Performance of the complete travel-time equation of state at simultaneous high pressure and temperature

The complete travel-time equation of state (CT-EOS) is presented by utilizing thermodynamics relations, such as; $$K_T = K_S (1 + \alpha \gamma T)^{ - 1} , \gamma = \frac{{\alpha K_S }}{{\rho C_P }}, \left. {\frac{{\partial C_P }}{{\partial P}}} \right)_T = - \frac{T}{\rho }\left[ {\alpha ^2 + \left. {\frac{{\partial \alpha }}{{\partial T}}} \right)_P } \right], etc.$$ The CT-EOS enables us to analyze ultrasonic experimental data under simultaneous high pressure and high temperature without introducing any assumption, as long as the density, or thermal expansivity, and heat capacity are also available as functions of temperature at zero pressure. The performance of the CT-EOS was examined by using synthesized travel-time data with random noise of 10^?5 and 10^?4 amplitude up to 4 GPa and 1500 K. Those test conditions are to be met with the newly developed GHz interferometry in a gas medium piston cylinder apparatus. The results suggest that the combination of the CT-EOS and accurate experimental data (10^?4 in travel time) can determine thermodynamic and elastic parameters, as well as their derivatives with unprecedented accuracy, yielding second-order pressure derivatives (?² M/?P ²) of the elastic moduli as well as the temperature derivatives of their first-order pressure derivatives ?² M/?P?T). The completeness of the CT-EOS provides an unambiguous criterion to evaluate the compatibility of empirical EOS with experimental data. Furthermore because of this completeness, it offers the possibility of a new and absolute pressure calibration when X-ray (i.e., volume) measurements are made simultaneously with the travel-time measurements.     

Experimental study on the velocity of fragments in collisional breakup

The motion of fragments following a catastrophic destruction by either a normal or an oblique impact at 2.5–2.9 km sec^?1 into cubic and spherical basalt targets was studied with a high-speed framing camera. Velocities at the antipodes of the targets vary as (E/M)^0.75 (E = impact energy; M = target mass) and are lower than 200 m sec^?1 at E/M ? 10⁹ ergs g^?1. Excluding fine-grained particles from the impact site, 70 to 80% by mass fraction of the fragments have velocities lower than twice the antipodal velocity. Comminution and ejection energies wasted in this mass fraction were a few percent of the impact energy at E/M ? 5 × 10⁷ ergs g^?1. During a catastrophic impact into asteroids some of the fragmented bodies can be reconcentrated by mutual gravitation.     

Dendritic cordierite in argillaceous hornfels from the Toki area,Gifu Prefecture,central Japan

Dendritic cordierite occurs in argillaceous hornfels from the Toki area, Gifu Prefecture, Japan. The cordierite crystal consists of c-arms elongated parallel to the c-axes and a-arms perpendicular to the c-axis. The latter arms could be divided into six kinds of untwinned a-arms with different growth directions elongated parallel to the respective a-axis and twinned a-arms elongated parallel to the (110) twin plane. A-arms branch out from c-arms or other a-arms with different growth directions and c-arms sometimes branch out from a-arms, leading to a tree-like structure. Each of the c-arms contains three kinds of domains related by a three-fold axis about the c-axis. These domains are irregularly distributed without any relation to the shape of the c-arm and the domain boundaries are of zigzag shape. This domain arrangement suggests that c-arms grew as hexagonal cordierite and were later transformed into orthorhombic cordierite. The fact that each untwinned a-arm has a fixed growth direction to its orientation suggests that the a-arms grew as an orthorhombic cordierite. From the growth directions of c- and a-arms, orthorhombic and hexagonal phases are considered to grow preferentially along the c- and a-axes, respectively. The branching of a new arm is explained by nucleation on an old arm with a different preferred growth direction. The preferential growth is discussed in terms of a significant chemical potential gradient of the cordierite component. This has been preserved in the mineral zoning observed in the matrix around the cordierite porphyroblast.     

Controlled experiment in the ionosphere with a rocket-borne plasma gun

A controlled active experiment was performed by a plasma gun on-board a rocket to study the plasma stream across the magnetic field in space. A mother and daughter system was employed. An 8 kV 0.8 μF (25 J) capacitor bank on the daughter rocket was discharged every 12 s and about 10¹⁶ ion and electron pairs were ejected. A plasma signal was detected on the electron temperature probe. The propagation speed of the plasma stream is estimated to be 10⁶ cm/s, considerably lower than that obtained in the prelaunch test. The amplitude of the plasma signal decays as the inverse square of the mutual distance between the mother and daughter rockets and this decay is much slower than the free streaming. The importance of the geomagnetic field on the plasma propagation in space is discussed.     

