Integrated stochastic modeling of pharmaceuticals in sewage networks

Pharmaceuticals and particularly antibiotics can harm sensitive aquatic species. Their occurrence in urban wastewater systems is the consequence of five successive processes: (i) ingestion of the substance, (ii) accumulation in the urine, (iii) excretion, (iv) degradation in the sewer system and (v) transport to the wastewater treatment plant (WTP). These processes were included in an integrated model that can be used to assess the dynamics of pharmaceuticals at a WTP inlet. First, information on sales data, posology, pharmacokinetics and toilet flushing frequency were combined to create a source model of pharmaceuticals entering a sewer system. This production function was then coupled with a transport/degradation model to simulate concentrations of pharmaceuticals at a WTP inlet. In an example application, the full model was applied to simulate the concentration of the antibiotic ciprofloxacin on an hourly time scale. In this application, the model was calibrated and validated for a case study at a WTP in Lausanne, Switzerland. Validation of the integrated approach was successful despite the high variability evident in the model results. This modeling approach has potential use in pollution management and epidemiology related to wastewater.     

Biofiltration of fishpond effluents and accumulation of N-compounds (phycobiliproteins and mycosporine-like amino acids) versus C-compounds (polysaccharides) in Hydropuntia cornea (Rhodophyta)

The biofiltration capacity, biomass-yield and accumulation of N- and C-compounds of Hydropuntia cornea were analyzed. Algae were grown in different conditions for 28 d: outdoor and indoor, with or without fishpond effluents. N-uptake efficiency of these effluents was higher than 95% after 7 d both outdoors and indoors. N-enriched conditions reduced the extent of photoinhibition and increased the maximal quantum yield in H. cornea. The biomass-yield was higher in outdoor grown-algae after 7 d and decreased independently of the treatment after 28 d. N, acid polysaccharide (AP) and mycosporine-like amino acid (MAA)-yields decreased throughout the experiment in all conditions. The highest MAA-yield was observed in fishpond effluent outdoor-grown algae, indicating a positive effect of increased radiation on MAA accumulation. However, APs were higher under N-depleted conditions. The use of MAAs as UV-screening and antioxidants, and the use of AP as immunostimulants are discussed.     

Climate variability of southern Chile since the Last Glacial Maximum: a continuous sedimentological record from Lago Puyehue (40°S)

This paper presents a multi-proxy climate record of an 11 m long core collected in Lago Puyehue (southern Chile, 40°S) and extending back to 18,000 cal yr BP. The multi-proxy analyses include sedimentology, mineralogy, grain size, geochemistry, loss-on-ignition, magnetic susceptibility and radiocarbon dating. Results demonstrate that sediment grain size is positively correlated with the biogenic sediment content and can be used as a proxy for lake paleoproductivity. On the other hand, the magnetic susceptibility signal is correlated with the aluminium and titanium concentrations and can be used as a proxy for the terrigenous supply. Temporal variations of sediment composition evidence that, since the Last Glacial Maximum, the Chilean Lake District was characterized by three abrupt climate changes superimposed on a long-term climate evolution. These rapid climate changes are: (1) an abrupt warming at the end of the Last Glacial Maximum at 17,300 cal yr BP; (2) a 13,100–12,300 cal yr BP cold event, ending rapidly and interpreted as the local counterpart of the Younger Dryas cold period, and (3) a 3,400–2,900 cal yr BP climatic instability synchronous with a period of low solar activity. The timing of the 13,100–12,300 cold event is compared with similar records in both hemispheres and demonstrates that this southern hemisphere climate change precedes the northern hemisphere Younger Dryas cold period by 500 to 1,000 years. This is the third in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M.-F. Loutre and E. Chapron.     

Qualitative and Quantitative Description of Multibeam Echosounder Systematic Errors on Rocky Areas

This paper deals with the problem of systematic depth errors made in surveying dumped rocks with multibeam echosounder. These errors may induce dangers for navigation in very shallow water areas or huge costs for coastal engineering contractors who perform rock dumping operation and surveying. We analyze results from four different multibeam echosounder systems and compare those data to a reference digital terrain model of a dumped rocks area obtained from a 3D terrestrial laser scanner. The systematic depth errors are statistically described and analysed on local areas. Finally, we propose a look-up table linking the error amplitude with the rock size, resulting from our error analysis.     

