- The dynamic response behaviors of upright breakwaters under broken wave impact are analysed based on the mass-damper-spring dynamic system model. The effects of the mass, damping, stiffness, natural period, and impulse duration (or oscillation period) on the translation, rotation, sliding force, overturning moment, and corresponding dynamic amplifying factors are studied. It is concluded that the ampli-ying factors only depend on the ratio of the system natural period to impulse duration (or oscillation period) under a certain damping ratio. Moreover, the equivalent static approach to breakwater design is also discussed. 相似文献
An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H2S/HS–/SO
inf4sup2–
. The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H2S+HH–=Au(HS)
2–
+1/2H2 (K14); PtS+HS–+H+=Pt (HS)
20
(K15); PdS+HS–+H+=Pd (HS)
20
(K16); PtS2+H2=Pt (HS)
20
(K21).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H2 gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H2 at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits. 相似文献
We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California. 相似文献
Using more than three million Landsat satellite images, this research developed the first global impervious surface area (GISA) dataset from 1972 to 2019. Based on 120,777 independent and random reference sites from 270 cities all over the world, the omission error, commission error, and F-score of GISA are 5.16%, 0.82%, and 0.954, respectively. Compared to the existing global datasets, the merits of GISA include: (1) It provided the global ISA maps before the year of 1985, and showed the longest time span (1972–2019) and the highest accuracy (in terms of a large number of randomly selected and third-party validation sample sets); (2) it presented a new global ISA mapping method including a semi-automatic global sample collection, a locally adaptive classification strategy, and a spatio-temporal post-processing procedure; and (3) it extracted ISA from the whole global land area (not from an urban mask) and hence reduced the underestimation. Moreover, on the basis of GISA, the long time series global urban expansion pattern (GUEP) has been calculated for the first time, and the pattern of continents and representative countries were analyzed. The two new datasets (GISA and GUEP) produced in this study can contribute to further understanding on the human’s utilization and reformation to nature during the past half century, and can be freely download from http://irsip.whu.edu.cn/resources/dataweb.php.