution potential, 19.7 % has low pollution potential, and the remaining 31.3 % of the area has no risk of groundwater pollution. The regional distribution of nitrate is well correlated with the DRASTIC vulnerability index. In contrast to this, although the DRASTIC model indicated that the western part had no risk, nitrate concentrations were higher in some of these areas. In particular, higher nitrate concentrations were recorded along river valleys and around lakes, such as the Mulin River valley. This is mainly caused by the intensive agricultural development and favorable conditions for recharge along river valleys.     

Evaluation of Combined Direct-Push Methods Used for Aquifer Model Generation

Most established methods to characterize aquifer structure and hydraulic conductivities of hydrostratigraphical units are not capable of delivering sufficient information in the spatial resolution that is desired for sophisticated numerical contaminant transport modeling and adapted remediation design. With hydraulic investigation methods based on the direct-push (DP) technology such as DP slug tests, DP injection logging, and the hydraulic profiling tool, it is possible to rapidly delineate hydrogeological structures and estimate their hydraulic conductivity in shallow unconsolidated aquifers without the need for wells. A combined application of these tools was used for the investigation of a contaminated German refinery site and for the setup of hydraulic aquifer models. The quality of DP investigation and the models was evaluated by comparisons of tracer transport simulations using these models and measured breakthroughs of two natural gradient tracer tests. Model scenarios considering the information of all tools together showed good reproduction of the measured breakthroughs, indicating the suitability of the approach and a minor impact of potential technical limitations. Using the DP slug tests alone yielded significantly higher deviations for the determined hydraulic conductivities compared to considering two or three of the tools. Realistic aquifer models developed on basis of such combined DP investigation approaches can help optimize remediation concepts or identify flow regimes for aquifers with a complex structure.     

Active Galactic Nuclei

F11 Jets, supernovae, gammabursts – more light for theory? F35 A Direct Comparison of the QSO Samples from VPMS and SDSS F36 Gravitational Microlensing Simulations and Ensemble Broad‐Band Variability of the QSOs from VPMS F42 Luminosity function of low redshift quasars F43 Star Formation around Active Galactic Nuclei – Results from near infrared observations F58 High‐Redshift Quasars as Probes of Early Star Formation F66 On the dust emission of Seyfert nuclei F72 Propagation of Very Light MHD Jets F78 Giant Outflows in MassiveHigh‐z Radio Galaxies: Direct Evidence for AGNFeedback in the Early Universe F89 Lowfrequency mapping of ‘normal’ FR II radio galaxies: Resolving the puzzle of X‐shaped radio sources F90 Nature of X‐shaped radio sources: A statistical approach F100 Cosmological growth of Supermassive Black Holes: constraints on kinetic and radiative energy feedback F107 Molecular Tori in AGN F136 Electron‐Ion Recombination Rate Coefficients of Iron M‐Shell Ions for X‐Ray Astronomy F139 Hydrodynamic models of obscuring tori F145 The unique BL Lac Object S5 0716+714 F158 On the Cluster Environment of the BL Lac Object OJ 287 F179 The circumnuclear dust in nearby AGN resolved by mid‐infrared interferometry F184 NIR‐imaging of SDSS BL Lac objects F190 Blazar Observations in the TeV energy range with the MAGIC Telescope F198 Gas Inflow Rates in Nearby AGN Galaxies F202 Two zone SSC model for blazar jets F215 Long‐termVHE γ ‐ray monitoring of bright blazars with a dedicated telescope F218 Long termmonitoring of bright TeV Blazars with the MAGIC telescope F220 Fifteen Blazars in Very‐High Energy Gamma Rays: A Comparative Study F229 Numerical calculation of blazar spectra. Application to 1 ES 1218+30.4 F230 Blazar spectral energy distributions corrected for gamma ray attenuation F240 Observation of PG 1553+113 with the MAGIC Telescope F243 VHE Gamma‐Ray Flare of PKS2155‐304 detected by the MAGIC telescope F245 Observations of 3C279 with the MAGIC Telescope F258 Diffraction limited near infrared imaging spectroscopy of the NLR of NGC4151     

Magnetostratigraphic results from the eastern Arctic Ocean: AMS 14C ages and relative palaeointensity data of the Mono Lake and Laschamp geomagnetic reversal excursions

A new high-resolution magnetostratigraphic record from the eastern Arctic Ocean has yielded further evidence for the existence of the Laschamp excursion (37–35  ka), the Mono Lake excursion (27–25.5  ka) and possibly another very short excursion (22  ka) inferred from steep negative inclinations. Ages are based on nine AMS (accelerator mass spectrometry) ¹⁴C dates, oxygen isotope stratigraphy and correlation with ODP site 983. Estimates of relative palaeointensity variations for the time interval from 80 to 10  ka have revealed that the documented geomagnetic excursions are linked to large fluctuations of the relative palaeointensity. The lowest values were obtained for the two excursions and the normal–reversed (N–R) and reversed–normal (R–N) transitions of the Laschamp polarity excursion, which itself is characterized by a slight increase of relative palaeointensity during its reversed state. The results are in general agreement with palaeointensity studies from other regions, indicating that these fluctuations could be global phenomena and that the geomagnetic field of the Brunhes Chron was very variable in amplitude as well as in geometry. The new result is one of the rare records comprising large directional as well as large relative palaeointensity variations.