On the accuracy of atmospheric forcing for extra-tropical storm surge prediction

The ability of the SMARA storm surge numerical prediction system to reproduce local effects in estuarine and coastal winds was recently improved by considering one-way coupling of the air–sea momentum exchange through the wave stress, and best forecasting practices for downscaling. The inclusion of long period atmospheric pressure forcing in tide and tide/surge calculations corrected a systematic error in the surge, produced by the South Atlantic Ocean quasi-stationary pressure patterns. The maximum forecast range for the storm surge at Buenos Aires provided by the real-time use of water level observations is approximately 12 h. The best available water level prediction is the 6-h forecast (nowcast) based on the closest water level observations. The 24-h forecast from the numerical models slightly improves this nowcast. Although the numerical forecast accuracy degrades after the first 48 h, the improvement to the full range observation-based prediction is maintained at the inner Río de la Plata area and extends to the first 3 days at the intermediate navigation channels.     

Investigating the molecular systematic relationships amongst selected Plesionika (Decapoda: Pandalidae) from the Northeast Atlantic and Mediterranean Sea

Despite the high number of species and ecological diversity of pandalid shrimps, there has been no previous attempt to resolve evolutionary relationships of several genera using molecular tools. Although mitochondrial DNA cytochrome oxidase I (COI) is widely used in barcoding studies to delimit species boundaries, additional insights into phylogenetic affinities can be obtained, especially when used in combination with data from additional genes. The knowledge of molecular diversity is essential to understand phylogenetic relationships and will help systematic clarifications. Based on partial fragments of the 16S and COI genes, we have focused specifically on addressing the systematic relationships of the economically and ecologically important shrimp genus Plesionika within a framework of five genera from within the Pandalidae. Our results showed that species within Plesionika are substantially divergent when compared with other genera, exhibiting the highest average nucleotide divergence, with 0.1123 and 0.0846 in COI and 16S genes, respectively. In addition, sequence divergence was found to vary greatly within the genus Plesionika (COI/16S): 0.0247/0.0016 between Plesionika antigai and Plesionika heterocarpus and 0.1616/0.098 between Plesionika heterocarpus and Plesionika edwardsii. We did not find amino acid sequence divergence between P. heterocarpus and P. antigai compared with P. heterocarpus and P. edwardsii (8.10%, K2P distance). Three species of Plesionika (P. antigai, P. heterocarpus and Plesionika scopifera) appear well separated from other Plesionika species in both maximum likelihood and Bayesian analyses. The present study confirms the utility of COI over 16S as a genetic marker to resolve relationships between different species of Plesionika from the Northeast Atlantic and Mediterranean Sea, in addition to species delimitation. The findings highlight the need to further review paraphyly within Plesionika in an attempt to recognize a concordance in the evolutionary history of Plesionika with major ecological and geological events.     

Macrobenthic community for assessment of estuarine health in tropical areas (Northeast, Brazil): Review of macrofauna classification in ecological groups and application of AZTI Marine Biotic Index

The aim of the present study was to investigate the ecological quality of tropical estuaries on the northeastern coast of Brazil using the AMBI. Macrofauna classification based on ecological groups was reviewed using the Indicator Value (IndVal) coefficient. The results indicate that the ecosystems exhibit some level of disturbance. Most sites are situated between slightly-moderately disturbed boundaries due to the higher proportion of Nematoda (assigned here as Ecological Group I) and of Oligochaeta and Tubificidae (both classified as Ecological Group V). The AMBI proved efficient in evaluating environmental status, although the applicability of this index requires adjustments regarding some species in ecological groups. The present study also highlights the merits of the IndVal method for examining the assignments of species/taxa to an ecological group and demonstrates the validity of this coefficient is an assessment tool. Moreover, the complementary use of different methods is recommended for the assessment of ecosystem quality.     

Analysis of the Characteristics of Low-Latitude GPS Amplitude Scintillation Measured During Solar Maximum Conditions and Implications for Receiver Performance

Ionospheric scintillations are fluctuations in the phase and/or amplitude of trans-ionospheric radio signals caused by electron density irregularities in the ionosphere. A better understanding of the scintillation pattern is important to make a better assessment of GPS receiver performance, for instance. Additionally, scintillation can be used as a tool for remote sensing of ionospheric irregularities. Therefore, the study of ionospheric scintillation has both scientific as well as technological implications. In the past few years, there has been a significant advance in the methods for analysis of scintillation and in our understanding of the impact of scintillation on GPS receiver performance. In this work, we revisit some of the existing methods of analysis of scintillation, propose an alternative approach, and apply these techniques in a comprehensive study of the characteristics of amplitude scintillation. This comprehensive study made use of 32?days of high-rate (50?Hz) measurements made by a GPS-based scintillation monitor located in S?o José dos Campos, Brazil (23.2°S, 45.9°W, ?17.5° dip latitude) near the Equatorial Anomaly during high solar flux conditions. The variability of the decorrelation time (τ₀) of scintillation patterns is presented as a function of scintillation severity index (S ₄). We found that the values of τ₀ tend to decrease with the increase of S ₄, confirming the results of previous studies. In addition, we found that, at least for the measurements made during this campaign, averaged values of τ₀ (for fixed S ₄ index values) did not vary much as a function of local time. Our results also indicate a significant impact of τ₀ in the GPS carrier loop performance for S ₄?≥?0.7. An alternative way to compute the probability of cycle slip that takes into account the fading duration time is also presented. The results of this approach show a 38% probability of cycle slips during strong scintillation scenarios (S ₄ close to 1 and τ₀ near 0.2?s). Finally, we present results of an analysis of the individual amplitude fades observed in our set of measurements. This analysis suggests that users operating GPS receivers with C/N ₀ thresholds around 30?dB-Hz and above can be affected significantly by low-latitude scintillation.     

