Dissolved and particulate trace metal fluxes through the central English Channel, and the influence of coastal gyres

Measurements of dissolved Cd, Co, Cu, Mn, Ni, Pb, and Zn have been made on a seasonal basis at five stations on a north–south transect across the central English Channel between Cherbourg and the Isle of Wight. Vertical and horizontal distributions of dissolved Cd, Pb, Cu and Zn are relatively uniform except for sampling sites near the English coast. Dissolved Mn and Co show increased concentrations in the English coastal waters, and for Mn the seasonal trend in concentration follows the pattern seen in the Strait of Dover with higher values in the late summer. Ni and Cu are higher in concentration on the English side, which reflects mainly riverine sources. Measurements were also made of particulate forms of the metals above plus particulate Al, Ca, Fe, Mg, Sr and Ti. Water column concentrations of particulate metals broadly follow the distribution of suspended particulate matter, with highest concentrations near the UK coast. Trace metal concentrations have been integrated with modelled data on fluxes of water to provide estimates of fluxes for these elements into the eastern Channel, and an initial comparison is made with data for fluxes of metals through the Strait of Dover obtained during an earlier study. A major influence on the fluxes of particulate metals through the Isle of Wight-Cherbourg transect is the gyre system to the South east to the Isle of Wight, which has important east to west as well as west to east transport components. For those elements where the dissolved form of the metal dominates, the large flow of water in the central Channel waters leads to major fluxes of the metals towards the east and the Strait of Dover. However, the high suspended particulate matter loadings in the coastal waters and impact of the gyre system lead to net east to west fluxes of particulate Al, Fe, Mn and Ti. Comparison of these fluxes with data on the net west to east transport of these materials through the Strait of Dover infers that there must be a significant supply of these particulate metals to the eastern Channel.     

Spatial and temporal factors controlling short‐term sedimentation in a salt and freshwater tidal marsh,Scheldt estuary,Belgium, SW Netherlands

During a one‐year period temporal and spatial variations in suspended sediment concentration (SSC) and deposition were studied on a salt and freshwater tidal marsh in the Scheldt estuary (Belgium, SW Netherlands) using automatic water sampling stations and sediment traps. Temporal variations were found to be controlled by tidal inundation. The initial SSC, measured above the marsh surface at the beginning of inundation events, increases linearly with inundation height at high tide. In accordance with this an exponential relationship is observed between inundation time and sedimentation rates, measured over 25 spring–neap cycles. In addition both SSC and sedimentation rates are higher during winter than during summer for the same inundation height or time. Although spatial differences in vegetation characteristics are large between and within the studied salt and freshwater marsh, they do not affect the spatial sedimentation pattern. Sedimentation rates however strongly decrease with increasing (1) surface elevation, (2) distance from the nearest creek or marsh edge and (3) distance from the marsh edge measured along the nearest creek. Based on these three morphometric parameters, the spatio‐temporal sedimentation pattern can be modelled very well using a single multiple regression model for both the salt and freshwater marsh. A method is presented to compute two‐dimensional sedimentation patterns, based on spatial implementation of this regression model. Copyright © 2003 John Wiley & Sons, Ltd.     

Palynostratigraphy of the Chapada Group and its significance in the Devonian stratigraphy of the Paraná Basin,south Brazil