Metallogenesis of Porphyry Cu Deposits of the Western Luzon Arc, Philippines: K-Ar ages, SO3 Contents of Microphenocrystic Apatite and Significance of Intrusive Rocks

Abstract: K–Ar ages of the following porphyry Cu deposits in the western Luzon arc are determined: Lobo-Boneng (10.50.4 Ma), Santo Niño (9.50.3 Ma), Black Mountain (2.10.1 Ma), Dizon (2.50.2 Ma) and Taysan (7.30.2 Ma). Microphenocrys-tic apatite in the late Cenozoic intermediate to silicic intrusions associated with porphyry Cu deposits in the western Luzon arc contains sulfur as SO₃ detectable by electron probe microanalyzer. Sulfur is supposed to have been accommodated dominantly as oxidized species in oxidizing hydrous magmas that generated porphyry Cu deposits. Likewise, such high SO₃ contents in microphenocrystic apatite are common characteristics of the intermediate to silicic magmatism of the western Luzon arc, from tonalitic rocks of the Luzon Central Cordillera of about 15 Ma to an active magmatism at Mount Pinatubo. Thus, the western Luzon arc has been generating porphyry Cu mineralization associated with oxidizing hydrous intermediate to silicic magmatism related to eastward subduction, since Miocene to the present day. Intermediate to silicic rocks since 15 Ma to present-day western Luzon arc generally show high whole-rock Sr/Y ratio ranging from 20 to 184. However, porphyry Cu deposit is not necessarily related to the rocks that show higher Sr/Y ratios compared to the other barren rocks in the western Luzon arc. The characteristics of the intermediate to silicic magma associated with porphyry Cu deposit are not attributed to the composition of the source material of the magma, but to the properties defined by the high activity of oxidized species of sulfur in the fluid phase that is encountered during the generation of intermediate to silicic magmas.     

Attenuation of coda waves and Q c value beneath the Chengdu telemetered seismic network

Based on the single scattering model of coda power spectrum analysis, digital waveform data of 50 events recorded by the real-time processing system of the Chengdu telemetry network are analyzed to estimate the Q _c values of earth medium beneath the Chengdu telemetry network for several specified frequencies. It is found that the Q _c shows the frequency dependency in the form of Q _c = Q ₀ f ⁿ in the range of 1.0 to 20.0Hz. Estimated Q ₀ ranges from 60.83 to 178.05, and n is found to be 0.713 to 1.159. The average value of Q ₀ and n are 117 and 0.978 respectively. This result indicates the strong frequency dependency of the attenuation of coda waves beneath the Chengdu telemetry network. Comparing with the results obtained in other regions of the world, it is found that Q ₀ ⁻¹ value and its change with frequency are similar to those in regions with strong tectonic activity. This subject is supported by the Ministry of Personnel, China for partly sponsoring.     

Occurrence of Halogen-rich Phlogopite in Late Cenozoic Volcanic Rocks in the Japanese Arcs

Abstract. Halogen-rich phlogopite occurs in the groundmass of andesite and dacite lavas from Late Tertiary to Quaternary volcanoes associated with native sulfur and limonite deposits (Shiretoko-Iwozan, Hachimantai, Adatara, Omeshidake, Masaki) and hydrothermal ore deposits (Harukayama, Muineyama, Hishikari) in Japan. The F contents of the halogen-rich phlogopite range from 3.6 to 5.7 wt%, corresponding to atomic F/(F+C1+OH) ratios ranging from 0.45 to 0.69. On the other hand, the Cl contents of the halogen-rich phlogopite are around 0.2 wt%. The atomic Mg/(Mg+Fe) ratios range from 0.69 to 0.83.
The fluorine intercept value [IV(F)] defined by Munoz (1984) of the phlogopites ranges from 0.79 to 3.17, and the chlorine intercept value [IV(Cl)] ranges from -7.11 to -7.77. The observed IV(F) of the phlogopites broadly overlap the range of the IV(F) for biotites from porphyry copper deposits. On the other hand, the observed IV(Cl) are significantly lower than the IV(Cl) for biotites from porphyry copper deposits. Whereas the F contents of the phlogopite appear more prominent compared to the Cl contents, the calculation of halogen intercept values revealed that the phlogopites are enriched in Cl with respect to the element distribution effect of Mg-Fe substitution. Since the degree of Cl enrichment of the phlogopite is more significant compared to that of biotite in porphyry copper deposits, the phlogopites are considered to have formed under the condition of significantly high activity of halogens. Hydrothermal ore deposits may be formed in magmatic hydrothermal system associated with volcanoes where halogen-rich phlogopite is formed by hypersaline fluid.     