Study of the Interaction Mechanism in the Biosorption of Copper(II) Ions onto Posidonia oceanica and Peat

A systematic approach was used to characterize the biosorption of copper(II) onto two biosorbents, Posidonia oceanica and peat, focusing on the interaction mechanisms, the copper(II) sorption–desorption process and the thermal behavior of the biosorbents. Sorption isotherms at pH 4–6 were obtained and the experimental data were fitted to the Langmuir model with a maximum uptake (q_max) at pH 6 of 85.78 and 49.69 mg g^?1, for P. oceanica and peat, respectively. A sequential desorption (SD) with water, Ca(NO₃)₂, and EDTA was applied to copper‐saturated biosorbents. Around 65–70% copper(II) were desorbed with EDTA, indicating that this heavy metal was strongly bound. The reversibility of copper(II) sorption was obtained by desorption with HCl and SD. Fourier transform IR spectroscopy (FTIR) analysis detected the presence of peaks associated with OH groups in aromatic and aliphatic structures, CH, CH₂, and CH₃ in aliphatic structures, COO^? and COOH groups and unsaturated aromatic structures on the surface of both biosorbents, as well as peaks corresponding to Si? O groups on the surface of peat. The results of SEM‐EDX and FTIR analysis of copper‐saturated samples demonstrated that ion exchange was one of the mechanisms involved in copper(II) retention. Thermal analysis of biosorbent samples showed that copper(II) sorption–desorption processes affected the thermal stability of the biosorbents.     

Sediments Quality Assessment of Jacarepaguá Lagoon: The Venue of the 2011 Rock in Rio

In order to aid in the efforts of the 2016 Olympic Games, the organizers of 2011 Rock in Rio decided to build a permanent venue next to the Olympic Park. The area is problematic from the geotechnical point of view since it presents soils with low shear strength, low permeability, and high plasticity, so major soil improvement works were carried out. Bored soil–cement columns were placed to increase soil shear strength and reduce compressibility. A meter thick fill composed of gneiss residual soil was placed and trenches were digged to drain rainwater. However, earlier studies conducted on Jacarepaguá Lagoon have detected the presence of heavy metals in these sediments. In this study, an environmental survey on the Jacarepaguá Lagoon sediments took place in order to choose a place where its sediments could be dredged to be later used in the drainage facilities. The results indicated areas where the threshold level 1 (low probability of adverse effects) issued by the general procedures for sediments quality assessments for dredging purposes, Resolution no 344 of the Brazilian Federal Government, was surpassed. Levels above the limits established for cadmium (Cd), lead (Pb), copper (Cu), nickel (Ni), and zinc (Zn) were detected. Based on this consideration the State Environmental Agency issued a permit allowing the organizers of 2011 Rock in Rio to dredge an area close to City of Rock in order to obtain coarse sediments for the drainage facilities. In addition, it was found that those sediments were ideal for this application since their hydraulic conductivity is on the order of 10^?2 cm/s.     

Tracing seafloor methane emissions with benthic foraminifera: Results from the Ana submarine landslide (Eivissa Channel,Western Mediterranean Sea)