The Alto Garças Sub-basin in the northern part of the Paraná Basin evolved differently from the Apucarana Sub-basin in the south. The marine environment was shallower in the Alto Garças Sub-basin, which contains proportionately more silty and arenaceous rocks. The formations and members defined in the Apucarana Sub-basin are therefore difficult to apply in the Alto Garças Sub-basin, where the Chapada Group (units 1–4) is more applicable. An integrated miospore and chitinozoan biozonation of the Chapada Group facilitates direct correlation between the Chapada Group’s units and the classical formations of the Paraná Basin as defined in the Apucarana Sub-basin. The Furnas Formation and Chapada unit 1 constitute the same lithostratigraphic unit. Beds with rhyniophytes in the uppermost part of the Furnas Formation contain palynomorphs representative of the Si phylozone within the MN spore Zone (late Lochkovian), and the rhyniophyte beds occupy the same stratigraphic interval within Chapada unit 1 (the Lochkovian of the Paraná Basin lacks chitinozoans). The lower part of Chapada unit 2 contains spores of the PoW Su spore Zone and chitinozoans of the Ramochitina magnifica and Ancyrochitina pachycerata zones, together indicating a late Pragian–early Emsian age-span. The upper part of Chapada unit 2 corresponds to the GS (AP) and Per (AD pre-Lem) spore Zones, and chitinozoans of the Ancyrochitina parisi, the informal Ancyrochitina varispinosa and Alpenachitina eisenacki chitinozoan zones, thus suggestive of a late Emsian – earliest Givetian age-span. Unit 3 is a proximal and lateral facies equivalent of the upper part of unit 2. The lower part of unit 4 includes spores typical of the early Givetian Lli (AD Lem) spore Zone and chitinozoans of the Ramochitina stiphrospinata chitinozoan Zone; the uppermost (early late Frasnian) part contains spores of the lower BMu (IV) spore Zone and chitinozoans of the Lagenochitina avelinoi chitinozoan Zone. The sandstones of unit 3 were inundated during the earliest Givetian, and the resultant flooding surface marks the base of unit 4 basin-wide. Clearly, the two sub-basins were distinct depositional centers during the Devonian.     

Soil discrimination using diffuse reflectance Vis–NIR spectroscopy in a local toposequence

Vis–NIR spectroscopy is nowadays presented as a possible routine method for soil sample analysis. However, there is still no consensus on which is the best multivariate statistical method to use. We propose to use principal component analysis to complete the spectral data treatment. The soil samples came from a pedological cover made up of red–yellow Latosols: 88 samples of 11 soil profiles on four toposequences were collected; clay, organic matter, silica, iron, aluminum and titanium total contents were determined; the contents of goethite, hematite, gibbsite, and kaolinite were calculated. Diffuse reflectance Vis–NIR spectroscopy at wavelengths from 400 to 2400 nm combined with principal component analysis (PCA) was sufficiently sensitive to discriminate different Latosols. Wavelengths of 700 nm and 2200 to 2300 nm were influenced by content ratios of organic matter and iron oxides (700 nm), and kaolinite and gibbsite absorption (2200 and 2300 nm). The spectral responses were affected not only by the content of these constituents, but also by the composition of the minerals, so that the same class of Latosol may have different or similar spectral responses. The role of microaggregation is discussed.     

Track of fluid paleocirculation in dolomite host rock at regional scale by the Anisotropy of Magnetic Susceptibility (AMS): An example from Aptian carbonates of La Florida,Northern Spain

The present study aims to apply the AMS method (Anisotropy of Magnetic Susceptibility) at a regional scale to track the fluid circulation direction that has produced an iron metasomatism within pre-existing dolomite host rock. The Urgonian formations hosting the Zn–Pb mineralizations in La Florida (Cantabria, northern Spain) have been taken as target for this purpose. Sampling was carried out, in addition to ferroan dolomite host rock enclosing the Zn–Pb mineralizations, in dolomite host rock and limestone to make the comparison possible between magnetic signals from mineralized rocks, where fluid circulation occurred, and their surrounding formations. AMS study was coupled with petrofabric analysis carried out by texture goniometry, Scanning Electron Microscopy (SEM) observations and also Shape Preferred Orientation (SPO) statistics. SEM observations of ferroan dolomite host rock illustrate both bright and dark grey ribbons corresponding respectively to Fe enriched and pure dolomites. SPO statistics applied on four images from ferroan dolomite host rock give a well-defined orientation of ribbons related to the intermediate axis of magnetic susceptibility K₂. For AMS data, two magnetic fabrics are observed. The first one is observed in ferroan dolomite host rock and characterized by a prolate ellipsoid of magnetic susceptibility with a vertical magnetic lineation. The magnetic susceptibility carrier is Fe-rich dolomite. These features are probably acquired during metasomatic fluid circulations. In Fe-rich dolomite host rock, ?c? axes are vertical. As a rule, (0001) planes (i.e. planes perpendicular to ?c? axes) are isotropic with respect to crystallographic properties. So, the magnetic anisotropy measured in this plane should reflect crystallographic modification due to fluid circulation. This is confirmed by the texture observed using the SEM. Consequently, AMS results show a dominant NE–SW elongation interpreted as the global circulation direction and a NW–SE secondary elongation that we have considered as sinuosities of the fluid trajectory. The second type of magnetic fabric is essentially observed in the limestone and characterized by an oblate form of the ellipsoid of magnetic susceptibility, a horizontal magnetic foliation and mixed magnetic susceptibility carriers. It is interpreted as a sedimentary fabric.     

