Geomechanics of hazardous landslides

A catalogue of possible landslide initial failure mechanisms, taking into account the geological setting and the geometry of the slope, the joint structure, the habitus of the rock blocks, as well as the mechanical behaviour of the rocks and of the rock mass （deformation and strength parameters）, is presented. Its aim is to give geologists as well as engineers the opportunity to compare phenomena in the field and phenomena belonging to particular mechanisms and to find the mechanism occurring. The presented catalogue of initial landslide mechanisms only comprises the mechanisms having a clearly defined mechanical model that can be divided into empirical relations and into mechanical models, as well as an overview of run out models, which can be divided into empirical relations and into mechanical models.     

GPCC's new land surface precipitation climatology based on quality-controlled in situ data and its role in quantifying the global water cycle

In 1989, the need for reliable gridded land surface precipitation data sets, in view of the large uncertainties in the assessment of the global energy and water cycle, has led to the establishment of the Global Precipitation Climatology Centre (GPCC) at Deutscher Wetterdienst on invitation of the WMO. The GPCC has calculated a precipitation climatology for the global land areas for the target period 1951–2000 by objective analysis of climatological normals of about 67,200 rain gauge stations from its data base. GPCC's new precipitation climatology is compared to several other station-based precipitation climatologies as well as to precipitation climatologies derived from the GPCP V2.2 data set and from ECMWF's model reanalyses ERA-40 and ERA-Interim. Finally, how GPCC's best estimate for terrestrial mean precipitation derived from the precipitation climatology of 786 mm per year (equivalent to a water transport of 117,000 km³) is fitting into the global water cycle context is discussed.     

iTRAQ-based proteomic profiling of the marine medaka (Oryzias melastigma) gonad exposed to BDE-47

A recent study demonstrated that 2,2′,4,4′-tetrabromodiphenyl ether (BDE-47) may have an adverse effect on the reproduction in marine medaka (Oryzias melastigma), but the molecular mechanisms remain largely unknown. In this study, we investigated the protein expression profiles of male and female gonads of O. melastigma exposed to dietary BDE-47 at two dosages (0.65 and 1.30 μg/g/day, respectively) for 21 days. Extracted proteins were labeled with iTRAQ and analyzed on a MALDI TOF/TOF analyzer, as results, 133 and 144 unique proteins were identified in testis and ovary, respective, and they exerted dose- and sex-dependent expression patterns. In testis, among the 42 differentially expressed proteins; down-regulation of histone variants and parvalbumins implicated BDE-47 may disrupt the spermatogenesis and induce sterility in fishes. In ovary, 38 proteins were differentially expressed; the elevation of vitellogenins and apolipoprotein A–I expression indicated BDE-47 acts as an estrogen-mimicking compound and led to reproductive impairment in O. melastigma.     

Prevalence and diversity of norovirus genogroups I and II in Hong Kong marine waters and detection by real-time PCR

Marine waters from six sites around Hong Kong with varying levels of sewage pollution were examined for noroviruses (NoVs) by PCR cloning and sequencing of a highly-variable N-terminal region of the VP1 capsid gene, at the ORF1-ORF2 junction of NoV. Phylogenetic analysis of genogroups GI- and GII-specific PCR clones obtained from different marine sites indicated that human NoV GI.1 and GII.4 strains are the most prevalent genotypes circulating in Hong Kong waters. GI- and GII-specific TaqMan-based real-time PCR assays targeting the ORF1-ORF2 junction of NoVs were used to quantify NoV particles in marine water samples in parallel with total Escherichia coli counts which were enumerated on TBX medium. No correlation of any significance between NoV and E. coli counts was observed which highlighted the inadequacy in using E. coli as a fecal indicator to predict the level of NoVs in marine waters to protect public health.     

Biomarker-based paleo-record of environmental change for an eutrophic,tropical freshwater lake,Lake Valencia,Venezuela

The lipids in a sediment core from Lake Valencia, a hypereutrophic freshwater lake in Venezuela, are examined to understand environmental changes over the last ∼13,000 years. From the latest Pleistocene to the earliest Holocene, total organic carbon (TOC) substantially increased from 2.2 to 10%, while total organic carbon over total nitrogen (TOC/TN) decreased from as high as 34 to as low as 10. Correspondingly, the concentration of terrestrially derived triterpenoids markedly decreased, and the dominant n-alkane shifted from C₃₁ to C₂₃ or C₂₅. During the same period, algal biomarkers such as botryococcenes, dinosterol, isoarborinol, C₂₀ HBIs and 1,15C₃₂ keto-ol markedly increased in abundance. These changes suggested a greater contribution of algal organic matter at the onset of the Holocene, which was concurrent with increasing rainfall and the formation of a permanent lake (Lake Valencia) in the Aragua Valley, Venezuela. The age profile of Paq, a n-alkane based proxy, showed large oscillations (0.20–0.81), reflecting historical variations in source strength of submerged/floating vs. terrestrial/emergent OM inputs. An abrupt increase in tetrahymanol abundance at ∼7,260 cal years BP suggests the establishment of an oxic–anoxic boundary in the lake’s water column. After reaching its maximum abundance at ∼2,100 cal year BP, botryococcenes, a biomarker of Botryococcus braunii, gradually decreased to below the detection limit in the uppermost sediments, while different algal/microbial biomarkers such as diploptene, dinosterol and isoarborinol substantially increased. These different historical profiles of algal/microbial biomarkers reflect different responses of source organisms to environmental changes throughout this period. The δ¹³C determinations presented exceptionally enriched values for botryococcene isomers (−7.7 to −15.1‰), indicating the utilization of bicarbonate as carbon sources in an extremely productive ecosystem.     

