Characteristics of alkenone distributions in suspended and sinking particles in the northwestern North Pacific

We investigated alkenones recorded in suspended particles and a settling particle time series collected at three stations, 40N (40°N, 165°E), KNOT (44°N, 155°E), and 50N (50°N, 165°E), in the northwestern North Pacific from December 1997 to May 1999. Emiliania huxleyi, the most abundant alkenone producer in this area, is present in surface to subsurface (to ∼50 m depth) waters. The alkenone concentrations recorded in the suspended particles indicated that the seasonal alkenone particle distribution differed significantly interannually. Alkenone export fluxes at the three sediment-trap stations ranged from 0.16 to 49.3 μg m⁻² day⁻¹, and the maximum export flux, which occurred in summer to fall (July-November), was associated with a high organic carbon export flux. The amount of alkenone produced during the maximum export season accounted for 60-80% of the total annual amount of alkenone, and the alkenones accumulated in the sediment below the traps had characteristics corresponding to subsurface waters during the summer-autumn season. Alkenone-derived temperatures recorded in suspended particles corresponded to the in situ temperature within ∼2 °C. Although alkenone-derived temperatures corresponded approximately to the temperatures observed in the stratified subsurface waters at the three trap stations during the high-export season, large differences were observed during the low-export (winter-spring) period. For example, the alkenone-derived temperatures observed at stations KNOT and 50N were much higher than the in situ subsurface temperatures reported in the World Ocean Atlas 2001. Relatively large differences between alkenone-derived temperatures and in situ temperatures in the subarctic might be due to (1) a low-light limitation or (2) contributions of allochthonous alkenones in particulate material transported from subtropical areas within a warm-core ring.     

Tissemouminites: A new group of primitive achondrites spanning the transition between acapulcoites and winonaites

The Northwest Africa (NWA) 090 meteorite, initially classified as an acapulcoite, presents petrological, chemical, and isotopic characteristics comparable to a group of seven primitive winonaites: Dhofar 1222, NWA 725, NWA 1052, NWA 1054, NWA 1058, NWA 1463, and NWA 8614. Five of these samples were previously classified as acapulcoites or ungrouped achondrites before being reclassified as winonaites based on their oxygen isotopic compositions. These misclassifications are indicative of the particular compositional nature of these primitive achondrites. All contain relict chondrules and a lower closure temperature of metamorphism of 820 ± 20 °C compared to other typical winonaites, as well as mineral elemental compositions similar to those of acapulcoites. The oxygen isotopic signature of these samples, δ¹⁷O of 1.18 ± 0.17‰, δ¹⁸O of 3.18 ± 0.30‰, and Δ¹⁷O of −0.47 ± 0.02, is in fact resolvable from both acapulcoites and winonaites. We investigate the relationship between these eight primitive achondrites, typical winonaites, and acapulcoites, to redefine petrological, mineralogical, and geochemical criteria of primitive achondrite classification. Distinguishing between winonaites, acapulcoites, and this group of eight primitive achondrites can be unambiguously done using a combination of several mineralogical and chemical criteria. A combination of olivine fayalite content and FeO/MnO ratio, as well as plagioclase potassium content allow us to separate these three groups without the absolute necessity of oxygen isotope analyses. NWA 090 as well as the other seven primitive achondrites, although related to winonaites, are most likely derived from a parent body distinct from winonaites and acapulcoites–lodranites, and define a new group of primitive achondrites that can be referred to as tissemouminites.     

Petrology and shock history of the first depleted-like poikilitic shergottite Asuka 12325

Asuka (A) 12325 is the first poikilitic shergottite having a depleted pattern in light rare earth elements (REE). Compared with known poikilitic shergottites, A 12325 has smaller but more abundant pyroxene oikocrysts with remarkable Fe-rich pigeonite rims, indicating that A 12325 cooled relatively faster at a shallower part of the crust. The redox condition (logfO₂ = IW + 0.6-IW + 1.7) and Fe-rich chemical compositions of each mineral in A 12325 are close to enriched shergottites. The intermediate shergottites could not form by a simple mixing between parent magmas of A 12325 and enriched shergottites. Although A 12325 contains various high-pressure minerals such as majorite and ringwoodite, plagioclase is only partly maskelynitized. Therefore, the maximum shock pressure may be within 17–22 GPa. Thermal conduction and ringwoodite growth calculation around a shock vein revealed that the shock dwell time of A 12325 is at least 40 ms. The weaker shock pressure and longer shock dwell time in A 12325 may be attained by an impact event similar to those of nakhlites and Northwest Africa (NWA) 8159. Such a weak shock ejection event may be as common on Mars as a severe shock event recorded in shergottites. Alteration of sulfide observed in A 12325 may imply the presence of magmatic fluid in its reservoir on Mars. A 12325 expands a chemical variety of Martian rocks and has a unique shock history among poikilitic shergottites while A 12325 also implies that poikilitic shergottites are common rocks on Mars regardless of their sources.     

