Indoor Air Background Levels of Volatile Organic Compounds and Air-Phase Petroleum Hydrocarbons in Office Buildings and Schools

A background indoor air study has been completed which includes the collection of indoor air samples from office buildings and schools. The anonymous study was designed with input from the U.S. Environmental Protection Agency and the Massachusetts Department of Environmental Protection. The sampling was implemented in 2013, 2014, and 2015 and included the collection of 25 school building samples and 61 office building samples. The study generated 14,668 new indoor air background data points, with samples collected from buildings located in 26 cities in 18 states, including Arizona, California, Connecticut, Indiana, Kansas, Maine, Massachusetts, Minnesota, Montana, New Hampshire, New Jersey, New York, Nevada, North Carolina, Ohio, Texas, Utah, and Washington. Indoor air background concentrations of target compound volatile organic compounds (VOCs) ranged from less than the laboratory method reporting limit of 0.044 μg/m³ to concentrations up to 1190 μg/m³, with hydrocarbon ranges from less than the reporting method limit of 10 μg/m³ to concentrations up to 3000 μg/m³. Some VOCs were identified ubiquitously in indoor air background, and some were identified at concentrations which exceeded risk-based regulatory screening levels. These study results provide useful and updated information on indoor air background and air quality in offices and schools and can be used in future regulatory guidance update considerations, for further examination of relationships between these data and residential study data, in human health risk assessments and risk communication, and in planning future studies.     

Improvement and comparison of the rainfall–runoff methods in SWAT at the monsoonal watershed of Baocun,Eastern China

ABSTRACT

A new physics-based rainfall–runoff method of the Soil and Water Assessment Tool (SWAT) was developed, which integrates a water balance (WB) approach with the variable source area (WB-VSA). This approach was further compared with four methods—soil-water-dependent curve number (CN-Soil), evaporation-dependent curve number (CN-ET), Green and Ampt equation (G&A) and WB—in a monsoonal watershed, Eastern China. The regional sensitivity analysis shows that volumetric efficiency coefficient (VE) with river discharges is sensitive to the most parameters of all approaches. The results of model calibration against VE demonstrate that WB-VSA is the most accurate owing to its reflection of the spatial variation of runoff generation as affected by topography and soil properties. Other methods can also mimic baseflow well, but the G&A and CN-ET simulate floods much worse than the saturation excess runoff approaches (WB-VSA, WB and CN-Soil). Meanwhile, CN-Soil as an empirical method fails to simulate groundwater levels. By contrast, WB-VSA captures them best.

Editor M.C. Acreman; Associate editor S. Kanae     

Temporal patterns in macrograzer effects on epilithic algae and meiofauna: a comparative approach to test for single species and whole grazer community effects

Within the shallow littoral zones of lakes, periphyton is an essential component, representing an important source of primary production and a food resource for herbivores. Periphytic communities are abundantly inhabited by meiofaunal organisms, which are mostly dominated by nematodes. During the last 3 decades, consumer–resource interactions between herbivore consumers and periphytic components (mainly algae) have been intensively studied. Although whole grazer community and single species effects on periphyton are known from field and laboratory experiments, the importance of single, dominant grazer taxa in direct comparison to whole community impacts is unknown. To investigate the continuity of grazing effects of a single, dominant macrograzer (Theodoxus fluviatilis, Gastropoda, Prosobranchia) on epilithic meiofauna and algae with respect to the whole grazer community, a temporally structured field experiment was carried out in Lake Erken (Sweden). Grazer impacts on periphytic algae and meiofauna were tested by controlling macrograzer access to littoral periphyton communities for 8 weeks in an exclosure/enclosure experimental design. Overall, the results showed macrograzer presence to have temporally constant, strongly negative effects on algal biomass as well as meiofaunal abundance and community composition. Moreover, T. fluviatilis alone accounted for up to 80% of the grazing effects, indicative of their ability to regulate periphytic communities in lakes. The present study yields new insights into the effects of a single grazer species and stressed temporal patterns of consumer–resource interactions in freshwater lakes.     