Variation of colour patterns in larval Hydropsyche (Trichoptera): Implications for species identifications and the phylogeny of the genus

Larvae of the lotic caddisfly genus Hydropsyche may occur in densities of thousands to several tens of thousands of individuals/m² across continents and running water types. Therefore, stream ecologists frequently face the task of identifying larvae of this genus. Early keys to larval Hydropsyche of Asia, Europe and North America often used the relatively complicated frontoclypeal colour pattern for species discrimination, whereas equivocal views about the variation of this pattern limited its use in recent keys. Has each species of a given species group a different (although intraspecifically variable) basic pattern of lighter spots on the darker frontoclypeus, or have all species of a group the same basic colour pattern that varies more or less intraspecifically? An answer to this question has obvious implications for the identification of the species as well as for the phylogeny of the genus, so we examined the variation of this colour pattern across ∼11,000 specimens of 10 Hydropsyche species from the Loire River (France).All 10 species had the same basic colour pattern on the frontoclypeus (six contrasting light patches on a dark background) that varied intraspecifically across a certain range of colour contrasts. Comparing other sources illustrating the frontoclypeus of Hydropsyche larvae provided more support for the idea that six contrasting light patches on the frontoclypeus is the typical basic colour pattern that varies within almost all European species; males of these species have a simple phallus form. Two European and many North American species of the genus (from the Ceratopsyche group) have a different basic colour pattern of seven light patches on the frontoclypeus that varies also intraspecifically; males of these species have a complicated phallus form.If the variation of such colour patterns in co-existing populations of several species is known, the relative contrast differences among the individual patches on the frontoclypeus and the form of the individual patches can provide valuable information for rapid species identification. Analysis of this variation may also contribute to phylogenetic studies of the genus Hydropsyche and other hydropsychids.     

Estimates of Horizontal Groundwater Flow Velocities in Boreholes

Currently, monitoring tools can be deployed in observation boreholes to better assess groundwater flow, flux of dissolved contaminants and their mass discharge in an aquifer. The relationship between horizontal water velocity in observation boreholes and Darcy fluxes in the surrounding aquifer has been studied for natural flow conditions (i.e., no pumping). Interpretation of measurements taken with dilution tests, the colloidal borescope, the Heat Pulse Flowmeter, and other techniques require the conversion of observed borehole velocity u to aquifer Darcy flux q_∞ . This conversion is typically done through a proportionality factor α = u/q_∞ . In experimental studies as well as in theoretical developments, reported values of α vary almost three orders of magnitude (from 0.5 to 10). This large variability in reported values of α could be explained by: (1) unclear distinction between Darcy flux and water seepage velocity, (2) unclear definition of water velocity in the borehole, (3) effects of well screen and the presence of the measurement device itself on the observable velocities, and (4) hydraulic conditions in the borehole annulus. We address (1), (2) from a conceptual/theoretical perspective, and (3) by means of numerical simulations. We show that issue (1) in low porosity aquifers can yield to order-of-magnitude discrepancies in estimates of q_∞ ; (2) may result in discrepancies of up to 50%, and (3) can cause differences up to 20% of water velocity in the borehole void space compared to the theoretical case of an open borehole.     

Performance of the LandSoil expert-based model to map erosion and sedimentation: application to a cultivated catchment in central Belgium

Intensive agricultural practices on sensitive soils induce high erosion rates in central Belgium. Expert-rules models quantify runoff and erosion at catchment scale, avoiding over-parameterization, and can include some direct or indirect connectivity features. The aim of this article is to test the ability of an expert-based model, LandSoil, to quantify runoff and to locate erosion and sedimentation areas in a small cultivated loamy catchment in Belgium during the years 2014, 2015 and 2016. Spatialized data are important for assessing model outputs and the erosive response. Measurements of runoff and observation of spatial erosion/deposition patterns, especially around major connectivity points, permitted an assessment of the reliability of the model results. Runoff modelling gave contrasting results (good linear adjustment at the outlet of the 83 ha sub-catchment (point 1): r² of 0.96, Nash–Sutcliffe criterion of 0.95; less good at the outlet of the 3.9 ha sub-catchment (point 2): r² of 0.28, Nash–Sutcliffe criterion of –0.47). For point 2 the poor results are explained by the very few runoff events observed, a scaling effect and the small area with a single land use. Graduated rulers demonstrate that the model is able to provide a coherent pattern of erosion/deposition. The study highlights great sensitivity to the effect of land use, land allocation, landscape design and slope gradients. Grass strips induce deposition of eroded particles when slopes are gentle (< 2%). Woodland strips decrease connectivity by being in the stream but deposit thinner sediment layers. Field boundaries have a role in the transport, but not really the quantity, of sediments. This model validation in the Belgian loess context allows us to use LandSoil in other similar environments in order to estimate the effects of landscape management scenarios. © 2020 John Wiley & Sons, Ltd.     

