Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.     

Pattern and chronology of glacial Lake Peace shorelines and implications for isostacy and ice‐sheet configuration in northeastern British Columbia,Canada

Recognition of positions of glacial lakes along the margin of continental ice sheets is critical in reconstructing ice configuration during deglaciation. Advances in remote sensing technology (e.g. LiDAR) have enabled the generation of accurate digital‐elevation models (DEMs) that reveal unprecedented geomorphic detail. Combined with geographical information systems, these tools have considerably advanced the mapping and correlation of geomorphic features such as relict shorelines. Shorelines of glacial Lake Peace (GLP) developed between the Laurentide and Cordilleran ice sheets in northeastern British Columbia and northwestern Alberta. Shoreline mapping from high resolution DEMs produced more than 55 500 elevation data points from 3231 shorelines, enabling the identification of four major phases of GLP: Phase I (altitude 960–990 m a.s.l.); Phase II (890–915 m a.s.l.); Phase III (810–865 m a.s.l.); and Phase IV (724–733 m a.s.l.). The timing of Phase II of GLP is estimated by two optical ages of <16.0±2.5 and 14.2±0.5 ka BP. Extensive mapping of the shorelines allows for measuring of glacial isostatic adjustment as ice retreated. Shorelines currently dip to the northeast at around 0.4–0.5 m km^?1. This slope reflects the asynchronous retreat of the Cordilleran (CIS) and Laurentide (LIS) ice sheets. The relative uplift in the southwest of the study area within the Rocky Mountains and foothills suggests that the Late Wisconsinan (MIS 2) CIS persisted in the foothill after the LIS lost mass and retreated, or that the Late Wisconsinan CIS was very thick and caused deep crustal loading, which resulted in more uplift in the southwest before reaching equilibrium during, or shortly after deglaciation.     

Class I and Class II Rocks: Implication of Self-sustaining Fracturing in Brittle Compression

Tests to determine the complete stress–strain curve of rocks indicate whether the rocks can be classified a Class I or Class II. Class II rocks exhibits the potential for self-sustained failure in the post-peak region. The purpose of the research described in this paper was to investigate whether or not this self-sustained failure characteristic is related to the fragmentation of the rock. The aim of the research was, therefore, to determine possible relationships between fragmentation and various properties of several rocks types, including the influence of the Class II characteristic. Fragmentation of rock depends on its self-sustaining failure behaviour and the energy available in the post-peak region to shatter the rock. The correlation of static and dynamic rock properties with size of fragments resulting from compression tests demonstrate clear relationships of Class II rocks, but the same cannot be said for Class I rocks. Analyses of test results show that fragmentation increases with an increase in rock strength, and is explosive for Class II rocks. Probability density distributions were constructed to show the overall comparison of fragment sizes produced during failure of Class II and Class rocks. The calculated probability of passing at X₅₀ and X₁₀ sieve sizes show that Class II rocks as a group are more finely fragmented. It can therefore be concluded that, when breaking rocks under the same steady loading conditions, Class II rocks will show greater fragmentation than Class I rocks.     

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.     

Kampelite,Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O,a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex (Kola Peninsula,Russia)

Mineralogy and Petrology - Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma,...     

Development,urban planning and political decisions. A triad that built territories at risk

Natural Hazards - Chilean geography exposes the country to high-level risks such as earthquakes and tsunamis. The disasters of 1930, 1960, 2010, and 2014 testify to the continuous link between...     

Activity-composition relations in FeTiO3-MnTiO3 ilmenite solid solutions from EMF measurements at 1050–1300 K

The activity of FeTiO₃ in the binary ilmenitepyrophanite (FeTiO₃-MnTiO₃) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO₃=2 Fe+2 TiO₂+O₂ in T-O₂ space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, W _Fe-Mn ^ilm , of 2.2±0.3 kJ g-atom^–1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives W _Fe-Mn ^gt =1.2±0.5 kJ g-atom^–1 for the almandine-spessartine (Fe₃Al₂Si₃O₁₂-Mn₃Al₂Si₃O₁₂) solid solution.     

March 1986 eruptive episodes at Piton de la Fournaise volcano (Reunion Island)

From May 1985 to April 1986 five discrete eruptions have occurred at Piton de la Fournaise volcano. On March the 17th, a sixth episode began with four distinct stages. They took place along the southeast rift zone of the volcano, from the summit to the sea coast. It was the first rift zone eruption in the south since 1800 A.D. and the first ever monitored at Piton de la Fournaise volcano.Three fissural vents opened at decreasing altitude emitting about 12 to 15 × 10⁶ m³ of olivine basalts between 19th March and 1st April. Strong seismic activity was accompanied by deformation of the summit area, and large-scale variations of the magnetic field. A summital event characterized the end of the flank activity with collapse of a new pit-crater and outflow of small amounts of degassed aphyric basalt.