Further constraints for Permo-Carboniferous magnetostratigraphy: case study of the sedimentary sequence from San Salvador–Patlanoaya (Mexico)De nouvelles contraintes pour la magnétostratigraphie du Permo-Carbonifères : cas d'étude de la séquence sédimentaire de San Salvador–Patlanoaya (Mexique)

We report rock-magnetic and magnetostratigraphic results from one of the best exposed Permo-Carboniferous outcrops in Mexico, in order to determine some decisive magnetostratigraphy constraints. Some spinels, most probably titanomagnetites, seem to be responsible for aimantation, although greigite may also exist judging from thermal desaimantation of isothermal remanence. Remanence analyses indicate that only one remanent component could be recognized with minor secondary overprint, which were easily removed applying 100–180 °C. Six normal and four reverse magnetozones were recognized from bottom to top in Patlanoya section between 340 and 280 Myr. Both normal and reverse polarity rocks were found in Carboniferous time around 340 Myr, in agreement with previous paleomagnetic works. Our record revealed two normal subchrons within PCRS (Kiaman), the dominantly reverse superchron, at 305 and 280 Myr, respectively. These, which may be speculatively correlated to normal aimantation, occasionally occurred during PCRS interval. More detailed studies are needed in order to establish a more precise magnetostratigraphy for Permo-Carboniferous time. To cite this article: L.M. Alva-Valdivia et al., C. R. Geoscience 334 (2002) 811–817.     

Values for a post-Kyoto discourse

Environmental policy, including the Kyoto Protocol, is laden with values. Recognizing this fact can help UNFCCC parties come to agreement. Much of the contention surrounding the post-Kyoto negotiations can be explained through a framework of values. This article summarizes the arguments used by proponents and critics of emissions trading of greenhouse gas emissions under the Kyoto Protocol through such a framework of values. Proponents and critics of emissions trading espouse common values, such as achievement, to work toward ameliorating climate change; there is less agreement on emissions trading seen through values such as responsibility and fairness. As non-Annex I parties are expected to take a more active role in the second commitment period, identifying values held by those working on their behalf will facilitate negotiations and help develop a discourse that is inclusive of their interests. Annex I parties can also benefit from the identification of the values to better convey their interests. All parties can use the values framework identified here to construct a more durable climate change regime.     

Identifying the exposure of two subsistence villages in Alaska to climate change using traditional ecological knowledge

Dramatic climatic change in the Arctic elevates the importance of determining the risk of exposure for people living in vulnerable areas and developing effective adaptation programs. Climate change assessment reports are valuable, and often definitive, sources of information for decision makers when constructing adaptation plans, yet the scope of these reports is too coarse to identify site-specific exposure to the impacts of climate change and adaptation needs. Subsistence hunters and gatherers in the Arctic are valuable knowledge holders of climate-related change in their area. Incorporating both their traditional ecological knowledge and information found in climate science assessment reports can offer adaption planners a deeper understanding of exposure to climate change and local adaptation needs. In this study, we compare information found in assessment reports of climate change in the Arctic with what we have learned from the Alaskans Sharing Indigenous Knowledge project from 2009 to 2012, a research project documenting traditional ecological knowledge in two Native villages in Alaska, Savoonga and Shaktoolik. Content analysis of the interviews with hunters and gatherers reveal the site-specific impacts of climate change affecting these two villages. We find that their traditional ecological knowledge is complimentary and largely corroborates the climate science found in assessment reports. Traditional ecological knowledge, however, is more current to the social and local conditions of the villages, and presents a more unified social and biophysical portrayal of the impacts of climate change. If taken together, these two forms of knowledge can focus adaptation planning on the pertinent needs of the communities in question.     

An approach to estimate Lower Jurassic seawater oxygen‐isotope composition using δ18O and Mg/Ca ratios of belemnite calcites (Early Pliensbachian,northern Spain)

Palaeotemperature estimates from the oxygen‐isotope compositions of belemnites have been hampered by not knowing ancient seawater isotope compositions well enough. We have tackled this problem using Mg/Ca as a proxy for temperature and here, we present a ~2 Ma record of paired Mg/Ca and δ¹⁸O measurements of Jurassic (Early Pliensbachian) belemnites from the Asturian basin as a palaeo‐proxy of seawater oxygen‐isotope composition. From the combined use of the two approaches, we suggest a δ¹⁸O_w composition of about ?0.1‰ for the Jamesoni–Ibex zones. This value may have been increased by about 0.6‰ during the Davoei Zone due to the effect of waters with a different δ¹⁸O_w composition. These findings illustrate the inaccuracy of using a globally homogeneous ice‐free value of δ¹⁸O_w = ?1‰ for δ¹⁸O_carb‐based palaeotemperature reconstructions. Our data suggest that previous palaeotemperatures calculated in the region from δ¹⁸O values of belemnites may have been underestimated as the seawater oxygen isotopic composition could have been higher.     

