Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: Isotopic (C,O) study of the Khushaym Matruk natural analogue (central Jordan)

The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ¹³C-values down to −31.4‰/PDB show the contribution of CO₂ derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO₂ in the near field.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.     

On non-adiabatic oscillations of gaseous systems in hydromagnetics

The general variational principle obtained by Unno for the study of stellar stability is extended to include the effects of magnetic fields in the general case where the perturbations are nonadiabatic. The unperturbed configuration is non-rotating, but internal motions are possible.A general stability equation is derived, using the modified variational principle. In the simplest case, this equation is identical to the one derived by Unno except for the appearance of magnetic terms in one of the coefficients (through the Lorentz force). If dissipation is neglected, the characteristic equation reduces to the one derived by Frieman and Rotenberg in the stationary case and by Kovetz in the static case.The stability of magnetic stars against homologous oscillations is examined and the usual result for the dynamical mode is obtained.     

Influence of injection conditions on field tracer experiments

Calibration of ground water transport models is often performed using results of field tracer experiments. However, little attention is usually paid to the influence, on resulting breakthrough curves, of injection conditions and well-aquifer interactions, more particularly of the influence of the possible trapping of the tracer in the injection wellbore. Recently, a new mathematical and numerical approach has been developed to model injection conditions and well-aquifer interactions in a very accurate way. Using an analytical solution derived from this model, a detailed analysis is made of the evolution of the tracer input function in the aquifer. By varying injection conditions from one simulation to another, synthetic breakthrough curves are generated with the SUFT3D ground water flow and transport finite-element simulator. These tests show clearly that the shape of the breakthrough curves can be dramatically affected by injection conditions. Using generated breakthrough curves as "actual" field results, a calibration of hydrodispersive parameters is performed, neglecting the influence of injection conditions. This shows that neglecting the influence of actual injection conditions can lead to (1) errors on fitted parameters and (2) misleading identification of the active transport processes. Conclusions and guidelines are drawn in terms of proposed methodologies for better controlling the tracer injection in the field, in order to minimize risk of misinterpretation of results.     

A fast flux tube-based method for solute-transport simulation

A new method to calculate the transport of dissolved species in aquifers is presented. This approach is an extension of the stream tubes which are used for flow computation. The flux tubes defined here are conservative for solutes, but not for water mass. The flux tubes are first defined in a general domain and then calculated in a two-dimensional uniform flow field. The tubes?? computation is based on a parametric solution. The method is extended further in order to deal with heterogeneous media. A particle-tracking algorithm is used where the deviation of the flux-tube boundaries due to dispersion is accounted for. The approximate solution obtained by this approach is compared to classical numerical solutions given by a finite difference code (RT3D) and a finite element code (FEFLOW). This comparison was performed for several test cases with increasing complexity. The differences between the flux-tube approach and the other methods always remain small, even regarding mass conservation. The major advantage of the flux-tube approach is the ability to reach a solution quickly, as the method is hundreds to thousands of times faster than classical finite difference or finite element models.     

冲绳海槽中部距今近70ka以来的孢粉记录及物源探讨

研究钻孔DGKS-9602位于冲绳海槽中部,岩芯长度为931 cm,钻孔年代覆盖了氧同位素1～4阶段,年代可追溯至距今73 ka.孢粉分析结果证明,孢粉带与氧同位素阶段有较好的对应关系,其中松属花粉与蒿属花粉比值(P/A)与海平面变化曲线相互吻合.应用非相似性类比法将钻孔孢粉样品与陆地表土孢粉样品进行欧氏距离计算,从而...     

Review of the causes of the rise of the illegal South African abalone fishery and consequent closure of the rights-based fishery

The rise of organised illegal fishing and trade in abalone from the late 1990s destabilised South Africa’s historically stable, quota-managed fishery, culminating in its closure in 2008. The development of the fishery is described in a historical context, including the evolution of South Africa’s science-based abalone fishery management system. The diverse suite of responses deployed to combat illegal fishing and the black market trade in abalone are reviewed, including;- fishery reform to expand rights to a greater number of previously disadvantaged fishers, a territorial user rights fishery (TURF) system, special compliance operations and courts, the CITES listing of abalone, and the serial reduction in the TAC, culminating in the controversial and legally contested closure of the fishery. The main causes of the rise of the illegal fishery are diagnosed as 1) the massive increase in the abalone price that occurred in the 1990s triggering an abalone fishing “gold-rush” and 2) the failure of the post-Apartheid fishery reform process to accommodate many traditional fishers in a legal fishing rights framework resulting in them operating outside the formal fishery management system. By contextualising the abalone fishery as a complex system, embedded in South Africa’s socio-political setting, we show how the resource focussed fishery management system did not have the capacity to incorporate the powerful social, political and economic drivers determining fisher behaviour. We conclude with the need to revisit South Africa’s abalone fishery management paradigm, and argue that a more integrated governance approach is required that takes into account the biological, socio-political and economic factors determining the fishery activities.     

Differential regional responses in drought length, intensity and timing to recent climate changes in a Mediterranean forested ecosystem

The Mediterranean area is one of the regions of the world where GCMs agree the most on precipitation changes due to climate change. In this study we aim to assess the impact of recent climate change on drought features of Mediterranean ecosystems in Southern France. Regional climatic trends for the 1971–2006 period are compared to drought trends based on a water balance model accounting for soil properties, vegetation structure and functioning. Drought, defined here as periods when soil water potentials drop below ??0.5 MPa, is described in terms of intensity, duration and timing, which are integrative of both climate variability and site conditions. Temporal trends in precipitation, temperature and solar radiation lead altogether to drier and warmer conditions over the region but with a high spatial heterogeneity; for similar climatic trends, a significant increase in drought intensity was detected in the wettest areas of the region, whereas drought intensity in the driest areas did not change. Indeed, in the wettest areas, we observed an earlier onset of drought by about 1 month, but a constant end of drought. In the driest areas of the region, we observed the same earlier onset of drought but combined with an earlier end of drought, thus leading to a shift of the dry season without increasing its duration. The definition of drought features both in terms of intensity but also of seasonal timing appears relevant to capture historical or forecasted changes in ecosystem functioning. Studies concerning climate change impacts on forested ecosystems should be interpreted with caution when using climate proxies alone.     

Une methode d'etude experimentale “in situ” de la zone d'echange entre les nuages convectifs et leur environnement

Le développement d'un projet de recherche consacré à l'étude des nuages convectifs a amené les auteurs à concevoir et à élaborer un système complet de mesures adapté à cette étude. Les grandeurs thermodynamiques classiques (Température, Pression, Humidité) ainsi que les vitesses d'ascendance autour et à l'intérieur des nuages sont mesurées grâce à l'utilisation d'un avion Cessna 206 équipé de ce système. Une première étape consiste à mettre en évidence les phénomènes relatifs aux échanges entre le nuage et le milieu environnant.