Decomposition of kyanite and solubility of Al2O3 in stishovite at high pressure and high temperature conditions

In order to constrain the high-pressure behavior of kyanite, multi-anvil experiments have been carried out from 15 to 25 GPa, and 1,350 to 2,500°C. Both forward and reversal approaches to phase equilibria were adopted in these experiments. We find that kyanite breaks down to stishovite + corundum at pressures above ∼15 GPa, and stishovite + corundum should be the stable phase assemblage at the pressure–temperature conditions of the transition zone and the uppermost part of the lower mantle of the Earth, in agreement with previous multi-anvil experimental studies and ab initio calculation results, but in disagreement with some of the diamond-anvil cell experimental studies in the literature. The Al₂O₃ solubility in nominally dry stishovite has been tightly bracketed by forward and reversal experiments; it is slightly but consistently reduced by pressure increase. Its response to temperature increase, however, is more complicated: increases at low temperatures, maximizes at around 2,000°C, and perhaps decreases at higher temperatures. Consequently, the Al₂O₃ solubility in dry stishovite at conditions of high temperature–high pressure is very limited.     

Vertical material flux under seasonal sea ice in the Okhotsk Sea north of Hokkaido, Japan

Downward material fluxes under seasonal sea ice were measured using a time-series sediment trap installed at an offshore site in the Okhotsk Sea north of Hokkaido, Japan, from 13 January to 23 March 2005. The maximum fluxes of lithogenic material (753 mg m⁻² day⁻¹) and organic matter (mainly detritus; 333 mg m⁻² day⁻¹) were recorded during the period in which sea ice drifted ashore and increased in extent, from 13 January to 9 February. Organic matter as fecal pellets (81–93 mg m⁻² day⁻¹) and opal as biosilica (51–67 mg m⁻² day⁻¹), representing diatom fluxes, were abundant in sediment trap samples obtained during the period of full sea ice coverage from 10 February to 9 March. Microscopic observations revealed that fecal pellets were largely diatom frustules, suggesting that zooplankton actively grazed on ice algae during the period of full sea ice coverage. During the period of retreating sea ice, from 10 to 23 March, the phytoplankton flux showed a rapid increase (from 9.5 to 22.5 × 10⁶ cells m⁻² day⁻¹), reflecting their release into the water column as the sea ice melted. Our results demonstrate that the quantity and quality of sinking biogenic and lithogenic materials vary with the seasonal extent of sea ice in mid-winter.     

A basic study on the application of LRFD in “the technical standard for port and harbour facilities in Japan”: a case of gravity type quay wall in a persistent design situation

ABSTRACT

The Partial Factor Method (PFM) based on the Level 1 reliability design method was introduced in 2007 to the Technical Standards for Port and Harbour Facilities (TSPHF-2007) in Japan. After nearly 10 years of practical use of TSPHF-2007, the design standard has been revised based on requests from the practitioners who recommend the transition from the PFM to the Load Resistance Factor Design (LRFD). In this paper, we discuss the setting method of the target failure probability to determine the partial factors based on code calibration. Furthermore, we examine the impacts of implementing the LRFD concept to the TSPHF by taking the sliding and overturning of a gravity type quay wall as an example to represent port and harbour facilities. We found no practical difference in caisson width derived using the LRFD and the PFM, whereas the degree of matching of the target failure probability was somewhat more precise for the PFM. This finding indicates that the LRFD is a more reasonable design method than the PFM in terms of the simplicity of the performance function itself and the ease of engineering interpretation during the design procedure.     

Flow behavior and microstructures of hydrous olivine aggregates at upper mantle pressures and temperatures

Deformation experiments on olivine aggregates were performed under hydrous conditions using a deformation-DIA apparatus combined with synchrotron in situ X-ray observations at pressures of 1.5–9.8 GPa, temperatures of 1223–1800 K, and strain rates ranging from 0.8 × 10^?5 to 7.5 × 10^?5 s^?1. The pressure and strain rate dependencies of the plasticity of hydrous olivine may be described by an activation volume of 17 ± 6 cm³ mol^?1 and a stress exponent of 3.2 ± 0.6 at temperatures of 1323–1423 K. A comparison between previous data sets and our results at a normalized temperature and a strain rate showed that the creep strength of hydrous olivine deformed at 1323–1423 K is much weaker than that for the dislocation creep of water-saturated olivine and is similar to that for diffusional creep and dislocation-accommodated grain boundary sliding, while dislocation microstructures showing the [001] slip or the [001](100) slip system were developed. At temperatures of 1633–1800 K, a much stronger pressure effect on creep strength was observed for olivine with an activation volume of 27 ± 7 cm³ mol^?1 assuming a stress exponent of 3.5, water fugacity exponent of 1.2, and activation energy of 520 kJ mol^?1 (i.e., power-law dislocation creep of hydrous olivine). Because of the weak pressure dependence of the rheology of hydrous olivine at lower temperatures, water weakening of olivine could be effective in the deeper and colder part of Earth’s upper mantle.     