The Danebury Iron Age meteorite—An H5 ordinary chondrite “find” from Hampshire,England

What remains of a 30 g sample, first recognized as a meteorite in 1989 during characterization of metalworking debris from Danebury, an Iron Age hillfort, in Hampshire, England, has been classified as an H5 ordinary chondrite. Its arrival on Earth has been dated as 2350 ± 120 yr BP, making it contemporary with the period of maximum human activity at the recovery site. Despite its considerable terrestrial residence age, the interior of the specimen is remarkably fresh with a weathering index of W1/2. There is, however, no evidence of human intervention in its preservation. Its near‐pristine state is explained in terms of its serendipitous burial during the back‐fill of a pit dug into chalk by prehistoric people for the storage of grain. This chance discovery has interesting ramifications for the survival of meteorites in areas having a high pH because of a natural lime content arising as a result of the local geology.     

Thresholds of Adverse Effects of Macroalgal Abundance and Sediment Organic Matter on Benthic Habitat Quality in Estuarine Intertidal Flats

Confidence in the use of macroalgae as an indicator of estuarine eutrophication is limited by the lack of quantitative data on the thresholds of its adverse effects on benthic habitat quality. In the present study, we utilized sediment profile imagery (SPI) to identify thresholds of adverse effects of macroalgal biomass, sediment organic carbon (% OC) and sediment nitrogen (% N) concentrations on the apparent Redox Potential Discontinuity (aRPD), the depth that marks the boundary between oxic near-surface sediment and the underlying suboxic or anoxic sediment. At 16 sites in eight California estuaries, SPI, macroalgal biomass, sediment percent fines, % OC, and % N were analyzed at 20 locations along an intertidal transect. Classification and Regression Tree (CART) analysis was used to identify step thresholds associated with a transition from "reference" or natural background levels of macroalgae, defined as that range in which no effect on aRPD was detected. Ranges of 3–15 g dw macroalgae m^?2, 0.4–0.7 % OC and 0.05–0.07 % N were identified as transition zones from reference conditions across these estuaries. Piecewise regression analysis was used to identify exhaustion thresholds, defined as a region along the stress–response curve where severe adverse effects occur; levels of 175 g dw macroalgae m^?2, 1.1 % OC and 0.1 % N were identified as thresholds associated with a shallowing of aRPD to near zero depths. As an indicator of ecosystem condition, shallow aRPD has been related to reduced volume and quality for benthic infauna and alteration in community structure. These effects have been linked to reduced availability of forage for fish, birds and other invertebrates, as well as to undesirable changes in biogeochemical cycling.     

Eocene paleobotanical altimetry of Victoria's Eastern Uplands

On the high-elevation, low-relief Bogong Plateau, within the Eastern Uplands in Victoria, well-preserved diverse macrofloras and microfloras have been recovered from Eocene sediments at two sites underlying Eocene–Oligocene basalts. Estimates of mean annual temperature (MAT) were made from the floras at each site, using a novel method calculating probability density functions and maximum likelihood co-occurrence climate envelopes of the nearest living relatives of multiple fossil taxa, and the proportion of non-toothed rather than toothed leaf margins of all fossil leaves. The most likely scenario is an Eocene MAT at Bogong Plateau of 18°C, consistent with the cloudy mesothermal montane environment indicated by the abundance of tree ferns and other flora. From the MAT, the maximum Eocene paleo-elevation of the flora sites on the plateau can be calculated using the ‘lapse rate’ method, and was probably around 550?700 m above sea-level (～1000 m lower than at present), but with large uncertainties for these estimates. The macrofloras accumulated in stream valleys, so the maximum elevation of the Eastern Uplands at the time was greater, matching other estimates of >800 m. Uplift to the present elevation probably occurred ca 8–4 Ma, so the alpine environment on the high plains dates to this time, and the high-altitude biota has therefore developed in the last 8 million years.     

‘Local gradient’ and between‐site variability of erosion rate on badlands in the Karoo,South Africa

Site‐average values of local gradient, defined as the steepest slope angle measured at a point, are a powerful predictor of long‐term rates of soil loss as measured by erosion pins on the non‐channel floor portions of ten badland study sites in the Karoo area of South Africa. Local gradient may be easily measured using a smartphone clinometer. The successful use of local gradient here is in strong contrast to the previous failure of other site‐specific attributes, including other measures of gradient and relief, to explain between‐site variation in erosion rate on these study sites. Each measurement of local gradient may be thought of as a sample of the site's microtopography. Microrelief is a strong determinant of the emergent patterns of inter‐channel overland flow, and hence of the patterns of inter‐channel erosion by flow. Local gradient changes most rapidly during the initial stages of channel incision. When channels are established, local gradient changes more slowly leading to almost‐parallel retreat of channel sidewalls. A sensitivity analysis suggests that measurements of local gradient are not all equal with regard to prediction of long‐term erosion rate. A greater share of predictive power is contributed by measurements made on very steep or vertical channel side wall areas, and a lesser share is contributed by measurements made on interfluves. Copyright © 2017 John Wiley & Sons, Ltd.     

