Vertical distribution of suspended sediment concentrations seawards of the breaking zone

On the basis of the current concepts on the wave flow structure and solid particle motion in turbulent flow, an equation was derived which enables the suspended sediment concentration profile to be computed from known wave parameters. The equation was verified by laboratory and full-scale experiments which proved that it can be implemented for practical computations of the concentration profile seawards of the breaking zone. The formula yields the best results when operating on wave characteristics corresponding to maximum spectral density.     

Internal consistency of a water analysis and uncertainty of the calculated distribution of aqueous species at 25°C

Many water analyses contain more than the minimum number of analytical determinations needed to calculate the distribution of species at ~ 25°C. The speciation of a water that contains $\text{n}$ cations and ligands other than H⁺ and OH^? can be calculated if just $\text{n}$ analytical determinations are available. In the frequent case where $\text{n + 1}$ (or more) determinations are available, one can calculate from the speciation a value for the ($\text{n + 1}$)th variable. The comparison between this computed value and its analytical counterpart (not used in calculating the speciation) constitutes a test for internal consistency among the $\text{n + 1}$ determinations that make up the whole analysis.Application of this test requires knowing the uncertainties of the calculated speciation and of the value computed for the ($\text{n + 1}$)th variable from the speciation. Such uncertainties have been ignored in previous algorithms, but have been determined herein by a Monte Carlo method of error propagation which is very well suited to systems of nonlinear algebraic equations.By comparing the titration alkalinity against the alkalinity calculated from the speciation, several published analyses for which the cation/anion balance is < 3% can be shown to be internally inconsistent. Such analyses may be unsuitable for geochemical calculations (water/rock interaction, estimation of reservoir temperatures, etc.).Several existing speciation algorithms disregard the possibility that the analytical data used as input are internally inconsistent.     

Temporal development of fabric in uniaxially stressed polycrystalline media—A theory

We present a kinetic theory for the development of lattice-preferred orientation in a uniaxiallystressed aggregate consisting of elastically uniaxial crystals. The fabric is brought about by grain-boundary migration alone; other fabric-producing mechanisms, such as plastic deformation, syntectonic recrystallization, and dissolution/reprecipitation, are specifically excluded from the theory. The formulation statistically averages the mass transfer between a typical crystal and its adjacent neighbors over all the possible crystallographic orientations of these neighbors and over all the possible orientations of the interfaces between the neighbors and the crystal of interest. The rate of mass exchange between two adjacent crystals is proportional (1) to the difference between chemical potentials and (2) to the surface area common to them. With these assumptions we find an equation for the massfraction density of crystals that have a given orientation (with respect to the stress) at any given time. The theory predicts that beyond a certain time a gap develops in the distribution of crystal orientations allowed: the only crystals that continue to exist are those for which the c-axis is within a certain, timedependent range about the stress.     

Solubility of Fe-ettringite (Ca6[Fe(OH)6]2(SO4)3 · 26H2O)

The solubility of Fe-ettringite (Ca₆[Fe(OH)₆]₂(SO₄)₃ · 26H₂O) was measured in a series of precipitation and dissolution experiments at 20 °C and at pH-values between 11.0 and 14.0 using synthesised material. A time-series study showed that equilibrium was reached within 180 days of ageing. After equilibrating, the solid phases were analysed by XRD and TGA while the aqueous solutions were analysed by ICP-OES (calcium, sulphur) and ICP-MS (iron). Fe-ettringite was found to be stable up to pH 13.0. At higher pH-values Fe-monosulphate (Ca₄[Fe(OH)₆]₂(SO₄) · 6H₂O) and Fe-monocarbonate (Ca₄[Fe(OH)₆]₂(CO₃) · 6H₂O) are formed. The solubilities of these hydrates at 25 °C are:      

Facies,geometry and growth phases of the Valdorria carbonate platform (Pennsylvanian,northern Spain)