Recharge sources and hydrogeological effects of irrigation and an influent river identified by stable isotopes in the Motril‐Salobreña aquifer (Southern Spain)

Measurement of the stable isotopes oxygen‐18 and deuterium in water is an important tool to characterize aquifer recharge sources. In the driest areas of the Mediterranean, this application is of special interest due to the scarcity of water and the resulting common incidence of human influence on natural hydrological systems. The Motril‐Salobreña detrital aquifer (southern Spain) is a clear example of such an impact as inhabitants have designed irrigation systems and a dam was recently built across the course of the Guadalfeo River, which feeds the aquifer. The sampling of (river or ground) water has allowed the determination of stable isotope contents (oxygen‐18 and deuterium), both temporally and spatially, and the relative importance of the main recharge sources in certain sectors. In addition, we were able to infer seasonal trends and to improve existing knowledge of the main flow paths and the position of a seasonal groundwater divide. Data analysis shows evaporation plays a minor role (despite the high temperatures in the zone), scarce rainwater influence, and the overwhelming contribution of recharge from the Guadalfeo River and from the carbonate aquifer (Escalate aquifer) in contact with the Motril‐Salobreña aquifer. Irrigation return flow during the summer months comprises the main recharge due to the significant volumes of water that infiltrate. The construction of the dam will almost certainly entail great changes in the current dynamics of the hydrogeology of the Motril‐Salobreña aquifer; therefore, knowledge of its behaviour is crucial in order to carry out sustainable use of its groundwater resources. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial trends in the geochemical composition of sediments in the Panuco River discharge area, Gulf of Mexico.

Major and trace elements, organic matter, carbonates, loss of ignition, grain size, gravel, sand, silt, clay, and qualitative mineralogical composition were determined on surficial marine sediments sampled during the stormy (February), dry (May), and rainy (September) seasons in the coastal area adjacent to Panuco River discharges into the Gulf of Mexico. The sediments supplied by the river move in a north-east direction, and are deposited in the north-east extreme of the studied area. Terrigenous sediments show a strong association of Al₂O₃ with Fe₂O₃, Na₂O, K₂O, P₂O₅, Rb, Cu, Zn, organic matter, clay, and grain size (Mz). Mineralogical analysis shows that they are formed by quartz, kaolinite, montmorillonite, illite-montmorillonite and biotite. The highest metal concentration of Cu (25 mg/kg), Zn (155 mg/kg), Pb (50 mg/kg) and organic matter (1.26%) was observed in the sampling points located very close to the river mouth. A statistical analysis was done with the information contained in the variables. Five significant factors explain 77% of the total variance: factor 1 is due to sediments from a terrigenous source, factor 2 corresponds to sediments from a biogenous source, factor 3 is associated to sediments with heavy minerals, factor 4 is due to Co concentration, and factor 5 is due to Ni concentration. The sediments supplied from the river had a short-term local impact on the sediment distribution, as observed by the carbonate and heavy mineral concentration of the sediments.     

Aptian— Albian tectonic pattern of the Basque— Cantabrian Basin (Northern Spain)

