WEATHERING TRENDS IN FINE DEBRIS BENEATH A SNOW PATCH,NIWOT RIDGE,FRONT RANGE,COLORADO

Seven soil pits dug in a downhill sequence beneath Martinelli snow patch, Niwot Ridge, Front Range, Colorado, reveal that soils are coarse-grained with only limited evidence of silt translocation. Clay mineralogy within the pits exhibits a widespread and distinct change at a depth of ～15–20 cm. The most common characteristic of this change is a distinct increase in vermiculite in the lower layer, usually accompanied by a decrease in kaolinite and/or smectite. This pattern is interpreted to reflect decreased weathering intensity with depth. Microenvironments beneath the snow patch which exhibit high chemical weathering rates on coarse surficial debris also appear to experience high rates of clay production relative to referenced dry alpine sites, with specific clay mineralogies varying in a fashion commonly found in humid temperate environments. Data generated in this study appear to provide site-specific support for the regionally-developed Synthetic Alpine Slope Model. Spatial variations in eolian additions and meltwater produce complex patterns in chemical weathering of fines beneath large snow patches, although the nature of clay-mineral change is typical of humid, temperate, mid-latitude environments. [Key words: chemical weathering, alpine environments, clay mineralogy, Synthetic Alpine Slope Model.]     

Enigmatic Efflorescence in Kärkevagge, Swedish Lapland: The Key to Chemical Weathering?

The second marvel to catch the eye of the visitor to Kärkevagge, after the impressive boulder deposit on the floor of the valley, is the series of prominent white stripes running down the valley's dark cliffs. Streams and springs descending the eastern flank of Kärkevagge are marked by the presence of whitish coatings on the black rock surfaces and on cobbles lining ephemeral waterways. These were referred to as 'lime crusts' by early investigators, but they are not reactive to HCl. We believe that they are a precipitate resulting from acid attack on the local rocks. Pyrite is common in many of the rocks in the valley and its oxidation produces sulfuric acid. As the dissolved mineral elements are carried in the drainage water, efflorescence forms on the surfaces where the water flows due to evaporation or to changes in temperature. The exact mineralogy of the white crusts is unknown, but the crusts are dominated by Al, S, and O, and in some cases by Ca, depending on the substrate and local conditions. Gypsum, illite, and chlorite have been identified by X–ray diffraction of some scrapings of white–coated rocks. However, we believe that some unidentified oxy–hydroxy aluminum sulfates make up the bulk of the precipitates.     

The fiberless multislit spectrograph SFM

We describe the multislit spectrograph SFM. It is designed to obtain simultaneously spectrograms of faint objects over a field of 10 arcminutes for an entrance aperture ratio f/10, or of 15 arcmin for f/8. The SFM makes the dispersed image of the entrance slits directly, without any fiber optics. The number of entrance slits can be as large as a few hundreds, depending on the distribution of the sources on the sky and on the wavelength range. The present reciprocal dispersion is 79Åmm^–1 in the wavelength range 3600 – 6400Å. The SFM is expected to reachm _v22 with a signal to noise ratio of 10 for a spectral resolution of 3.3Å and an integration time of 5 hours, when used with the photon counting detector CP40.Radial velocities can be measured either by using calibration spectrograms or by the objective prism technique.The mask of entrance slits is made photochemically from a plate previously recorded of the field to be observed, taken during the same observing run. The auxiliary equipment Mascograph, specially designed for this purpose, is described.First spectrograms in the field of M15 obtained with the SFM using the Calar-Alto 3.50m telescope are presented.Based on observations collected at the Calar-Alto 3.5m telescope, operated by the German MPIfA (Heidelberg), and at the 3.60m CFHT, operated jointly by the Canadian SRC, the French CNRS and the University of Hawaii     

Simple Chloride Sensors for Continuous Groundwater Monitoring

The development of chloride sensors which can be used for continuous, on‐line monitoring of groundwater could be very valuable in the management of our coastal water resources. However, sensor stability, drift, and durability all need to be addressed in order for the sensors to be used in continuous application. This study looks at the development of a simple, inexpensive chloride electrode, and evaluates its performance under continuous use, both in the laboratory and in a field test in a monitoring well. The results from the study showed a consistent response to changing chloride concentrations over longer periods. The signal was seen to be stable, with regular drift in both laboratory and field test. In the field application, the sensor signal was corrected for drift, and errors were observed to be under 7% of that of conductivity measurements. The study also found that the chloride sensor remained responsive even at low chloride concentrations, where the conductivity electrode was no longer responding to changing chloride levels. With the results, it is believed that the simple chloride sensor could be used for continuous monitoring of groundwater quality.     

