Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

Wind erosion from military training lands in the Mojave Desert, California, U.S.A.

Military training activities reduce vegetation cover, disturb crusts, and degrade soil aggregates, making the land more vulnerable to wind erosion. The objective of this study was to quantify wind erosion rates for typical conditions at the Marine Corps Air Ground Combat Center, Twentynine Palms, CA, U.S.A. Five Big Spring Number Eight (BSNE) sampler stations were installed at each of five sites. Each BSNE station consisted of five BSNE samplers with the lowest sampler at 0·05 m and the highest sampler at 1·0 m above the soil surface. Once a month, sediment was collected from the samplers for analysis. Occurrence of saltating soil aggregates was recorded every hour using Sensits, one at each site. The site with the most erosion had a sediment discharge of 311 kg m⁻¹ over a period of 17 months. Other sites eroded much less because of significant rock cover or the presence of a crust. Hourly sediment discharge was estimated combining hourly Sensit count and monthly sediment discharge measured using BSNE samplers. More simultaneously measured data are needed to better characterize the relationship between these two and reconstruct a detailed time-series of wind erosion. This measured time-series can then be used for comparison with simulation results from process-based wind erosion models such as the Wind Erosion Prediction System (WEPS), once it has been adapted to the unique aspects of military lands.     

Asymmetric one‐storey elastic systems with non‐linear viscous and viscoelastic dampers: Simplified analysis and supplemental damping system design

Investigated is the accuracy in estimating the response of asymmetric one‐storey systems with non‐linear viscoelastic (VE) dampers by analysing the corresponding linear viscous system wherein all non‐linear VE dampers are replaced by their energy‐equivalent linear viscous dampers. The response of the corresponding linear viscous system is determined by response history analysis (RHA) and by response spectrum analysis (RSA) extended for non‐classically damped systems. The flexible and stiff edge deformations and plan rotation of the corresponding linear viscous system determined by the extended RSA procedure is shown to be sufficiently accurate for design applications with errors generally between 10 and 20%. Although similar accuracy is also shown for the ‘pseudo‐velocity’ of non‐linear VE dampers, the peak force of the non‐linear VE damper cannot be estimated directly from the peak damper force of the corresponding linear viscous system. A simple correction for damper force is proposed and shown to be accurate (with errors not exceeding 15%). For practical applications, an iterative linear analysis procedure is developed for determining the amplitude‐ and frequency‐dependent supplemental damping properties of the corresponding linear viscous system and for estimating the response of asymmetric one‐storey systems with non‐linear VE dampers from the earthquake design (or response) spectrum. Finally, a procedure is developed for designing non‐linear supplemental damping systems that satisfy given design criteria for a given design spectrum. Copyright © 2003 John Wiley & Sons, Ltd.     

Inelastic displacement ratios for evaluation of existing structures

Results of a detailed statistical study of constant relative strength inelastic displacement ratios to estimate maximum lateral inelastic displacement demands on existing structures from maximum lateral elastic displacement demands are presented. These ratios were computed for single‐degree‐of‐freedom systems with different levels of lateral strength normalized to the strength required to remain elastic when subjected to a relatively large ensemble of recorded earthquake ground motions. Three groups of soil conditions with shear wave velocities higher than 180m/s are considered. The influence of period of vibration, level of lateral yielding strength, site conditions, earthquake magnitude, distance to the source, and strain‐hardening ratio are evaluated and discussed. Mean inelastic displacement ratios and those associated with various percentiles are presented. A special emphasis is given to the dispersion of these ratios. It is concluded that distance to the source has a negligible influence on constant relative strength inelastic displacement ratios. However, for periods smaller than 1s earthquake magnitude and soil conditions have a moderate influence on these ratios. Strain hardening decreases maximum inelastic displacement at a fairly constant rate depending on the level of relative strength for periods of vibration longer than about 1.0s while it decreases maximum inelastic displacement non‐linearly as the period of vibration shortens and as the relative‐strength ratio increases for periods of vibration shorter than 1.0s. Finally, results from non‐linear regression analyses are presented that provide a simplified expression to be used to approximate mean inelastic displacement ratios during the evaluation of existing structures built on firm sites. Copyright © 2003 John Wiley & Sons, Ltd.     

Landslide susceptibility analysis using GIS and artificial neural network

The purpose of this study is to develop landslide susceptibility analysis techniques using an arti?cial neural network and to apply the newly developed techniques to the study area of Yongin in Korea. Landslide locations were identi?ed in the study area from interpretation of aerial photographs, ?eld survey data, and a spatial database of the topography, soil type and timber cover. The landslide‐related factors (slope, curvature, soil texture, soil drainage, soil effective thickness, timber age, and timber diameter) were extracted from the spatial database. Using those factors, landslide susceptibility was analysed by arti?cial neural network methods. The landslide susceptibility index was calculated by the back‐propagation method, which is a type of arti?cial neural network method, and the susceptibility map was made with a geographic information system (GIS) program. The results of the landslide susceptibility analysis were veri?ed using landslide location data. The validation results showed satisfactory agreement between the susceptibility map and the existing data on landslide location. A GIS was used to ef?ciently analyse the vast amount of data, and an arti?cial neural network to be an effective tool to maintain precision and accuracy. The results can be used to reduce hazards associated with landslides and to plan land use and construction. Copyright © 2003 John Wiley & Sons, Ltd.     

