Uraninite recrystallization and Pb loss in the Oklo and Bangombé natural fission reactors, Gabon

The Oklo and Bangombé natural fossil fission reactors formed ca. 2 Ga ago in the Franceville basin, Gabon. The response of uraninite in the natural reactors to different geological conditions has implications for the disposal of the UO₂ in spent nuclear fuel. Uraninite and galena from two reactor zones, RZ16 at Oklo and RZB at Bangombé, were studied to clarify the chronology and effect of alteration events on the reactor zones. In addition, ion microprobe U-Pb analysis of zircons from a dolerite dyke in the Oklo deposit were completed to better constrain the age of the dyke, and thereby testing the link between the dyke and an important alteration event in the reactor zones.The analyzed uraninite from RZ16 and RZB contains ca. 6 wt% PbO, indicating a substantial loss of radiogenic Pb. Transmission electron microscopy showed that microscopic uraninite grains in the reactor zones consist of mainly defect-free nanocrystalline to microcrystalline aggregates. However, the nanocrystalline regions have elevated Si contents and lower Pb contents than coarser uraninite crystallites. Single stage model ages of large, millimeter-sized galena grains at both RZ16 and RZB correlate well with the age of the Oklo dolerite dyke, 860 ± 39 Ma (2σ). Thus, the first major Pb loss from uraninite occurred at both Oklo and Bangombé during regional extension and the intrusion of a dyke swarm in the Franceville basin, ∼860-890 Ma ago. Uraninite Pb isotopes from RZ16 and RZB give lower ages of ca. 500 Ma. These ages agree with the “chemical” ages of the uraninite, and show that an ancient Pb loss occurred after the intrusion of the dolerite dykes. The presence of nanocrystallites in the reactor uraninite indicates internal recrystallization, which may have occurred around 500 Ma, resulting in the 6wt% PbO uraninite. It is suggested that leaching by fluid interaction triggered by the Pan-African orogeny was important during this second Pb-loss event. Thus, there are indications that uraninite at both the Oklo and Bangombé natural reactors has experienced at least two ancient episodes of Pb loss associated with internal recrystallization. These recrystallization events have occurred without significantly depleting the 2 Ga fission products compatible with the uraninite structure.     

Response variability in structural dynamics

This paper presents a technique for treating uncertainties in the dynamic models of a structural system. The formulation of the method is presented for a simple case of a single-degree-of-freedom linear oscillator. The uncertainties are modelled as random variables and are assumed to be time-independent. The solution is expanded as a series involving the random terms, and a system of linear ordinary differential equations for the unknowns of the problem is derived using the weighted residual method. The system of equations is then integrated in time and the response variability is computed. Validation calculations show that the results from the method agree well with those obtained by other solution techniques. Finally, some possible applications and extensions of the present work are discussed.     

Zum Abbau von Formaldehyd durch adaptierte Bakterien

Municipal activated sludge was cultivated in a medium composed of formaldehyde, glucose and mineral salt. By passages with increasing formaldehyde content a bacterial culture was selected which remained active also at initial concentrations of 1 g/1 formaldehyde. With this culture, formaldehyde and glucose were oxidized simultaneously to formate and gluconate, which subsequently served simultaneously as substrate for the growth of bacteria. Glucose alone was also oxidized to gluconate, which then was used as substrate for growth. Formaldehyde alone was only oxidized. If the actual formaldehyde concentration was kept low, however, by fed-batch cultivation, it was assimilated also through formate formation. The biochemical background and the importance of the findings for the purification of formaldehyde-containing wastewaters are discussed.     