During the Aptian and Albian thick terrigenous and carbonate successions of sediments up to 5000 m thick, including shallow water rudist limestones (Urgonian facies), were deposited in the Basque– Cantabrian Basin of northern Spain as a result of an intense rift-related subsidence. Based on criteria from surface and subsurface data, syn-sedimentary faults, folds, angular unconformities, diapirs and sub-basins are distinguished within the Urgonian successions. Faults are grouped into N– S, E– W, NW– SE and NE– SW families and most are normal and strike-slip. Folds are gentle anticlines and synclines related to major faults. The angular unconformities have small hiatuses, poor lateral continuity and they are associated with either folds or tilted blocks. Diapirs are related to the intersection of major basement faults and in at least one instance the diapir was fossilized by Late Albian times. Strong differential subsidence controlled by basement faults determined the division of the basin into many subbasins of different sizes, which acted as depocentres (e.g. Bilbao). Despite the tectonic inversion which affected the basin during the Tertiary and created thrusts in their margins and centre, the present position of the syn-sedimentary tectonic structures gives approximate clues about the broad structural style and this reveals the original model of basin extension. Features characteristic of strike-slip identified in different parts of the basin are displaced geological lines, wrench corridors, drag effects, thickness shifts, paired uplifts and basins, vaulting of ‘slabs’, decreasing displacements, horsetail and fault splays, ‘chessboard’, oroflexural bending, pull-apart geometries, in-line horst slices, and restraining/releasing bends. Sinistral strike-slip movements along major NW– SE faults are supposedly responsible for transtension, which characterized the basin particularly during the Albian. In this scenario, the main wrench movements would have concentrated along the Oiz domain (Biscay Tertiary Synclinorium) and is a situation that has more in common with the strike-slip model proposed by some workers for the western Pyrenees, than with the simple extension models proposed for the northern margin of the Bay of Biscay.     

Transfers from the Earth to $$L_2$$ L 2 Halo orbits in the Earth–Moon bicircular problem

Celestial Mechanics and Dynamical Astronomy - The Cassini spacecraft discovered many close-in small satellites in Saturnian system, and several of them exhibit exotic orbital states due to...     

Primary and diagenetic isotopic signals in fossils and hemipelagic carbonates: the Lower Jurassic of northern Spain

Stable isotope and trace element analyses of 230 Jurassic (Pliensbachian–Toarcian) samples from northern Spain have been performed to test the use of geochemical variations in fossils (belemnites and brachiopods) and whole‐rock hemipelagic carbonates as palaeoceanographic indicators. Although the succession analysed (Reinosa area, westernmost Basque–Cantabrian Basin) has been subject to severe thermal alteration during burial diagenesis, the samples appear to be well preserved. The degree of diagenetic alteration of the samples has been assessed through the application of integrated petrographic, chemical and cathodoluminescence analyses. It is demonstrated that brachiopods and whole‐rock carbonates, although widely used for palaeoceanic studies, do not retain their primary marine geochemical composition after burial diagenesis. In contrast, there is strong evidence that belemnite rostra preserve original isotopic values despite pervasive diagenesis of the host rock. Well‐preserved belemnite shells (non‐luminescent to slightly luminescent) typically show stable isotope values of +4·3‰ to –0·7‰δ¹³C, +0·7‰ to –3·2‰δ¹⁸O, and trace element contents of <32 μg g^–1 Mn, <250 μg g^–1 Fe, >950 μg g^–1 Sr and Sr/Mn ratios >80. This study suggests that the degree to which diagenesis has affected the preservation of an original isotopic composition may differ for different low‐Mg calcite fossil shells and hemipelagic bulk carbonates, behaviour that should be considered when marine isotopic signatures from other ancient carbonate rocks are investigated. Multiple non‐luminescent contemporaneous belemnite samples passed the petrographic and geochemical tests to be considered as palaeoceanic recorders, yet their δ¹³C and δ¹⁸O values exhibited moderate scatter. Such variability is likely to be related to the palaeoecological behaviour of belemnites and/or high‐frequency secular variations in sea‐water chemistry superimposed on the long‐term isotopic trend. A pronounced positive carbon‐isotope excursion (up to +4·3‰) is documented in the early Toarcian serpentinus biozone, which correlates with the Toarcian δ¹³C maximum reported in other European and Tethyan regions.     

Feasibility of Solid‐State Fermentation Using Spent Fungi‐Substrate in the Biodegradation of PAHs

The ability of Trametes versicolor and Pleurotus ostreatus to grow on agroindustrial wastes, such as orange peels, and to degrade model polycyclic aromatic hydrocarbons (PAHs) in solid‐state fermentation (SSF) was evaluated. Best results in laccase production were obtained with T. versicolor cultures (3000 U L^?1), however, P. ostreatus (2700 U L^?1) showed higher ability to degrade the tested PAHs phenanthrene (PHE) and pyrene (PYR). Moreover, orange peels can be used as biofertilizer and the oxidative ability of the spent fungus and substrate obtained in SSF can be used in the remediation of polluted soil. The results obtained confirm this hypothesis. Thus, the decontamination achieved in soils polluted with PYR was around 43% (after 30 days) by addition of spent fungus and substrate from SSF.