Formation and shortening deformation of a back-arc rift basin revealed by deep seismic profiling, central Japan

The northern Fossa Magna (NFM) basin is a Miocene rift system produced in the final stages of the opening of the Sea of Japan. It divides the major structure of Japan into two regions, with north-trending geological structures to the NE of the basin and EW trending structures to the west of the basin. The Itoigawa-Shizuoka Tectonic Line (ISTL) bounds the western part of the northern Fossa Magna and forms an active fault system that displays one of the largest slip rates (4–9 mm/year) in the Japanese islands. Deep seismic reflection and refraction/wide-angle reflection profiling were undertaken in 2002 across the northern part of ISTL in order to delineate structures in the crust, and the deep geometry of the active fault systems. The seismic images are interpreted based on the pattern of reflectors, the surface geology and velocities derived from refraction analysis. The 68-km-long seismic section suggests that the Miocene NFM basin was formed by an east dipping normal fault with a shallow flat segment to 6 km depth and a deeper ramp penetrating to 15 km depth. This low-angle normal fault originated as a comparatively shallow brittle/ductile detachment in a high thermal regime present in the Miocene. The NFM basin was filled by a thick (>6 km) accumulation of sediments. Shortening since the late Neogene is accommodated along NS to NE–SE trending thrust faults that previously accommodated extension and produce fault-related folds on their hanging wall. Based on our balanced geologic cross-section, the total amount of Miocene extension is ca. 42 km and the total amount of late Neogene to Quaternary shortening is ca. 23 km.     

Primary Ore Mineral Assemblage and Fluid Inclusion Study of the Batu Hijau Porphyry Cu-Au Deposit, Sumbawa, Indonesia

Abstract. The Batu Hijau porphyry Cu‐Au deposit, Sumbawa Island, Indonesia, is associated with a tonalitic intrusive complex. The temperature‐pressure condition of mineralization at the Batu Hijau deposit is discussed on the basis of fluid inclusion microthermometry. Then, the initial Cu‐Fe sulfide mineral assemblage is discussed. Bornite and chalcopyrite are major copper ore minerals associated with quartz veinlets. The quartz veinlets have been classified into ‘A’ veinlets associated with bornite, digenite, chalcocite and chalcopyrite, ‘B’ veinlets having chalcopyrite bornite along vuggy center‐line, rare ‘C’ chalcopyrite‐quartz veinlets, and late ‘D’ veinlets consisting of massive pyrite and quartz (Clode et al., 1999). Copper and gold mineralization is associated with abundant ‘A’ quartz veinlets. Abundant fluid inclusions are found in veinlet quartz consisting mainly of gas‐rich inclusions and polyphase inclusions throughout the veinlet types. The hydrothermal activity occurred in temperature‐pressure conditions of aqueous fluid immiscibility into hypersaline brine and dilute vapor. The halite dissolution (Tm[halite]) and liquid‐vapor homogenization (Th) temperatures of the polyphase inclusions in veinlet quartz range from 270 to 472d?C and from 280 to 454d?C, respectively. The estimated salinity ranges from 36 to 47 wt% (NaCl equiv.). The apparent pressures lower than 300 bars are estimated to have been along the liquid‐vapor‐halite curve for the fluid inclusions having the Th lower than the Tm that trapped the brine saturated with halite, or at slightly higher pressure relative to liquid‐vapor‐halite curve for the fluid inclusions having the Th higher than the Tm that trapped the brine unsaturated with halite. The actual temperature and pressure during the hydrothermal activity at the Batu Hijau deposit are estimated to have been around 300d?C and 50 bars. At such temperature‐pressure conditions, the principal and initial Cu‐Fe sulfide mineral assemblages are thought to be chalcopyrite + bornite solid solution (bnss) for the chalcopyrite‐bearing assemblage, and chalcocite‐digenite solid solution and bnss for the chalcopyrite‐free assemblage.