Effective barometric admittance and gravity residuals

In the analysis of surface gravity signals that may originate from the Earth's core, the step of correcting for the atmospheric pressure fluctuations is one that must be done carefully. We apply two techniques for determining the local, or effective, barometric admittance function between simultaneous observations of surface gravity and pressure. The first is a frequency domain fit that computes the admittance on a band-by-band basis. Using data from both the Canadian and French superconducting gravimeters we determined that the magnitude of the local, or background, admittance increases smoothly and monotonically from about 0.2 μgal mbar⁻¹ at long periods (> 10 days) to about 0.35 μgal mbar⁻¹ at frequencies greater than 3 cycles per day (c.p.d.); the phase lag is within a few degrees of 180°. By comparison, the effective admittances of the large-scale harmonics of the solar heating tide (S₁---S₇) are much smaller, between 0.1 and 0.3 μgal mbar⁻¹, for most of the harmonics of a day. In the second approach we fit a symmetrical time domain admittance function having lengths between 1 and 19 h using both a standard least-squares fit to a white noise residual and a new, and clearly superior, fit assuming a brown noise residual. Both time and frequency domain approaches give comparable results and contribute to a significant lowering of the residual level in non-tidal bands.     

Climatic change and design criteria in water resources management a regional case study

As a result of the anthropogenic greenhouse effect there is fear of alterations of the world climate, which also may result in hydrological changes and consequently in water resources management. In a case study it was investigated if such changes could be identified for a regional catchment area. Summarized it may be said that the regional analysis of hydro-meteorological data in the catchment area of the Sieg showed the expected effects of the anthropogenic climate change on the regional water cycle. Rises in annual mean temperature and precipitation could be observed over a period from 1892 until 1993. However, a significant relation between evident changes and greenhouse effect could not be stated. Changes in discharge do not show consistent behavior. Especially apparent contradictions show that additional examinations are necessary in order to make the complex natural inter-relationships between climate and regional water cycle with the impacts of existing anthropogenetic interferences visible and applicable for practical engineering tasks.     

Fracture induced emission of alkali atoms from feldspar

Emission of neutral atoms (K and Na) and molecules (H₂O and KOH) observed during fracture of K-feldspar have been accounted for by two independent mechanisms. H₂O and KOH emissions are attributed to the venting of fluid-filled inclusions, while emission of atomic K is due to surface effects accompanying cleavage of crystalline feldspar. The intensity of emitted potassium, at least 6 × 10¹⁴ atoms/cm² of surface area, is sufficient to affect K activities in solution during microbrecciation in the presence of rock-dominated fluids.     

Sulfur isotopes of the Nairne Pyrite deposit,South Australia

The Nairne Pyrite deposit occurs in at least five horizons in a succession of graywackes, quartzites, and siltstones of Cambrian age. Pyrite and pyrrhotite have been traced along bedding planes for almost 100 km suggesting, of course, a syngenetic origin for the sulfides. Sulfur isotopic analyses of samples from the Nairne Pyrite open-cut project provide S³⁴ values ranging from –12.8 to –20.6 permil. Such enrichment in S³², even though the spread in S³⁴ values is comparatively narrow, is suggestive of bacteriogenic sulfur which corroborates the geological evidence that the deposit is bacteriogenic — syngenetic in origin.

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Zusammenfassung Die Pyrit-Lagerstätte Nairne umfaßt wenigstens fünf Horizonte cambrischer Grauwacken, Quartzite und feine Sand- bis Tonsteine. Pyrit und Magnetkies sind über eine Distanz von fast 100 km schichtgetreu, was auf einen syngenetischen Ursprung der Sulfide hinweist. Schwefelisotop-Analysen von Pyrit aus dem Tagebau-Projekt erstrecken sich über einen S³⁴-Bereich von –12,8 bis –20,6 Promille. Diese Anreicherung weist auf einen bakteriellen Ursprung des Schwefels hin, obgleich die Spannweite der Resultate sehr eng ist. Somit ist die Feldvermutung einer syngenetisch-bakteriellen Entstehung bekräftigt.

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The isotopic analyses included in this paper were supported through the U. S. Atomic Energy Commission Contract AT (11-1) 1553, for which we are most grateful.