A measurement of the 362 GHz absorption line of Mars atmospheric H2O2

The 362.156 GHz absorption spectrum of H₂O₂ in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H₂O₂ abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (L_s) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HO_x abundances above ∼10 km altitudes between the L_s=112° period of the Encrenaz et al. upper limit measurement and the current L_s=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H₂O₂ line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H₂O₂. Observation of Mars H₂O₂ also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.     

On the stability of particular solutions of the singly averaged Hill problem

We consider the particular solutions of the evolutionary system of equations in elements that correspond to planar and spatial circular orbits of the singly averaged Hill problem. We analyze the stability of planar and spatial circular orbits to inclination and eccentricity, respectively. We construct the instability regions of both particular solutions in the plane of parameters of the problem.     

Prospects for astrometry with the Hubble Space Telescope

The Hubble Space Telescope (HST), a large optical telescope having an aperture of 2.4 meters and a length of 8.8 meters, is being developed by the National Aeronautics and Space Administration. This telescope will be placed into earth orbit by the space shuttle. Astrometric observations with the HST are made using a Fine Guidance Sensor which is capable of measuring the position of one object relative to another with an accuracy of ±0.002 arcseconds. The astrometric user of HST will be provided with an Astrometric Data Reduction Software package (ADRS). The variety of astrometric problems to be investigated with HST is discussed.     

Kinematics of stars in Kovalsky-Kapteyn figures. II

Rostov State Pedagogical Institute; All-Union Scientific Research Institute Gradient. Translated from Astrofizika, Vol. 33, No. 3, pp. 379–393, November–December, 1990.     

A transformation of the two-body problem

A transformation of the differential equations of motion of the two-body problem in the spherical coordinates to oscillator form is derived. It is shown that the independent variable transformation dt/ds=r² is a transformation which makes the oscillator form possible.     

Enzymatic synthesis of methyl-galactoaldehyde

Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide synthesis.