A procedure for evaluating seismic energy demand of framed structures

Energy serves as an alternative index to response quantities like force or displacement to include the duration‐related seismic damage effect. A procedure to evaluate the absorbed energy in a multistorey frame from energy spectra was developed. For low‐ to medium‐rise frames, it required a static pushover analysis of the structure to determine the modal yield force and ductility factor of an equivalent single‐degree‐of‐freedom system for the first two modes. The energy spectra were then used to determine the energy contribution of each mode. A procedure was also developed to distribute the energy along the frame height based on energy shapes. This study showed that the second‐mode response in some cases needs to be considered to reflect the energy (or damage) concentration in the upper floors. Copyright © 2002 John Wiley & Sons, Ltd.     

System identification of the Vincent Thomas suspension bridge using earthquake records

The Vincent Thomas Bridge in the Los Angeles metropolitan area, is a critical artery for commercial traffic flow in and out of the Los Angeles Harbor, and is at risk in the seismically active Southern California region, particularly because it straddles the Palos Verdes fault zone. A combination of linear and non‐linear system identification techniques is employed to obtain a complete reduced‐order, multi‐input–multi‐output (MIMO) dynamic model of the Vincent Thomas Bridge based on the dynamic response of the structure to the 1987 Whittier and 1994 Northridge earthquakes. Starting with the available acceleration measurements (which consists of 15 accelerometers on the bridge structure and 10 accelerometers at various locations on its base), an efficient least‐squares‐based time‐domain identification procedure is applied to the data set to develop a reduced‐order, equivalent linear, multi‐degree‐of‐freedom model. Although not the main focus of this study, the linear system identification method is also combined with a non‐parametric identification technique, to generate a reduced‐order non‐linear mathematical model suitable for use in subsequent studies to predict, with good fidelity, the total response of the bridge under arbitrary dynamic environments. Results of this study yield measurements of the equivalent linear modal properties (frequencies, mode shapes and non‐proportional damping) as well as quantitative measures of the extent and nature of non‐linear interaction forces arising from strong ground shaking. It is shown that, for the particular subset of observations used in the identification procedure, the apparent non‐linearities in the system restoring forces are quite significant, and they contribute substantially to the improved fidelity of the model. Also shown is the potential of the identification technique under discussion to detect slight changes in the structure's influence coefficients, which may be indicators of damage and degradation in the structure being monitored. Difficulties associated with accurately estimating damping for lightly damped long‐span structures from their earthquake response are discussed. The technical issues raised in this paper indicate the need for added spatial resolution in sensor instrumentation to obtain identified mathematical models of structural systems with the broadest range of validity. Copyright © 2003 John Wiley & Sons, Ltd.     

Sources and distribution of terrigenous organic matter delivered by the Atchafalaya River to sediments in the northern Gulf of Mexico

Suspended sediments (SS) from the Atchafalaya River (AR) and the Mississippi River and surficial sediment samples from seven shallow cross-shelf transects west of the AR in the northern Gulf of Mexico were examined using elemental (%OC, C/N), isotopic (δ¹³C, Δ¹⁴C), and terrigenous biomarker analyses. The organic matter (OM) delivered by the AR is isotopically enriched (∼−24.5‰) and relatively degraded, suggesting that soil-derived OM with a C4 signature is the predominant OM source for these SS. The shelf sediments display OC values that generally decrease seaward within each transect and westward, parallel to the coastline. A strong terrigenous C/N (29) signal is observed in sediments deposited close to the mouth of the river, but values along the remainder of the shelf fall within a narrow range (8-13), with no apparent offshore trends. Depleted stable carbon isotope (δ¹³C) values typical of C3 plant debris (−27‰) are found near the river mouth and become more enriched (−22 to −21‰) offshore. The spatial distribution of lignin in shelf sediments mirrors that of OC, with high lignin yields found inshore relative to that found offshore (water depth > 10 m).The isotopic and biomarker data indicate that at least two types of terrigenous OM are deposited within the study area. Relatively undegraded, C3 plant debris is deposited close to the mouth of the AR, whereas more degraded, isotopically enriched, soil-derived OM appears to be deposited along the remainder of the shelf. An important input from marine carbon is found at the stations offshore from the 10-m isobath. Quantification of the terrigenous component of sedimentary OM is complicated by the heterogeneous composition of the terrigenous end-member. A three-end-member mixing model is therefore required to more accurately evaluate the sources of OM deposited in the study area. The results of the mixing calculation indicate that terrigenous OM (soil-derived OM and vascular plant debris) accounts for ∼79% of the OM deposited as inshore sediments and 66% of OM deposited as offshore sediments. Importantly, the abundance of terrigenous OM is 40% higher in inshore sediments and nearly 85% higher in offshore sediments than indicated by a two-end-member mixing model. Such a result highlights the need to reevaluate the inputs and cycling of soil-derived OM in the coastal ocean.