Geochemistry and origin of Archean volcanic rocks from the Upper Keewatin assemblage (ca 2.7 Ga), Lake of the Woods Greenstone Belt, Western Wabigoon Subprovince, Superior Province, Canada

Abstract   Volcanic rocks from the Upper Keewatin assemblage ( ca 2720 Ma) were geochemically classified into five groups; komatiites, tholeiitic rocks having near-flat primitive mantle-normalized abundance patterns, Nb-enriched basalts and andesites (NEBA) plus normal calc-alkaline (NCA) rocks, adakites and shoshonites. The adakites having [La/Yb]_N >30 and <30 were probably derived from felsic magmas formed by partial melting of a subducted slab at relatively greater and smaller depths, respectively. Ascending adakite magmas, by interaction with the overlying mantle wedge, decreased in Al₂O₃ / Y ratio and selectively lost high-field strength elements, thereby forming mantle sources for both NEBA + NCA and shoshonite magmas. Under the influence of a mantle plume, the source of komatiites, the NEBA + NCA magmas were generated from that part of the mantle wedge metasomatized by adakite magmas having [La / Yb]_N <30, and tholeiitic magmas from unmetasomatized part of the same mantle wedge. Magmas of both adakites having [La / Yb]_N >30 and shoshonites were generated in a normal Archean Arc system setting.     

Trace element composition and degree of partial melting of pelitic migmatites from the Aoyama area, Ryoke metamorphic belt, SW Japan: Implications for the source region of tourmaline leucogranites

Degree of partial melting of pelitic migmatites from the Aoyama area, Ryoke metamorphic belt, SW Japan is determined utilizing whole-rock trace element compositions. The key samples used in this study were taken from the migmatite front of this area and have interboudin partitions filled with tourmaline-bearing leucosome. These samples are almost perfectly separated into leucosome (melt) and surrounding matrix (solid). This textural feature enables an estimate of the melting degree by a simple mass-balance calculation, giving the result of 5–11 wt.% of partial melting. Similar calculations applied to the migmatite samples, which assume average migmatite compositions to be the residue solid fraction, give degree of melt extraction of 12–14 wt.% from the migmatite zone. The similarity of the estimated melting degree of 5–11 wt.% with that in other tourmaline–leucogranites, such as Harney Peak leucogranite and Himalayan leucogranites, in spite of differences in formation process implies that the production of tourmaline leucogranites is limited to low degrees of partial melting around 10 wt.%, probably controlled by the breakdown of sink minerals for boron such as muscovite and tourmaline at a relatively early stage of partial melting. Because the amount of boron originally available in the pelitic source rock is limited (on average 100 ppm), 10 wt.% of melting locally requires almost complete breakdown of boron sink mineral(s) in the source rock, in order to provide sufficient boron into the melt to saturate it in tourmaline. This, in turn, means that boron-depleted metapelite regions are important candidates for the source regions of tourmaline leucogranites.