Isoprenoid alkanes with irregular “head-to-head” linkages

A lightly biodegraded crude oil from the Tolkinsk field (Upper Jurassic), situated in north-west Siberia, was found to contain a series of C₂₈–C₃₉ isoprenoid alkanes. Most of these components contain a pristane unit linked head-to-head with other isoprenoid units. The structures of these components were elucidated by mass spectral interpretations, comparisons with a synthesised standard and by reference to data published previously in the literature. These results extend the carbon number range, the variety of structural types, and the number of reported occurrences of these compounds in geological samples. These results provide further evidence for a contribution of bacterial cell-wall lipids to crude oils.     

On the mathematical modelling of the spectral structure of geomagneticPC1 pulsations via the response of Alfvén's ionospheric resonator

Summary A method of numerical simulation of the coefficient of reflection of the ionospheric transition layer as a function of frequency is applied to the experimental data related to several series of pearl-type pulsations Pc1 (f = 0.2 – 2 Hz) recorded at the observatories of Kerguelen, Sogra and Nurmijarvi. The inverse problem of modelling, i.e. determining the vertical profiles of ionospheric electron concentration corresponding to the actual experimental situations, was solved approximately. The initial assumption for interpreting the specific nature of the series of Pc1 micropulsations parallel in time was their resonance origin under reflection of the signal at magnetically conjugate ionospheres, Alfvén's resonators, in both of the Earth's hemispheres.     

Sr, C and O isotope systematics in the Pucará basin, central Peru

A combined Sr, O and C isotope study has been carried out in the Pucará basin, central Peru, to compare local isotopic trends of the San Vicente and Shalipayco Zn-Pb Mississippi Valley-type (MVT) deposits with regional geochemical patterns of the sedimentary host basin. Gypsum, limestone and regional replacement dolomite yield ⁸⁷Sr/⁸⁶Sr ratios that fall within or slightly below the published range of seawater ⁸⁷Sr/⁸⁶Sr values for the Lower Jurassic and the Upper Triassic. Our data indicate that the Sr isotopic composition of seawater between the Hettangian and the Toarcian may extend to lower ⁸⁷Sr/⁸⁶Sr ratios than previously published values. An ⁸⁷Sr-enrichment is noted in (1) carbonate rocks from the lowermost part of the Pucará basin, and (2) different carbonate generations at the MVT deposits. This indicates that host rocks at MVT deposits and in the lower-most part of the carbonate sequence interacted with ⁸⁷Srenriched fluids. The fluids acquired their radiogenic nature by interaction with lithologies underlying the carbonate rocks of the Pucará basin. The San Ramón granite, similar Permo-Triassic intrusions and their clastic derivatives in the Mitu Group are likely sources of radiogenic ⁸⁷Sr. The Brazilian shield and its erosion products are an additional potential source of radiogenic ⁸⁷Sr. Volcanic rocks of the Mitu Group are not a significant source for radiogenic ⁸⁷Sr; however, molasse-type sedimentary rocks and volcaniclastic rocks cannot be ruled out as a possible source of radiogenic ⁸⁷Sr. The marked enrichment in ⁸⁷Sr of carbonates toward the lower part of the Pucará Group is accompanied by only a slight decrease in ¹⁸O values and essentially no change in ¹³C values, whereas replacement dolomite and sparry carbonates at the MVT deposits display a coherent trend of progressive ⁸⁷Sr-enrichment, and ¹⁸O- and ¹³C-depletion. The depletion in ¹⁸O in carbonates from the MVT deposits are likely related to a temperature increase, possibly coupled with a ¹⁸O-enrichment of the ore-forming fluids. Progressively lower ¹³C values throughout the paragenetic sequence at the MVT deposits are interpreted as a gradually more important contribution from organically derived carbon. Quantitative calculations show that a single fluid-rock interaction model satisfactorily reproduces the marked ⁸⁷Sr-enrichment and the slight decrease in ¹⁸O values in carbonate rocks from the lower part of the Pucará Group. By contrast, the isotopic covariation trends of the MVT deposits are better reproduced by a model combining fluid mixing and fluid-rock interaction. The modelled ore-bearing fluids have a range of compositions between a hot, saline, radiogenic brine that had interacted with lithologies underlying the Pucará sequence and cooler, dilute brines possibly representing local fluids within the Pucará sequence. The composition of the local fluids varies according to the nature of the lithologies present in the neighborhood of the different MVT deposits. The proportion of the radiogenic fluid in the modelled fluid mixtures interacting with the carbonate host rocks at the MVT deposits decreases as one moves up in the stratigraphic sequence of the Pucará Group.     

Spiral filaments — The signature of singular points in a large delta spot

A large delta spot (active region NOAA 6891, October 23 – November 4, 1991) is analysed, and it is found that some spiral filaments across the spot can be regarded as signatures of a singular point entity (SPE) which lies near a separator of this complicated magnetic field region. Near such an entity, 86% of the flares in the region were produced, including two white-light flares, one of which, being the largest flare of the region, was accompanied by a powerful mass ejection. In an island delta spot, a SPE could be recognized very close to the usual U-shaped inversion lines. Together with the other characteristics (bright H emission, highly sheared magnetic field, umbra obscured by H, magnetic flux imbalance in the range 21–31), the SPE can help us to predict effectively the sites for great flares to occur (Zirin and Liggett, 1987).On leaving from Purple Mountain Observatory, Nanjing, China.     