Simulation of the 2004 tsunami of Les Saintes in Guadeloupe (Lesser Antilles) using new source constraints

Natural Hazards - The arc of the Lesser Antilles is associated with a significant tectonic activity due to the subduction of the Atlantic oceanic plate under the Caribbean plate. Earthquakes in...     

Visible and near-infrared spectrophotometry of the Deep Impact ejecta of Comet 9P/Tempel 1

We have obtained optical spectrophotometry of the evolution of Comet 9P/Tempel 1 after the impact of the Deep Impact probe, using the Supernova Integral Field Spectrograph (SNIFS) at the UH 2.2-m telescope, as well as simultaneous optical and infrared spectra using the Lick Visible-to-Near-Infrared Imaging Spectrograph (VNIRIS). The spatial distribution and temporal evolution of the “violet band” CN (0-0) emission and of the 630 nm [OI] emission was studied. We found that CN emission centered on the nucleus increased in the 2 h after impact, but that this CN emission was delayed compared to the light curve of dust-scattered sunlight. The CN emission also expanded faster than the cloud of scattering dust. The emission of [OI] at 630 nm rose similarly to the scattered light, but then remained nearly constant for several hours after impact. On the day following the impact, both CN and [OI] emission concentrated on the comet nucleus had returned nearly to pre-impact levels. We have also searched for differences in the scattering properties of the dust ejected by the impact compared to the dust released under normal conditions. Compared to the pre-impact state of the comet, we find evidence that the color of the comet was slightly bluer during the post-impact rise in brightness. Long after the impact, in the following nights, the comet colors returned to their pre-impact values. This can be explained by postulating a change to a smaller particle size distribution in the ejecta cloud, in agreement with the findings from mid-infrared observations, or by postulating a large fraction of clean ice particles, or by a combination of these two.     

Sensitivity of simulated Asian and African summer monsoons to orbitally induced variations in insolation 126, 115 and 6 kBP

We have conducted four numerical experiments with an atmospheric general circulation model (AGCM) to investigate the sensitivity of Asian and African monsoons to small changes (–5 to +12%), with respect to present-day, in incoming solar radiation at the top of the atmosphere. We show that, during the mid-Holocene (6 kBP where kBP means thousands of years before present-day) and the last interglacial (126 kBP), the Northern Hemisphere seasonal contrast was increased, with warmer summers and colder winters. At the time of glacial inception (115 kBP) however, summers were cooler and winters milder. As a consequence, Asia and tropical North Africa experienced stronger (weaker) summer monsoons 6 and 126 kBP (115 kBP), in agreement with previous numerical studies. This present study shows that summer warming/cooling of Eurasia and North Africa induced a shift of the main low-level convergence cell along a northwest/southeast transect. When land was warmer (during the summer months 6 and 126 kBP), the monsoon winds converged further inland bringing more moisture into northern India, western China and the southern Sahara. The southern tips of India, Indochina and southeastern China, as well as equatorial North Africa became drier. When land was cooler (during the summer 115 kBP), the main convergence zone was located over the west Pacific and the wet (dry) areas were those that were dry (wet) 6 and 126 kBP. The location and intensity of the simulated precipitation maxima were therefore very sensitive to changes in insolation. However the total amount of monsoon rain in Asia as well as in Africa remained remarkably stable through the time periods studied. These simulated migrations of convective activities were accompanied by changes in the nature of precipitation events: increased monsoon rains in these experiments were always associated with more high precipitation events (> 5 mm day ^–1), and fewer light showers (1 mm day^–). Rainy days with rates between 1 and 5 mm day^–1 were almost unchanged.