霞浦湖沉积物需氧速率的研究

１９９５年２月,用大口径采样器采集日本霞浦湖土浦湾和湖心柱状沉积物样品,在２０℃恒温蔽光封闭条件下,研究了该湖泊沉积物需氧（ＳＯＤ）速率及实验前后上覆水和间隙水中形态营养物浓度变化,结果表明,实验初期（０－５ｈ）ＳＯＤ速率随时间呈线性上升,大于５ｈ后呈非线性下降,对线性部分计算的ＳＯＤ速率约在０．６－１．８ｍｇ／（ｍ＾２．ｄ）之间,实验发现,上覆水和表层间隙水中形态营养物Ｆｅ（Ⅱ）,ＮＨ＾＋４－Ｎ     

Predictability of storm wave heights in the ice-free Beaufort Sea

A predictability study on wave forecast of the Arctic Ocean is necessary to help identify hazardous areas and ensure sustainable shipping along the trans-Arctic routes. To assist with validation of the Arctic Ocean wave model, two drifting wave buoys were deployed off Point Barrow, Alaska for two months in September 2016. Both buoys measured significant wave heights exceeding 4 m during two different storm events on 19 September and 22 October. The NOAA-WAVEWATCH III^? model with 16-km resolution was forced using wind and sea ice reanalysis data and obtained general agreement with the observation. The September storm was reproduced well; however, model accuracy deteriorated in October with a negative wave height bias of around 1 m during the October storm. Utilising reanalysis data, including the most up-to-date ERA5, this study investigated the cause: grid resolution, wind and ice forcing, and in situ sea level pressure observations assimilated for reanalysis. The analysis has found that there is a 20% reduction of in situ SLP observations in the area of interest, presumably due to fewer ships and deployment options during the sea ice advance period. The 63-member atmospheric ensemble reanalysis, ALERA2, has shown that this led to a larger ensemble spread in the October monthly mean wind field compared to September. Since atmospheric physics is complex during sea ice advance, it is speculated that the elevated uncertainty of synoptic-scale wind caused the negative wave model bias. This has implications for wave hindcasts and forecasts in the Arctic Ocean.     

Anomalous behavior of cristobalite in helium under high pressure

We have investigated the high-pressure behavior of cristobalite in helium by powder X-ray diffraction. Cristobalite transformed to a new phase at about 8 GPa. This phase is supposed to have a molar volume of about 30 % larger than cristobalite, suggesting the dissolution of helium atoms in its interstitial voids. On further compression, the new phase transformed to a different phase which showed an X-ray diffraction pattern similar to cristobalite X-I at about 21 GPa. On the other hand, when the new phase was decompressed, it transformed to another new phase at about 7 GPa, which is also supposed to have a molar volume of about 25 % larger than cristobalite. On further decompression, the second new phase transformed to cristobalite II at about 2 GPa. In contrast to cristobalite, quartz did not show anomalous behavior in helium. The behavior of cristobalite in helium was also consistent with that in other mediums up to about 8 GPa, where the volume of cristobalite became close to that of quartz. These results suggest that dissolution of helium may be controlled not only by the density (amount of voids) but also by the network structure of SiO₄ tetrahedra (topology of voids).     

CaPtO3 as a novel post-perovskite oxide

Structural, morphological, magnetic, and thermal properties have been investigated for a novel post-perovskite oxide CaPtO₃ synthesized under high pressure. By comparing obtained structural parameters with those for known post-perovskite compounds, we argue that the chemical bond has a strong covalent character. Precise measurements of the Langevin susceptibility χ ₀ = −9.6 × 10⁻⁵ emu/mol and Debye temperature θ ∼ 470 K provide a good opportunity to confirm the reliability of first-principle calculations on predicting physical properties of the Earth’s D” layer.