The 14 km wide Valdorria outcrop (Pennsylvanian, northern Spain) is one of the few examples of entirely exposed flat‐topped and high‐relief carbonate platforms reported in the fossil rock record. Laterally and vertically traceable stratal patterns expose three phases of growth. Phase I is a 430 m thick platform to slope succession that prograded over 6 km, and is dated as Early Bashkirian (Akavasian–Askynbashian). Phase II aggraded and prograded, exhibiting 180 m thickness of cyclical platform top deposits, dated as Late Bashkirian (Asatauian). Phase III is a mound‐shape structure that developed over the platform top of Phase II as a new phase of platform nucleation. It is 535 m thick and 2 km wide, and dated as Late Bashkirian (Asatauian–Transition interval). The observed changes of growth styles during platform evolution, from a prograding to an aggrading–prograding system, and a rapid aggradational phase, are inferred to be controlled by flexural subsidence in the active Cantabrian foreland basin, at the Variscan orogenic front. The metre‐scale shallowing‐upward cycles of the platform top are most probably due to glacioeustasy, as evidenced by well‐recorded subaerial exposure surfaces superimposed on subtidal deposits, and by a stratal pattern recurrent in a short interval of about 160 kyr. Observations of outcropping Bashkirian cyclothems in an isolated carbonate system, devoid of siliciclastic input, are relevant for a better understanding of the impact of high‐frequency sea‐level fluctuations on the carbonate factory. Moreover, progradation of the platform margin during Phase I reaches a rate of 2500 m/Myr, and 1810 m/Myr during Phase II; rates that are high when compared to other Pennsylvanian examples. The aggradation rate of 447 m/Myr calculated for the Late Bashkirian–Transition interval (Phases II and III; uncorrected for compaction, missing beats and erosion) is uncommonly high in comparison to coeval Pennsylvanian examples. The platform exhibits a self‐nourishing prograding microbial boundstone‐dominated slope. Thus, the slope‐shedding model applies well to Valdorria. However, Phase II recorded eustatic variations able to inhibit the slope microbial boundstone factory during low sea‐level stands; this is marked by common slope red‐stained breccias synchronous to platform top subaerial exposure phases. Contrarily, periods of relative high sea‐level and rapid subsidence in Phase III registered a greater development of cemented microbial boundstone. These observed, partly opposing relationships of sea‐level stands, shedding modes and slope architecture provide an improvement of the currently used slope‐shedding model. The overall architecture of the Valdorria outcrop compares well with that of other contemporaneous platforms, such as Sierra del Cuera and Bolshoi Karatau. Valdorria shares the high‐relief and flat‐topped, steep slopes, cyclothemic patterns and occurrence of karst features with the Pricaspian Basin platforms (Tengiz, Karachaganak and Kashagan), with minor variations in facies distribution of the internal platform. Furthermore, the continuous seismic‐scale outcrop of Valdorria, together with its isolated setting and asymmetrical growth, makes it a very good candidate for potential subsurface analogues of hydrocarbon‐bearing systems.     

Primary production, plant and detrital biomass, and particle transport in the Columbia River Estuary

The dynamics of primary production and particulate detritus cycling in the Columbia River Estuary are described, with particular reference to mechanisms that account for patterns within the water column, on the tidal flats, and in the adjacent wetlands. Analysis of patterns in phytoplankton flora and biomass and in distribution of detrital particulate organic matter (DPOC) in the water column indicated that salinities of 1–5 delineated an essentially freshwater flora from a marine or euryhaline flora, and that living phytoplankton was converted to DPOC at the freshwater-brackishwater interface. Similarly, the benthic diatom assemblages on tidal flats reflected either the fresh or the brackish nature of the water inundating the flats. Emergent vascular plants were grouped into six associations by cluster analysis, the associations being separated mainly on the bases of different relative abundances of freshwater, euryhaline or brackishwater species, and on whether samples occurred in high or low marsh areas.Annual rates of net areal 24-hr production averaged 55, 16, and 403gC m⁻²y⁻¹ for phytoplankton, benthic algae, and emergent vascular vegetation, respectively. Total production over the whole estuary was 17,667 metric tons C y⁻¹ for phytoplankton, 1,545mt C y⁻¹ for benthic algae, and 11,325mt C y⁻¹ for emergent vascular plants, for a grand total to 30,537mt C y⁻¹. Phytoplankton biomass turned over approximately 39 times per year on average, while benthic algae turned over about twice and emergent plants once per year.Budgets for phytoplankton carbon (PPOC) and DPOC were developed based on PPOC and DPOC import and export, grazing loss, and in situ production and conversion of PPOC to DPOC. It is suggested that 36,205mt y⁻¹ of PPOC is converted to DPOC in the estuary, principally at the freshwater-brackishwater interface. About 40,560mt y⁻¹ of PPOC is exported to the ocean, and 159,185mt y⁻¹ of DPOC is transported into the marine zone of the estuary (no data are available on DPOC export to the ocean). Thus, the estuary acts principally as a conduit for the transport of particles to the sea, and only secondarily as a converter of viable phytoplankton cells to detrital carbon and as a trap for DPOC.     

Towards the implementation of an integrated ecosystem fleet-based management of European fisheries

Using the Celtic Sea and the North Sea as case studies, the fleet-based approach is shown to be the pathway to implement an effective ecosystem approach to fisheries management (EAFM) in European seas. First, a diagnostic on the health of each ecosystem is proposed based on the reconstruction of long time-series of catch, the analysis of mean indicators or stocks trajectories derived from ICES stock assessment results, and the analysis of ecosystem indicators. Then, a fleet-based synthesis is presented using indicators of both the ecological impact and the economic performances of the major fleets operating within each ecosystem. In particular, assessment diagrams show whether each fleet segment, on average, sustainably exploits the stocks. Although results are preliminary due to the poor quality of available data, the analysis shows that simple indicators can be estimated and clearly highlight contrasts between fleet segments. Such an approach contributes to the evolution from a stock-based to a fleet-based management, which reflects the ecological, economical and social pillars of the sustainable development of fisheries.