Subglacial emplacement of tills and meltwater deposits at the base of overdeepened bedrock troughs

The sedimentary infills of subglacially eroded bedrock troughs in the Alps are underexplored archives for the timing, extent and character of Pleistocene glaciations but may contain excellent records of the Quaternary landscape evolution over several glacial–interglacial cycles. The onset of sedimentation in these bedrock troughs is often reflected by diamicts and gravels directly overlying bedrock in the deepest basin segments. Subglacial or proglacial depositional environments have been proposed for these coarse‐grained basal units but their characteristics and origin remain controversial. This article presents results from drill cores that recovered a coarse‐grained basal unit in a major buried bedrock‐trough system in the Lower Glatt Valley, northern Switzerland. The excellent core recovery allowed a detailed study combining macroscopic, microscopic and geochemical methods and gives unprecedented insights into the transition from erosion to deposition in overdeepened bedrock troughs. These results show that the basal infill comprises diamicts, interpreted as subglacial tills, separated by thin sorted interbeds, originating from subglacial cavity deposition. The stacking of these units is interpreted to represent repeated switching between a coupled and decoupled ice–bed‐interface indicating an ever‐transforming mosaic of subglacial bed conditions. Decoupling in response to high basal water pressures is probably promoted by the confined subglacial hydraulic conditions resulting from the bedrock acting as aquitards, the narrow reverse sloping outlet and a large catchment area. While stratigraphic and lithological evidence suggests that erosion and the onset of basal sedimentation occurred during the same glaciation, different scenarios for the relative timing of infilling in relation to formation and glaciation of the bedrock trough are discussed. Overlying deltaic and glaciolacustrine sediments suggest deposition during subsequent deglaciation of the bedrock trough. The basal sediment characteristics are in agreement with previous reports in hydrogeological and seismic exploration and suggest the occurrence of similar basal successions in other subglacially overdeepened basins in the Alps and elsewhere.     

Five new E′ centers and their 29Si hyperfine structures in electron-irradiated α-quartz

Single-crystal electron paramagnetic resonance (EPR) spectra of fast-electron-irradiated quartz, after annealing at 120 and 200°C, reveal five new E′ type centers, herein labeled E ₅^￠ , E ₆^￠ , E ₇^￠ , E ₈^￠ , \textand E ₉^￠ E_{ 5}^{\prime } ,\,E_{ 6}^{\prime } ,\,E_{ 7}^{\prime } ,\,E_{ 8}^{\prime } ,\,{\text{and}}\,E_{ 9}^{\prime } . Centers E ₅^￠ , E ₇^￠ , \textand E ₉^￠ E_{ 5}^{\prime } ,\,E_{ 7}^{\prime } ,\,{\text{and}}\,E_{ 9}^{\prime } are characterized by the orientations of the unique principal g and A(²⁹Si) axes close to a short Si–O bond direction, hence representing new variants of the well-established E ₁^￠ E_{ 1}^{\prime } center. Centers E ₆^￠ E_{ 6}^{\prime } and E ₈^￠ E_{ 8}^{\prime } have the orientations of the unique principal g and A(²⁹Si) axes approximately along a long Si–O bond direction, similar to the E ₂^￠ E_{ 2}^{\prime } centers. Therefore, these new E′ type centers apparently arise from the removal of different oxygen atoms and represent variable local distortions around the oxygen vacancies.     

Major human Hepatitis A virus genotype in Hong Kong marine waters and detection by real-time PCR

Marine waters from seven sites around Hong Kong with varying levels of sewage pollution were analyzed for Hepatitis A virus (HAV) by PCR cloning and DNA sequencing of the highly variable VP1/2A junction of the HAV genome. Phylogenetic analysis of 10 PCR clones from each of the HAV-positive marine sites indicated that human HAV genotype IB is the most widely distributed type in Hong Kong waters. A sensitive and quantitative TaqMan-based PCR method targeting the 5′-noncoding region (5′-NCR) of HAV was used to quantify HAV particles in marine water samples along with the total Escherichiacoli counts being enumerated on TBX medium for comparison. Our results showed that no correlation of any significance between HAV and E. coli counts was observed which underscores the inadequacy in using E. coli as a sanitary standard to predict the levels of HAV in marine waters.