Near-Infrared Colors of the Binary Kuiper Belt Object 1998 WW 31

We have measured near-infrared colorsof the binary Kuiper Belt object (KBO)1998 WW₃₁ using the Subaru Telescope withadaptive optics. The satellite was detectednear its perigee and apogee(0.18“ and 1.2” apart from the primary).The primary and the satellite have similar H–Kcolors, while the satellite is redder thanthe primary in J–H. Combined with the Rband magnitude previously published byVeillet et al., 2002, the color of the primaryis consistent with that of optically red KBOs. Thesatellite's R-, J-, H-colors suggest thepresence of ～1 μm absorption band dueto rock-forming minerals. If the surface of thesatellite is mainly composed by olivine, thesatellite's albedo is higher value than the canonicallyassumed value of 4%.     

The 1.7- to 4.2-μm spectrum of asteroid 1 Ceres: Evidence for structural water in clay minerals

A high-resolution Fourier spectrum (1.7–3.5 μm) and medium-resolution spectrophotometry (2.7–4.2 μm) were obtained for Asteroid 1 Ceres. The presence of the 3-μm absorption feature due to water of hydration was confirmed. The 3-μm feature is compared with the 3-μm bands due to water of hydration in clays and salts. It is concluded that the spectrum of Ceres shows a strong absorption at 2.7–2.8 μm due to structural OH groups in clay minerals. The dominant minerals on the surface of Ceres are therefore hydrated clay minerals structurally similar to terrestrial montmorillonites. There is also a narrow absorption feature at 3.1 μm which is attributable to a very small amount of water ice on Ceres. This is the first evidence for ice on the surface of an asteroid.     

Geochemical evolution of highly alkaline and saline tank waste plumes during seepage through vadose zone sediments

Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m) maintained at 70°C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH⁻ neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH > 10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past.     

Nitrate pollution of groundwater in the Yellow River delta,China

Nitrate pollution of groundwater in the Yellow River delta, China is an important issue related not only to nitrate dispersion and health concerns but also to mass transport and interactions of groundwater, sea, and river waters in the coastal area. The spatial distribution of nitrate, nitrate sources, and nitrogen transformation processes were investigated by field surveys and geochemical methods. Nitrate occurred mainly in shallow layers and had a spatial distribution coinciding with geomorphology and land/water use. Irrigation water from the Yellow River and anthropogenic waste are two main nitrogen sources of nitrate in the delta, and both denitrification and mixing processes could take place according to characteristics identified by ionic and isotopic data.     

The diameter and albedo of 1943 Anteros

We report the results of broadband visual and infrared photometry of the Apollo-Amor asteroid 1943 Anteros during its 1980 apparition. By means of a radiometric model, we calculate a diameter of 2.3 ± 0.2 km and a visual geometric albedo of 0.13 ± 0.03. The albedo and reflectance spectrum of Anteros imply that it is a type S asteroid. Thus, Anteros may have a silicate surface similar to other Apollo-Amor asteroids as well as some stony-iron meteorites.     

Mars: Far-infrared spectra and thermal-emission models

Spectra of Mars from 100 to 360 cm^?1 were obtained during three different observation periods from NASA's Kuiper Airborne Observatory. Also, a new thermal model was constructed for the surface of Mars, and synthetic spectra were computed from the models to compare with the observations. The models include the effects of a dusty atmosphere which absorbs, scatters, and reradiates energy. The synthetic spectra show significant effects on disk-averaged brigthness temperatures, as well as absorption features, due to silicate dust. The spectra of Mars, which are ratios of Mars to the Moon, do not fit the synthetic spectra unless the surface emissivities of Mars and the Moon have different dependencies on wavelenght. A possible explanation for this behavior is a difference in soil particle-size distributions between Mars and the Moon, with Mars being depleted in large particles compared to the Moon. Small particles are consistent with clay minerals which have been suggested elsewhere as constituents of the Martian surface.     

Organic carbon distribution, speciation, and elemental correlations within soil microaggregates: Applications of STXM and NEXAFS spectroscopy

Soils contain the largest inventory of organic carbon on the Earth’s surface. Therefore, it is important to understand how soil organic carbon (SOC) is distributed in soils. This study directly measured SOC distributions within soil microaggregates and its associations with major soil elements from three soil groups (Phaeozem, Cambisol, and Ultisol), using scanning transmission X-ray microscopy (STXM) and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy at a spatial resolution of 30 nm. Unlike previous studies, small intact soil microaggregates were examined directly in order to avoid preparatory procedures that might alter C speciation. We found that SOC exists as distinct particles (10s to 100s of nm) and as ubiquitous thin coatings on clay minerals and iron-oxides coatings. The distinct SOC particles have higher fractions of aromatic C than the coatings. NEXAFS spectra of the C coatings within individual microaggregates were relatively similar. In the Phaeozem soil, the pervasive spectral features were those of phenolic and carboxylic C, while in the Cambisol soil the most common spectral feature was the carboxyl peak. The Ultisol soil displayed a diffuse distribution of aromatic, phenolic, and carboxylic C peaks over all surfaces. In general, a wide range of C functional groups coexist within individual microaggregates. In this work we were able to, for the first time, directly quantify the major mineral elemental (Si, Al, Ca, Fe, K, Ti) compositions simultaneously with C distribution and speciation at the nm to μm scale. These direct microscale measurements will help improve understanding on SOC-mineral associations in soil environments.     

Further observations of 8-μm polar brightenings of Jupiter

North to south scans of Jupiter at 7.8-μm wavelength in early 1981 confirm polar brightening events that correlate with LCM_III, such that a polar limb is bright when the corresponding magnetic pole is tilted eartward. The correlation with magnetic features of the planet suggests that the energy source for the brightenings is magnetospheric particles incident upon the polar regions of the atmosphere. The northern polar events are more prominent and more regular than the southern ones. The polar emission may be indirectly related to the ultraviolet absorber observed near the poles by Voyager 2.     

Poroelastic Modeling of a Heterogeneous Geologic Medium: A Case Study from Kanto Basin in Japan

Vertical geological heterogeneity, such as clay content and grain size variation, may affect land subsidence caused by groundwater extraction. In order to test this hypothesis, one-dimensional pore-water mass balance and force balance equations of a water-saturated poroelastic medium were solved under different heterogeneous geological conditions. Results showed that clay content and grain size variation in sandstone could affect subsidence rates by up to an order of magnitude due to the changes in stiffness and permeability of the medium, indicating the importance of small-scale heterogeneity in subsidence simulation studies. Predicted values of subsidence were in good agreement with field measurements for two sites in the Kanto groundwater basin in Japan, showing the applicability of the model to other groundwater basins with clay-rich aquifers.