Limitation of fluid flow at the Nankai Trough megasplay fault zone

Along the Nankai Trough megasplay fault off SE Japan, the effect of fluid migration on subduction-related seismogenesis and tsunamigenesis remains unresolved. To investigate the existence and role of fluid flow, a SmartPlug borehole observatory was installed at Site C0010 of the Integrated Ocean Drilling Program NanTroSEIZE Kumano transect, where a shallow branch of the fault was intersected and in situ fluid pressure monitored from August 2009 to November 2010. The tidal signal in the formation showed no phase shift relative to seafloor loading. The attenuation of 0.73 reflects the loading efficiency accurately, and enabled calculation of a formation compressibility of 1.0×10^–9 Pa^–1 and a hydraulic diffusivity (HD) of 1.5×10^–5 m² s^–1. A similar HD is predicted by a tidal response model based on SmartPlug pressure data. By contrast, permeability measurements on intact samples from Site C0004 SE along-strike the splay fault and from Site C0006 in the frontal thrust zone were found to be similar and one magnitude smaller respectively, despite having a higher porosity. This is explained by the presence of fractures, which are covered by the larger scale of in situ measurements at Site C0010. Consequently, HD can be set to be at least 10^–5 m² s^–1 for the splay fault and 10^–6 m² s^–1 for the frontal thrust fault zone. Considering recent publications makes fluid flow at the splay fault unlikely, despite the presence of fractures. If the influence of fractures is limited, then processes leading to fault weakening may be enhanced.     

Analysis of Radionuclide Releases from the Fukushima Dai-ichi Nuclear Power Plant Accident Part II

The present part of the publication (Part II) deals with long range dispersion of radionuclides emitted into the atmosphere during the Fukushima Dai-ichi accident that occurred after the March 11, 2011 tsunami. The first part (Part I) is dedicated to the accident features relying on radionuclide detections performed by monitoring stations of the Comprehensive Nuclear Test Ban Treaty Organization network. In this study, the emissions of the three fission products Cs-137, I-131 and Xe-133 are investigated. Regarding Xe-133, the total release is estimated to be of the order of 6 × 10¹⁸ Bq emitted during the explosions of units 1, 2 and 3. The total source term estimated gives a fraction of core inventory of about 8 × 10¹⁸ Bq at the time of reactors shutdown. This result suggests that at least 80 % of the core inventory has been released into the atmosphere and indicates a broad meltdown of reactor cores. Total atmospheric releases of Cs-137 and I-131 aerosols are estimated to be 10¹⁶ and 10¹⁷ Bq, respectively. By neglecting gas/particulate conversion phenomena, the total release of I-131 (gas + aerosol) could be estimated to be 4 × 10¹⁷ Bq. Atmospheric transport simulations suggest that the main air emissions have occurred during the events of March 14, 2011 (UTC) and that no major release occurred after March 23. The radioactivity emitted into the atmosphere could represent 10 % of the Chernobyl accident releases for I-131 and Cs-137.     

Cold-regions Hydrological Indicators of Change (CHIC) for ecological flow needs assessment

Abstract

Ecological flow needs (EFN) frameworks incorporate a range of ecologically-relevant hydrological variables based on prior knowledge of river regime characteristics. However, when applied in cold regions, these approaches have largely ignored the influence of winter ice cover and the spring freshet on hydrological regimes: key components of river systems in cold regions with important direct effects on water quality, aquatic habitat and ecology. Here, we combine a review of the published literature on cold-regions hydrology and hydro-ecology with available hydrometric information for sites across Canada, a major cold-region country, to explore phenomena unique to these systems. We identify several ecologically-relevant hydrological measures (i.e. annual ice on/off dates, ice-cover duration, spring freshet initiation, peak water level during river ice break-up), pairing these with established metrics for incorporation into an enhanced suite of indicators specifically designed for cold regions. This paper presents the Cold-regions Hydrological Indicators of Change (CHIC), which can provide the basis for the assessment of EFN and climate change assessments in cold-region river ecosystems.

Editor Z.W. Kundzewicz; Guest editor M. Acreman

Citation Peters, D.L., Monk, W.A., and Baird, D.J., 2014. Cold-regions Hydrological Indicators of Change (CHIC) for ecological flow needs assessment. Hydrological Sciences Journal, 59 (3–4), 502–516.     