Uranus and Neptune interior models

This paper is concerned with the interior structure of Uranus and Neptune. Our approach is three-fold. First, a set of three-layer models for both Uranus and Neptune are constructed using a method similar to that used in the study of the terrestrial planets. The variations of the mass density (s) and flattening e(s) with fractional mean radius s for two representative models of Uranus and Neptune are calculated. The results are tabulated. A comparison of these models shows that these two planets are probably very similar to each other in their basic dynamical features. Such similarity is very seldom seen in our solar system. Secondly, we check the conformance between the theoretical results and observational data for the two planets. And thirdly, the 6th degree Stokes zonal parameters for Uranus and for Neptune are predicted, based on the interior models put forward in this paper.     

Analysis of the Marshall Islands Fireball of February 1, 1994

On February 1, 1994, a large meteoroid impacted over the Pacific Ocean at 2.6° N, 164.1° E. The impact was observed by space based IR sensors operated by the US Department of Defense and by visible wavelength sensors operated by the US Department of Energy. During entry the object broke into several pieces, one of which detonated at 34 km and another at 21 km altitude. The entry velocity of the object is estimated to be 24–25 km/sec. Based on the visible wavelength data, the integrated intensity of the radiated energy of the fireball was approximately 1.3 × 10¹³ joules. Assuming a 6000 K black body and a 30% efficiency for the conversion of the kinetic energy of the body into visible light, we estimate the mass of the body to be between 1.6×10⁵ kg and 4.4×10⁶ kg, and to have a diameter of between 4.4 and 13.5 meters. The object entered at a 45° angle, traveling on a heading of approximately 300°, i.e. from the southeast to the northwest. Calculations using a gross-fragmentation model indicate that the body was most likely a stony object larger than 10 m with an Apollo orbit prior to impact.E T Space SystemsSandia National LaboratoriesOndejov Observatory     

Physical conditions in the compact double star HD 187399

We present the results of a study of the spectra of the compact double system HD 187399. We have measured and identified lines in the spectrum of the main star and computed their equivalent widths, the central residual intensities, and the electron densities in the atmosphere of the main star and the common envelope of the system. We have constructed the curve of radial velocities of the main star and determined the expansion velocity of the common envelope of the system: v_r =90 km/sec. We have measured the velocity of the interstellar calcium: v_r =–3.5 km/sec. We have established the agreement of the radial velocity curves for the main star obtained in the present paper and in that of Merrill [1]. The comparison enabled us to make the following conjecture: there has been no noticeable loss of mass in the system HD 187399 over the past 35 years, and possibly all that has occurred is a flow of matter from one component toward the other. We note the strong similarity with the Lyrae system.Translated fromAstrofizika, Vol. 38, No. 2, 1995.     

Close Binary System Go Cygnus: Standard Ubv Observations and Light Curve Analysis

Standard UBV light curves of eclipsing binary star GO CYGNUS havebeen presented. These light curves indicate a Lyrae typevariations with circular orbit. The Light curve analysis have beencarried out on three colours U, B and V. The results obtained fromthese analysis represent an occultation solution with r r =1.24.     

The spa Deutsch-Altenburg and the hydrogeology of the Vienna basin (Austria)

 Some years ago the thermal water wells of the spa Deutsch-Altenburg were considered the result of a local water circulation. Extensive measurements of the water chemistry, trace elements, and environmental isotopes combined with drillings in the river bed of the Danube resulted in the indication of a key position of the mineral thermal wells of Deutsch-Altenburg for the groundwater circulation in the entire Vienna basin. The proof of this fact demanded the inclusion of the complicated geological position of the basin into the argumentation. The historical background of Bad Deutsch-Altenburg is the Roman municipium Carnuntum. During the reign of the Roman emperor Marc Aurel (161-180 A.C.) Carnuntum became the largest Roman municipium northeast of Rome with about 50 000 inhabitants covering the areas of present-day villages Petronell and Deutsch-Altenburg due to its strategic and trade position. The town was totally destroyed during the era of "migration of nations." The land surface was farmland or meadows. The first document concerning the thermal water of Deutsch-Altenburg is an expertise of the medical faculty of the University of Vienna (1548). During the siege of Vienna by the Turkish army under Kara Mustafa (1683–84) Deutsch-Altenburg was again, destroyed. It was only at the end of the 19th century that the modern installation of the spa began. The healing thermal water with the highest content of sulfur in Austria made Deutsch-Altenburg one of the most well-known spas in the country. The archaeological excavation of Carnuntum is the largest in Austria. Received: 6 October 1995 · Accepted: 13 November 1995     

New data about structure and time of formation of the Khamar-Daban terrane: U-Pb LA-ICP-MS zircon ages

This paper provides new data on the age of detrital zircons from metaterrigenous rocks of the Khamardaban Group (Kornilovskaya and Shubutuiskaya formations) which crown the succession of the Khamar-Daban terrain. It was established that the accumulation of the protoliths of both formations occurred in the interval between the Late Riphean and Early Ordovician. In this case, there is a difference between sequences of Shubutuiskaya and Kornilovskaya formations due to a sharp change in a provenance area and depositional conditions, which is a consequence of the change in the paleogeodynamic environment. In addition, this indicates the tectonic juxtaposition of these sequences and probability of accumulation of deposits of the Shubutuiskaya Formation within Dzhida island arc system.