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31.
32.
Rate constants for the reaction of OH radicals with some branched alkyl nitrates have been measured applying a competitive technique. Methyl nitrite photolysis in synthetic air was used as OH radical source at 295±2 K and 1000 mbar total pressure. Using a rate constant of 2.53×10-12 cm3 s-1 for the reaction of OH radicals with n-butane as reference, the following rate constants were obtained (units: 10-12 cm3 s-1): isopropyl nitrate, 0.59±0.22; isobutyl nitrate, 1.63±0.20; 3-methyl-2-butyl nitrate, 1.95±0.15; 2-methyl-1-butyl nitrate, 2.50±0.15; 3-methyl-1-butyl nitrate, 2.55±0.35. These values have been combined with the literature data to recalculate the substituent factors F(X) for the different nitrate groups which can be used to predict OH rate constants for organic nitrates for which experimental data are not available.Preliminary measurements of the photolysis frequency of isopropyl nitrate have shown that for this nitrate as a model substance, OH reactions and direct photolysis are of equal importance under tropospheric conditions. 相似文献
33.
Significance of the remotely sensed thermal infrared measurements obtained over a citrus orchard 总被引:1,自引:0,他引:1
In this work we have developed a theoretical model that helps the interpretation of the remotely sensed thermal infrared measurements carried out over citrus orchards. A detailed analysis of the different factors which take part in the definition of the effective emissivity and temperature (observation height, viewing angle, type of soil, dimensions and separation between orange trees) is made. The model was validated under vertical observation in a citrus orchard during seven nights. In this situation we have determined that the model performs to an accuracy of about 1%. 相似文献
34.
Results from a new model of river basin evolution 总被引:1,自引:0,他引:1
This paper briefly describes a model of the erosional development of catchments and their channel networks. The model differentiates between the dominant transport processes in hillslope and channels. The development of channels and hillslopes occurs in an integrated manner as a function of physically observable mechanisms. The growth of a river basin is qualitatively described. The model concepts are used to study the basin during periods of growth (transient periods), as well as during dynamic equilibrium. This leads to hypotheses about the relationship between slopes, relief, tectonic uplift, erodability, runoff, and catchment area. It is shown that the model leads to very reasonable and desirable behaviour of hillslopes during retreat and degradation. 相似文献
35.
Geochemical Indicators of Intrinsic Bioremediation 总被引:19,自引:0,他引:19
A detailed field investigation has been completed at a gasoline-contaminated aquifer near Rocky Point, NC, to examine possible indicators of intrinsic bioremediation and identify factors that may significantly influence the rate and extent of bioremediation. The dissolved plume of benzene, toluene, ethylbenzene, and xylene (BTEX) in ground water is naturally degrading. Toluene and o-xylene are most rapidly degraded followed by m-, p-xylene, and benzene. Ethylbenzene appears to degrade very slowly under anaerobic conditions present in the center of the plume. The rate and extent of biodegradation appears to be strongly influenced by the type and quantity of electron acceptors present in the aquifer. At the upgradient edge of the plume, nitrate, ferric iron, and oxygen are used as terminal electron acceptors during hydrocarbon biodegradation. The equivalent of 40 to 50 mg/I of hydrocarbon is degraded based on the increase in dissolved CO2 relative to background ground water. Immediately downgradient of the source area, sulfate and iron are the dominant electron acceptors. Toluene and o-xylene are rapidly removed in this region. Once the available oxygen, nitrate, and sulfate are consumed, biodegradation is limited and appears to be controlled by mixing and aerobic biodegradation at the plume fringes. 相似文献
36.
Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl4 and CH3OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH3OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH3OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH3OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ13C values of about +5 to + 10%. and δ15N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH3OH-extract also has a δ15N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH3OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH3OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl4 has essentially no nitrogen, and δ3C and δD values are lower than for CH3OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin. 相似文献
37.
Conservative tracers are necessary to obtain groundwater transport velocities at the field scale. Deuterated water is an
effective tracer for this purpose due to its similarity to water, chemical stability, non-reactivity, ease of handling and
sampling, relatively neutral buoyancy, and reasonable price. Reliable detection limits of 0.1 mg deuterium/L may be obtained
in field tests. A field example is presented in which deuterated water, bromide, and pentafluorobenzoic acid are used as groundwater
tracers. Deuterated water appeared to be transported conservatively, producing almost identical breakthrough curves as that
of other soluble tracers.
Electronic Publication 相似文献
38.
39.
The search for exoelectron emission from Apollo 12 materials usually produced negative results, suggesting that the concentration of naturally occurring traps is very low. Weak exoelectron activity was found scattered inhomogeneously within a pigeonite basalt rock and in a deep core tube sample. Its erratic appearance and intensity makes any interpretation of radiation history most difficult and is attributed to the activity being carried by only a few scattered crystals. The thermally stimulated emission of exoelectrons is judged an unsuitable technique for tracing the radiation histories of these samples. 相似文献
40.
Davis JA May MD Greenfield BK Fairey R Roberts C Ichikawa G Stoelting MS Becker JS Tjeerdema RS 《Marine pollution bulletin》2002,44(10):1117-1129
In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%. 相似文献