Crude Oil Metabolites in Groundwater at Two Spill Sites

Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.     

Late Miocene paleoenvironment of the Lambert Graben embayment, East Antarctica, evident from: Mollusc paleontology, sedimentology and geochemistry

The Upper Miocene (10.7–9.0 Ma) Battye Glacier Formation was deposited 250 km inland from the modern Amery Ice Shelf edge in Prydz Bay, East Antarctica. The composition of clay minerals distinguishes a Lower Member, which reflects regional erosion of Precambrian metamorphic basement, from an Upper Member, which records increased erosion of local Permian–Triassic Amery Group strata. The Upper Member was deposited in an ice-proximal environment akin to the modern fjords of East Greenland, with substantial diamict deposition resulting from melting iceberg discharge. The Lower Member was deposited in an ice-distal environment and included the accumulation of the fossil-bearing McLeod Beds. The McLeod Beds contain much siliceous biogenic sediment (≤ 15% opal), which is rare to absent in the predominantly hemipelagic mud of modern East Greenland fjords. The McLeod Beds also contain largely monospecific in situ Hiatella sp. mollusc assemblages suggestive of environmental stress, potentially caused by low salinity melt-water and a high input of terrigenous sediment, which excluded most other benthic taxa. Geochemical results from primary aragonite in Hiatella shells imply large freshwater input into the marine environment during mollusc growth, causing low δ¹⁸O, Na, Mg and high Fe values. The present study indicates that iceberg melt-water influence entering the marine environment was greater during the Late Miocene than today around Antarctica, and documents the paleoenvironment associated with a discrete period of ice margin retreat and marine incursion into the Lambert embayment.     

Hydrogeological aspects of bacterial contamination of some western Ireland karstic limestone aquifers

The paper describes the results of a study of the relationship between the hydrogeology of some karstic aquifers and bacterial contamination. The study showed that even where the contaminant load is low the nature of the aquifers ensured that contamination was endemic. Although a close correlation between antecedent precipitation and contamination was demonstrated, it was a complex relationship and further investigation, particularly of flood pulses, would be necessary to elucidate the relationship.     

Late Quaternary marine deposition in New South Wales and southern Queensland — An evolutionary model

From new data on coastal and continental shelf morphology, sediments, stratigraphy and chronology, it is possible to formulate a general model of late Quaternary marine sedimentation, for New South Wales and southern Queensland. This model integrates various factors influencing deposition in coastal and shelf environments, in relation to glacio‐eustatic sea level oscillations.

The model involves several components, including (i) very slow to negligible continental margin subsidence during the Quaternary, (ii) an inherited geomorphic framework; (iii) oscillations of sea level of c 100 m amplitude every 100 000 years, with interglacial high sea levels being close to present and only the Last Interglacial being significantly higher; and (iv) a wave climate that induces a potential south to north littoral sand transport at all sea level positions.

Terrigenous sediment that is moved from the hinterland through embayments to the shelf is either stored as barrier, estuarine or inner shelf deposits, or lost to depositional sinks on the continental slope or into coastal dune fields. Over many glacial‐interglacial cycles, sand has been progressively moved northward and has accumulated in vast aeolian sand deposits in southern Queensland. Littoral sand transport was especially effective during sea levels lower than present. The relatively shallow and lower gradient shelf north of Newcastle (33°S) has encouraged preservation at the coast of a wide range of depositional morphologies, including Pleistocene barriers, whereas the steeper southern shelf has induced net sediment loss seawards and shoreline erosion, excpt in the Holocene. To account for Holocene barrier development in the southern region, the model invokes reworking of sand deposits stranded high on the inner shelf at the end of the Pleistocene Epoch. These were in disequilibrium with Postglacial marine processes that operated at a lower level of the sea than did those during the Last Interglacial maximum.     

Chemical denudation rates in Kärkevagge, Swedish Lapland

This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km⁻² a⁻¹ were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.