Development of risk matrices for evaluating climatic change responses of forested habitats

We present an approach to assess and compare risk from climate change among multiple species through a risk matrix, in which managers can quickly prioritize for species that need to have strategies developed, evaluated further, or watched. We base the matrix upon earlier work towards the National Climate Assessment for potential damage to infrastructures from climate change. Risk is defined here as the product of the likelihood of an event occurring and the consequences or impact of that event. In the context of species habitats, the likelihood component is related to the potential changes in suitable habitat modeled at various times during this century. Consequences are related to the adaptability of the species to cope with the changes, especially the increasing intensity and/or frequency of disturbance events that are projected. We derived consequence scores from nine biological and 12 disturbance characteristics that were pulled from literature for each species. All data were generated from an atlas of climate change for 134 trees of the eastern United States (www.nrs.fs.fed.us/atlas). We show examples which depict a wide range of risk for tree species of northern Wisconsin, including species that may gain substantial habitat as well as lose substantial habitat, both of which will require the development of strategies to help the ecosystems adapt to such changes.     

Chemical Separation of Tungsten and Other Trace Elements for TIMS Isotope Ratio Measurements Using Organic Acids

One requirement for isotope ratio measurement results with small measurement uncertainties is that the element of interest is effectively separated from the sample matrix. Efficient chemical separation of W from matrix components, especially Ti, can be challenging, particularly for large test portion masses (> 1 g). We present a new W separation procedure that takes advantage of the distinct complexation behaviour of Ti and W with citrate ligand in a moderately low pH, oxidising solution. This preparation procedure can reduce the Ti/W ratio of large (4–10 g) basaltic (i.e., high‐matrix) test portions by a factor of 10⁵, relative to their original compositions, in a two‐step separation procedure. The procedure additionally provides a separate, well‐purified Mo fraction. We show that optimal separation requires precise selection of reagent concentrations and sample load. The procedure was employed to determine the μ¹⁸²W composition of BHVO‐2 as ?6.7 ± 4.2 (2 standard deviation, 2s). The principles derived from this method may prove useful for chemical separation of other elements used for geochemical and cosmochemical applications given an appropriate selection of organic acid. Future successful applications of this method may reveal that the use of organic acids as procedural reagents is a currently under‐utilised tool for efficient chemical separation protocols.     

Mojave Mars simulant—Characterization of a new geologic Mars analog

We have identified and characterized a basaltic Mars simulant that is available as whole rocks, sand and dust. The source rock for the simulant is a basalt mined from the Tertiary Tropico Group in the western Mojave Desert. The Mojave Mars Simulant (MMS) was chosen for its inert hygroscopic characteristics, its availability in a variety of forms, and its physical and chemical characteristics. The MMS dust and MMS sand are produced by mechanically crushing basaltic boulders. This is a process that more closely resembles the weathering/comminution processes on Mars where impact events and aerodynamic interactions provide comminution in the (relative) absence of water and organics. MMS is among the suite of test rocks and soils that was used in the development of the 2007/8 Phoenix Scout and is being used in the 2009 Mars Science Laboratory (MSL) missions. The MMS development team is using the simulant for research that centers on sampling tool interactions in icy soils. Herein we describe the physical properties and chemical composition of this new Mars simulant.     

Influence of stratospheric ozone changes on long-term trends in the meso- and lower thermosphere

As predicted by model calculations, long-term changes in the stratospheric ozone content should influence trends in the meso- and thermosphere also. These predictions have been tested by means of ionospheric reflection height data in the low-frequency (LF) range and critical frequency data series of the ionospheric E layer, foE, observed at different stations around the world. It was shown that an essential part of the derived trends in the mesosphere and in the lower thermosphere is correlated with long-term changes of the atmospheric ozone content. During the sub-interval with the strongest ozone decrease (1979–1995) the detected ionospheric trends are most pronounced. Additionally was also demonstrated that the longitudinally dependent ozone trends are related to similar variations in the foE trends.