The hypothesis that benthic foraminifera are useful proxies of local methane emissions from the seafloor has been verified on sediment core KS16 from the headwall of the Ana submarine landslide in the Eivissa Channel, Western Mediterranean Sea. The core MS312 from a nearby location with no known methane emissions is utilised as control. The core was analysed for biostratigraphy, benthic foraminiferal assemblages, Hyalinea balthica and Uvigerina peregrina carbon and oxygen stable isotope composition, and sedimentary structures. The upper part of the core records post-landslide deglacial and Holocene normal marine hemipelagic sediments with highly abundant benthic foraminifera species that are typical of outer neritic to upper bathyal environment. In this interval, the δ¹³C composition of benthic foraminifera indicates normal marine environment analogous to those found in the control core. Below the sedimentary hiatus caused by the emplacement of the slide, the foraminiferal assemblages are characterised by lower density and higher Shannon Index. Markedly negative δ¹³C shifts in benthic foraminifera are attributed to the release of methane through the seabed. The mean values of the ¹³C anomaly in U. peregrina are ? 0.951 ± 0.208 in the pre-landslide sediments, and ? 0.269 ± 0.152 in post-slide reworked sediments deposited immediately above the hiatus. The δ¹³C anomaly in Hyalinea balthica is ? 2.497 ± 0.080 and ? 2.153 ± 0.087, respectively. To discard the diagenetic effects on the δ¹³C anomaly, which could have been induced by Ca–Mg replacement and authigenic carbonate overgrowth on foraminifera tests, a benthic foraminifera subsample has been treated following an oxidative and reductive cleaning protocol. The cleaning has resulted, only in some cases, in a slight reduction of the anomaly by 0.95% for δ¹³C and < 0.80% for δ¹⁸O. Therefore, the first conclusion is that the diagenetic alteration is minor and it does not alter significantly the overall carbon isotopic anomaly in the core. Consequently, the pre-landslide sediments have been subject to pervasive methane emissions during a time interval of several thousand years. Methane emissions continued during and immediately after the occurrence of Ana Slide at about 61.5 ka. Subsequently, methane emissions decreased and definitely ceased during the last deglaciation and the Holocene.     

An investigation of ensemble-based assimilation of satellite altimetry and tide gauge data in storm surge prediction

Cyclogenesis and long-fetched winds along the southeastern coast of South America may lead to floods in populated areas, as the Buenos Aires Province, with important economic and social impacts. A numerical model (SMARA) has already been implemented in the region to forecast storm surges. The propagation time of the surge in such extensive and shallow area allows the detection of anomalies based on observations from several hours up to the order of a day prior to the event. Here, we investigate the impact and potential benefit of storm surge level data assimilation into the SMARA model, with the objective of improving the forecast. In the experiments, the surface wind stress from an ensemble prediction system drives a storm surge model ensemble, based on the operational 2-D depth-averaged SMARA model. A 4-D Local Ensemble Transform Kalman Filter (4D-LETKF) initializes the ensemble in a 6-h cycle, assimilating the very few tide gauge observations available along the northern coast and satellite altimeter data. The sparse coverage of the altimeters is a challenge to data assimilation; however, the 4D-LETKF evolving covariance of the ensemble perturbations provides realistic cross-track analysis increments. Improvements on the forecast ensemble mean show the potential of an effective use of the sparse satellite altimeter and tidal gauges observations in the data assimilation prototype. Furthermore, the effects of the localization scale and of the observational errors of coastal altimetry and tidal gauges in the data assimilation approach are assessed.     

Deposition and tectonic setting of the Palaeoproterozoic Castelo dos Sonhos metasedimentary formation,Tapajós Gold Province,Amazonian Craton,Brazil: age and isotopic constraints

The Castelo dos Sonhos Formation (CSF) represents a relic of a sedimentary basin located in the southeastern Tapajós Gold Province (TGP), at its boundary with the Iriri–Xingu Domain (IX), south of the Amazonian Craton. The formation comprises mature, coarse-grained metasandstones (quartz-arenites) intercalated with auriferous metaconglomerates with clasts of quartz and subordinately of banded iron formation, quartzite, schist, and felsic metavolcanic rocks. Lithology, planar, channelled, and large-scale cross-bedding suggest deposition in continental setting by the braided fluvial system associated with alluvial fans and subordinate aeolian dunes. The rocks underwent very low metamorphism and gently synformal folding, and were intruded by andesites and granitoids (2011–1918 Ma). U–Pb LA-ICP-MS zircon data indicate maximum depositional ages of 2050 Ma (metaconglomerate) and 2074, 2088, and 2104 Ma (metasandstones). Hence, deposition occurred at 2050–2011 Ma, slightly preceding or being coeval with the onset of the orogenic phase in TGP (2030–1956 Ma). The quartz-arenite composition, zircon U–Pb data, and negative εHf (?1.3 to ?13.0) and εNd (?2.9 to ?5.3) values indicate: (1) quartzose provenance, (2) prolonged transport and recycling of sedimentary sources, (3) multiple age peaks (2050–3700 Ma), with predominant sources of 2100 and 2750 Ma, and (4) long crustal residence time for the source rocks. Source areas were Rhyacian–Siderian orogenic belts to Mesoarchaean terranes of the Amazonian Craton located to the east, southeast, and northeast of TGP, along with Palaeoarchaean and Eoarchaean detrital zircons recycled from older sedimentary rocks. We interpret CSF as part of a larger foreland system related to the evolution of Rhyacian orogens, currently represented by the Bacajá and Santana do Araguaia domains. The present location of CSF in the easternmost TGP, close to its boundary with IX, is due to rifting (1.89–1.80 Ga) that produced the Uatumã Silicic Large Igneous Province (Uatumã SLIP), and the juxtaposition of the crustal domains is supported by gravity data.