Overestimation of short-term coastal cliff retreat rates in the eastern Mediterranean resolved with a sediment budget approach

Our understanding of sea-cliff erosion processes and their response to recent and/or projected environmental changes such as sea-level rise, climate change and anthropogenic development hinges on our ability to quantify sea-cliff retreat rates and their variability through time. Here, we focus on Israel's Mediterranean ‘Sharon’ sea-cliff as a case study for examining the significance of recent short-term (i.e. annual to decadal) cliff-top retreat rates that appear to exceed longer-term rates of ‘background’ (i.e. centennial to millennial) retreat by 1–2 orders of magnitude. We demonstrate that an inherent sampling bias in rate estimates inferred from observation intervals shorter than process episodicity can also explain such a pattern. This potential ambiguity leads to a striking paradox where despite highly accurate and robust documentation of recent cliff-top retreat, such as that obtained from aerial photographs and/or instrumental surveys, the short-term retreat rates of episodically retreating sea cliffs remain poorly constrained. To address this key data gap along the Sharon sea cliff we employed a sediment budget approach that focuses on quantifying the continuous wave scouring of cliff-collapsed material from the shore platform as a rate-limiting process for episodic retreat of the cliff above. We used four high-resolution (0.5 m/pixel) airborne LiDAR data sets acquired between 2006 and 2015 to determine short-term maximum retreat rates of up to ~0.08 m/yr during this nine-year period. These modern retreat rates compare to the cliff's background retreat rate of 0.03 to 0.09 m/yr since the mid-Holocene, as determined herein from multiple geologic and archeological observations. Our results demonstrate that previously reported twentieth century cliff-top retreat rates for this sea cliff, which range up to values of several meters per year, are biased and that sea-cliff erosion rates have not yet been significantly impacted by recent environmental changes in the eastern Mediterranean basin, such as the restriction of sediment supply following emplacement of the Nile's Aswan dam system. © 2018 John Wiley & Sons, Ltd.     

The formation and aqueous alteration of CM2 chondrites and their relationship to CO3 chondrites: A fresh isotopic (O,Cd, Cr,Si, Te,Ti, and Zn) perspective from the Winchcombe CM2 fall

As part of an integrated consortium study, we have undertaken O, Cd, Cr, Si, Te, Ti, and Zn whole rock isotopic measurements of the Winchcombe CM2 meteorite. δ⁶⁶Zn values determined for two Winchcombe aliquots are +0.29 ± 0.05‰ (2SD) and +0.45 ± 0.05‰ (2SD). The difference between these analyses likely reflects sample heterogeneity. Zn isotope compositions for Winchcombe show excellent agreement with published CM2 data. δ¹¹⁴Cd for a single Winchcombe aliquot is +0.29 ± 0.04‰ (2SD), which is close to a previous result for Murchison. δ¹³⁰Te values for three aliquots gave indistinguishable results, with a mean value of +0.62 ± 0.01‰ (2SD) and are essentially identical to published values for CM2s. ε⁵³Cr and ε⁵⁴Cr for Winchcombe are 0.319 ± 0.029 (2SE) and 0.775 ± 0.067 (2SE), respectively. Based on its Cr isotopic composition, Winchcombe plots close to other CM2 chondrites. ε⁵⁰Ti and ε⁴⁶Ti values for Winchcombe are 3.21 ± 0.09 (2SE) and 0.46 ± 0.08 (2SE), respectively, and are in line with recently published data for CM2s. The δ³⁰Si composition of Winchcombe is −0.50 ± 0.06‰ (2SD, n = 11) and is essentially indistinguishable from measurements obtained on other CM2 chondrites. In conformity with petrographic observations, oxygen isotope analyses of both bulk and micromilled fractions from Winchcombe clearly demonstrate that its parent body experienced extensive aqueous alteration. The style of alteration exhibited by Winchcombe is consistent with relatively closed system processes. Analysis of different fractions within Winchcombe broadly support the view that, while different lithologies within an individual CM2 meteorite can be highly variable, each meteorite is characterized by a predominant alteration type. Mixing of different lithologies within a regolith environment to form cataclastic matrix is supported by oxygen isotope analysis of micromilled fractions from Winchcombe. Previously unpublished bulk oxygen isotope data for 12 CM2 chondrites, when combined with published data, define a well-constrained regression line with a slope of 0.77. Winchcombe analyses define a more limited linear trend at the isotopically heavy, more aqueously altered, end of the slope 0.77 CM2 array. The CM2 slope 0.77 array intersects the oxygen isotope field of CO3 falls, indicating that the unaltered precursor material to the CMs was essentially identical in oxygen isotope composition to the CO3 falls. Our data are consistent with earlier suggestions that the main differences between the CO3s and CM2s reflect differing amounts of water ice that co-accreted into their respective parent bodies, being high in the case of CM2s and low in the case of CO3s. The small difference in Si isotope compositions between the CM and CO meteorites can be explained by different proportions of matrix versus refractory silicates. CMs and COs may also be indistinguishable with respect to Ti and Cr isotopes; however, further analysis is required to test this possibility. The close relationship between CO3 and CM2 chondrites revealed by our data supports the emerging view that the snow line within protoplanetary disks marks an important zone of planetesimal accretion.