Seasonal dynamics of trophic relationships among co-occurring suspension-feeders in two shellfish culture dominated ecosystems

The temporal dynamics of carbon and nitrogen isotope values of co-occurring suspension-feeders in two shellfish culture areas (Normandy, France) were investigated over two years to evaluate the inter-specific trophic partitioning and relative contributions of organic matter sources to benthic suspension-feeders' diet. Oysters (Crassostrea gigas), mussels (Mytilus edulis), cockles (Cerastoderma edule), slipper limpets (Crepidula fornicata), and sand-mason worms (Lanice conchilega) were sampled in an estuarine environment (Baie des Veys, east Cotentin, Normandy), while oysters, mussels, slipper limpets, and honeycomb worms (Sabellaria alveolata) were sampled in an open-marine environment (Lingreville-sur-mer, west Cotentin, Normandy). Whatever the sampling period, the bivalves, C. gigas and M. edulis, exhibited the lowest values of δ¹³C and δ¹⁵N compared with the other species. Feeding relationships among suspension-feeders in both C. gigas culture areas exhibited temporal variations due to the marine/estuarine influence and seasonal changes in food supply. In the open-marine ecosystem, the contribution of phytoplankton remained the most important for all species except S. alveolata, while in the estuarine ecosystem, microphytobenthos and/or macroalgae detritus contributed a larger extent to the organisms' diets. During phytoplankton bloom periods (e.g. May and July) suspension-feeders, except for S. alveolata, relied strongly on phytoplankton; however, the majority of suspension-feeders exhibited different opportunistic behaviour in winter when phytoplankton biomass might be a limiting factor. We hypothesized that differences in particle capture and selection by the suspension-feeders influenced their isotopic values. Feeding ecology of suspension-feeders partly explained why competition was limited and why ecosystems can often support unexpectedly large numbers of suspension-feeders. We also showed that understanding ecosystem characteristics of the organic matter sources is of primary importance to determine the extent to which members of the suspension-feeding guild potentially compete for food.     

Fluxes and seasonal changes in composition of organic matter in the English Channel

Dissolved and particulate organic matter (DOM and POM) have been investigated along a transect between Cherbourg and the Isle of Wight. In addition, the relative contribution of different sources of POM have been assessed by the use of lipid biomarkers (e.g. fatty acids). Seawater samples were collected at two depths (subsurface and above the bottom) at five stations located on the transect during five cruises (from September 1994 to July 1995). Particulate organic carbon (POC) and dissolved organic carbon (DOC) concentrations vary between 30–530 μg l⁻¹ and 0.5–2.7 mg l⁻¹, respectively, for all the cruises. Fluxes of POM and DOM have been estimated at 0.6×10¹² g yr⁻¹ and 6.5×10¹² g yr⁻¹ of carbon, respectively. General fluxes of water and therefore of DOC and POC are oriented eastward. However, around the Isle of Wight a westward oriented flux exists due to a gyre located in the area. The major DOC and POC fluxes occur in the central part of the Channel where the water column is deepest. Seasonal variations of different sources of POM (algal, bacterial and terrigenous) have been examined for the five cruises. The fresh algal organic fraction is relatively important in September in coastal waters with a predominance of diatom species on the English side, whereas it has a low or undetectable contribution during winter months. The bacterial fraction generally varies in concert with the algal component. It is low during the winter period and more important in bloom or post-bloom conditions, as for example in May. Terrestrial organic matter is restricted to coastal areas in September, and is present at low levels in May and July. Nevertheless, in November and February, terrigenous inputs have been clearly identified for the whole transect even in central waters.